公开(公告)号：US4017271A

公开(公告)日：1977-04-12

申请号：US588563

申请日：1975-06-19

申请人： Kenneth M. Barclay ,  James R. Birk ,  William E. Parkins

发明人： Kenneth M. Barclay ,  James R. Birk ,  William E. Parkins

IPC分类号： C01B3/36 ,  C10J3/57 ,  C10K1/00 ,  C10J3/00

CPC分类号： C10G19/00 ,  C10J3/57 ,  C10J3/78 ,  C10J3/84 ,  C01B2203/0283 ,  C01B2203/0415 ,  C01B2203/0475 ,  C01B2203/84 ,  C10J2300/093 ,  C10J2300/0943 ,  C10J2300/0946 ,  C10J2300/0956 ,  C10J2300/0959 ,  C10J2300/0969 ,  C10J2300/0976 ,  C10J2300/0986 ,  C10J2300/1662 ,  C10J2300/1671 ,  C10J2300/1815 ,  C10J2300/1846

摘要： A process for the production of a synthesis gas, capable of being upgraded to a high BTU pipeline gas, by the partial oxidation and substantially complete gasification of a carbonaceous material under CO-promoting conditions wherein the carbonaceous material, oxygen, and recycled carbon dioxide from the process are introduced into a molten salt containing an alkali metal carbonate and a minor portion of an alkali metal sulfide, the system being operated at a selected temperature and pressure between 1400.degree. and 2000.degree. F and between 1 and 100 atmospheres. The molar ratio of carbon dioxide to oxygen employed is controlled at from about 0.6:1 to about 1.2:1 to control the CO production and also to maintain the molten salt at a desired operating temperature. Sulfur and ash introduced with the fuel are retained in the molten salt. The gaseous effluent, containing a molar ratio of carbon monoxide to carbon dioxide substantially greater than one, is reacted in a water gas shift reaction, followed by removal of the carbon dioxide present in the gaseous effluent from the shift reaction to produce the synthesis gas, capable of being reacted further under appropriate conditions to produce pipeline gas, methanol, ammonia, or gasoline. At least a portion of the removed carbon dioxide is recycled for admixture with the oxygen to form the feed gas to the molten salt containing the carbonaceous material.

摘要翻译： 通过在CO促进条件下部分氧化和基本上完全气化碳质材料，生产合成气的方法，其能够升级为高BTU管道气体，其中碳质材料，氧气和循环二氧化碳从 将该方法引入含有碱金属碳酸盐和少量碱金属硫化物的熔盐中，该体系在1400〜2000°F的选择的温度和压力下操作，并且在1〜100个大气压下进行。 将二氧化碳与所使用的氧气的摩尔比控制在约0.6:1至约1.2:1，以控制CO产生并且还将熔融盐保持在期望的操作温度。 与燃料一起引入的硫和灰被保留在熔盐中。 含有一氧化碳与二氧化碳的摩尔比基本上大于1的气态流出物在水煤气变换反应中反应，然后除去存在于来自换档反应的气态流出物中的二氧化碳以产生合成气， 能够在合适的条件下进一步反应生成管道气体，甲醇，氨或汽油。 将去除的二氧化碳的至少一部分再循环用于与氧混合以在含有碳质材料的熔融盐中形成进料气体。

公开(公告)号：US4420464A

公开(公告)日：1983-12-13

申请号：US314611

申请日：1981-10-26

申请人： Kenneth M. Barclay

发明人： Kenneth M. Barclay

IPC分类号： C01G31/00 ,  C01G31/02 ,  C22B34/22

CPC分类号： C10J3/57 ,  C01G31/00 ,  C01G31/02 ,  C10J3/78 ,  C22B34/22 ,  C01P2006/60 ,  C01P2006/80 ,  C10J2300/0943 ,  C10J2300/0946 ,  C10J2300/0956 ,  C10J2300/0959 ,  C10J2300/1671 ,  C10J2300/1807 ,  Y10S423/12

摘要： A carbonaceous material containing vanadium is reacted with an oxidizing gas in a molten salt pool containing an alkali metal carbonate. Vanadium values present in the carbonaceous material are converted to water-soluble vanadium compounds which are recovered from the melt and reacted with a strong acid to precipitate the vanadium values as insoluble vanadates. The vanadates are recovered as product or optionally further converted to vanadium pentoxide.

摘要翻译： 含有钒的碳质材料与含有碱金属碳酸盐的熔盐池中的氧化气体反应。 存在于碳质材料中的钒值转化为水溶性钒化合物，其从熔体中回收并与强酸反应以将钒值沉淀为不溶性钒酸盐。 将钒酸盐作为产物回收或任选进一步转化为五氧化二钒。