公开(公告)号：US20150203639A1

公开(公告)日：2015-07-23

申请号：US14395108

申请日：2013-03-15

Applicant: (KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY)

Inventor： Kyung Youl Baek ,  Seung Sang Hwang ,  Soon Man Hong ,  Min Jae Ko ,  Yun Jae Lee ,  Hyun Ji Kim ,  Hyeon Yeol Jeon ,  Chong Min Koo

IPC: C08J3/24 ,  H01L51/00

CPC classification number: C08J3/246 ,  C08G61/126 ,  C08G2261/131 ,  C08G2261/1412 ,  C08G2261/1452 ,  C08G2261/3223 ,  C08G2261/354 ,  C08G2261/51 ,  C08G2261/74 ,  C08J2365/00 ,  C09D165/00 ,  H01L51/0036 ,  H01L51/0043 ,  Y10T428/31533

Abstract: The present invention provides a method for producing polythiophene star copolymer capable of being self-doped by an external stimulus, which includes the steps of: forming a polythiophene macroinitiator made by introducing a living radical polymerizable functional group into an end of polythiophene or a derivative thereof; forming through living radical polymerization a polymer macroinitiator for providing by an external stimulus at least a dopant selected from the group consisting of sulfonic acid radical, carboxylic acid radical and phosphoric acid radical; and polymerizing the polythiophene macroinitiator added with the polymer macroinitiator and at least one kind of divinyl monomer to produce the polythiophene star copolymer. The polythiophene star copolymer capable of being self-doped by an external stimulus according to the present invention is a self-doped material to stably increase conductivity, and can be used as a material for a conductive film.

Abstract translation: 本发明提供一种能够通过外部刺激自身掺杂的聚噻吩星型共聚物的制造方法，该方法包括以下步骤：通过将活性自由基聚合性官能团引入聚噻吩的末端或其衍生物形成聚噻吩大分子引发剂 ; 通过活性自由基聚合形成聚合物大分子引发剂，用于通过外部刺激提供至少一种选自磺酸根，羧酸根和磷酸根的掺杂剂; 并加入加入聚合物大分子引发剂的聚噻吩大分子引发剂和至少一种二乙烯基单体以制备聚噻吩星型共聚物。 根据本发明能够通过外部刺激自掺杂的聚噻吩星形共聚物是用于稳定地增加导电性的自掺杂材料，并且可以用作导电膜的材料。

公开(公告)号：US09908979B2

公开(公告)日：2018-03-06

申请号：US14395108

申请日：2013-03-15

Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

Inventor： Kyung Youl Baek ,  Seung Sang Hwang ,  Soon Man Hong ,  Min Jae Ko ,  Yun Jae Lee ,  Hyun Ji Kim ,  Hyeon Yeol Jeon ,  Chong Min Koo

IPC: C08J3/24 ,  C08G61/12 ,  C09D165/00 ,  H01L51/00

CPC classification number: C08J3/246 ,  C08G61/126 ,  C08G2261/131 ,  C08G2261/1412 ,  C08G2261/1452 ,  C08G2261/3223 ,  C08G2261/354 ,  C08G2261/51 ,  C08G2261/74 ,  C08J2365/00 ,  C09D165/00 ,  H01L51/0036 ,  H01L51/0043 ,  Y10T428/31533

Abstract: The present invention provides a method for producing polythiophene star copolymer capable of being self-doped by an external stimulus, which includes the steps of: forming a polythiophene macroinitiator made by introducing a living radical polymerizable functional group into an end of polythiophene or a derivative thereof; forming through living radical polymerization a polymer macroinitiator for providing by an external stimulus at least a dopant selected from the group consisting of sulfonic acid radical, carboxylic acid radical and phosphoric acid radical; and polymerizing the polythiophene macroinitiator added with the polymer macroinitiator and at least one kind of divinyl monomer to produce the polythiophene star copolymer. The polythiophene star copolymer capable of being self-doped by an external stimulus according to the present invention is a self-doped material to stably increase conductivity, and can be used as a material for a conductive film.