摘要:
An entangled fibrous mat comprising an elastic polymer fiber A and a nonelastic polymer fiber B, said fiber A having voids therein and being in a taut condition within the mat; while said fiber B is in a slack condition and is highly elastic and flexible, rich in fullness, and firm-bodied, thus being very suitable for use as a substrate for artificial leather.
摘要:
The leather-like sheet substrate of the present invention comprises a fiber-entangled nonwoven fabric that comprises a microfine fiber bundle (A) and a microfine fiber bundle (B) in a blending ratio (A)/(B) of 30/70 to 70/30 by mass and a polymeric elastomer contained in the fiber-entangled nonwoven fabric. The microfine fiber bundle (A) comprises 10 to 100 microfine fibers each of which has a single fiber fineness of 0.5 dtex or less and which are made of an elastic polymer having a JIS A hardness of 90 to 97. The microfine fiber bundle (B) comprises a microfine fiber which has a single fiber fineness of 0.5 dtex or less and which is made of a non-elastic polymer. Because of its excellent stretchability in both the machine and transverse directions and drapeability, the leather-like sheet substrate is particularly suitable as the material for clothing.
摘要:
A method of producing an entangled sheet of microfine long fibers using long fibers for forming microfine fibers. The method includes a step of forming a long-fiber web made of long fibers for forming microfine fibers, at least one component of the long fibers being a water-soluble, thermoplastic polyvinyl alcohol resin; a step of entangling the long-fiber web to form a long-fiber entangled sheet; a step of shrinking the long-fiber entangled sheet to form a long-fiber shrunk sheet; and a step of converting the long fibers for forming microfine fibers in the long-fiber shrunk sheet to microfine long fibers, thereby producing the entangled sheet of microfine long fibers. The step of entangling is conducted so as to allow the long-fiber entangled sheet to have an interlaminar peel strength of 2 kg/2.5 cm or more. The step of shrinking is conducted so as to shrink in an areal shrinkage of 35% or more.
摘要:
In accordance with the present invention, it has now been found that the coagulation property of polyurethane elastomers can be considerably improved without spoiling any desirable chemical property of the original elastomer, if polyurethane elastomers which are different only in N%, are mixed together in a specified range of mixing ratio or if a polyurethane elastomer is synthesized using a mixture of polymer glycols whose structural units are chemically the same, however, whose molecular weights are different from each other in a specified range, and a solution of the obtained elastomer is coagulated by a specified wet coagulation condition.
摘要:
A method of producing an entangled sheet of microfine long fibers using long fibers for forming microfine fibers. The method includes a step of forming a long-fiber web made of long fibers for forming microfine fibers, at least one component of the long fibers being a water-soluble, thermoplastic polyvinyl alcohol resin; a step of entangling the long-fiber web to form a long-fiber entangled sheet; a step of shrinking the long-fiber entangled sheet to form a long-fiber shrunk sheet; and a step of converting the long fibers for forming microfine fibers in the long-fiber shrunk sheet to microfine long fibers, thereby producing the entangled sheet of microfine long fibers. The step of entangling is conducted so as to allow the long-fiber entangled sheet to have an interlaminar peel strength of 2 kg/2.5 cm or more. The step of shrinking is conducted so as to shrink in an areal shrinkage of 35% or more.
摘要:
The leather-like sheet substrate of the invention comprises a nonwoven fabric of three-dimensionally entangled superfine fibers (A) of at most 0.5 dtex in fineness and a polymer elastomer (B) filled in the entangled interspaces of the nonwoven fabric, in which the superfine fibers (A) comprise an organophosphorus component-copolymerized polyester and the polymer elastomer (B) contains a metal hydroxide or is copolymerized with an organophosphorus component. The leather-like sheet substrate of the invention and artificial leather obtained from it contain no halogen and are resistant to flames. These have a soft feel and are suitable to applications in the interior field that requires flame retardancy, especially to seats for vehicles, etc.
摘要:
The leather-like sheet substrate of the invention comprises a nonwoven fabric of three-dimensionally entangled superfine fibers (A) of at most 0.5 dtex in fineness and a polymer elastomer (B) filled in the entangled interspaces of the nonwoven fabric, in which the superfine fibers (A) comprise an organophosphorus component-copolymerized polyester and the polymer elastomer (B) contains a metal hydroxide or is copolymerized with an organophosphorus component.The leather-like sheet substrate of the invention and artificial leather obtained from it contain no halogen and are resistant to flames. These have a soft feel and are suitable to applications in the interior field that requires flame retardancy, especially to seats for vehicles, etc.
摘要:
The flame-retardant leather-like sheet substrate of the present invention comprises a layer (A) that is made of an entangled nonwoven fabric comprising a polyester superfine fiber (a) of a single fiber fineness of 0.5 dtex or less containing no flame-retardant component and a flame-retardant polyester superfine fiber (b) of a single fiber fineness of 0.5 dtex or less containing a flame-retardant component in a ratio, (a)/(b), of 100/0 to 40/60 by mass, and a layer (B) that is made of an entangled nonwoven fabric comprising the polyester superfine fiber (a) and the flame-retardant polyester superfine fiber (b) in a ratio, (a)/(b), of 70/30 to 0/100 by mass. The entangled nonwoven fabrics of the layers (A) and (B) are impregnated with an elastomeric polymer (c) containing a flame-retardant component. The ratio of the polyester superfine fiber (a) and the flame-retardant polyester superfine fiber (b) in the flame-retardant leather-like sheet substrate is 10:90 to 90:10 by mass. The flame-retardant leather-like sheet substrate and the artificial leather made thereof have an excellent flame retardancy, a soft and high-quality feeling and appearance, a high abrasion resistance and peel strength, and excellent mechanical properties such as surface strength.