Abstract:
Disclosed are a pincer-type ligand having a structurally rigid acridane structure and a metal complex consisting of the pincer-type ligand and a metal bound to each other, and exhibiting high reactivity and stability during a variety of bonding activation reactions. T-shaped complexes can be prepared from acriPNP(4,5-bis(diisopropylphosphino)-2,7,9,9-tetramethyl-9H-acridin-10-ide), which is a pincer-type PNP ligand having an acridane structure, and metal complexes, which can be structurally rigid and thus exhibit excellent reactivity and stability based on minimized structural change thereof, can be prepared by introducing an acridane structure into the backbone thereof. The PNP ligand is structurally stable and has novel chemical properties, as compared to conventional similar ligands, and thus can be utilized in a wide range of catalytic reactions and material chemistry.
Abstract:
An organic light-emitting device includes: a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer, wherein the organic layer includes a condensed cyclic compound represented by Formula 1. An organic light-emitting device including the organometallic compound according to the embodiments of the present disclosure may have high efficiency: M(L1)(L2). Formula 1
Abstract:
An organometallic compound represented by ML1L2 and an organic light-emitting device including the same, wherein M may be selected from copper (Cu), cobalt (Co), and nickel (Ni), L1 may be selected from ligands represented by Formula 2, and L2 may be a monovalent organic ligand: When the organometallic compound represented by ML1L2 is used as a dopant in the emission layer of an organic light-emitting device, the organic light-emitting device may have low driving voltage and high quantum efficiency.
Abstract:
An organometallic complex represented by Formula 1-1 or Formula 1-2 is provided: wherein in Formulae 1-1 and 1-2, descriptions of R1 to R7, X1, X2, Y1 to Y4, rings A, B, C, and a to e are understood by referring to the description provided herein. An organic light-emitting device includes a first electrode, a second electrode facing the first electrode, and an organic layer that is disposed between the first electrode and the second electrode and includes an emission layer, wherein the organic layer includes at least one organometallic complex represented by Formula 1-1 or Formula 1-2.
Abstract:
Disclosed are a pincer-type ligand having a structurally rigid acridane structure and a metal complex consisting of the pincer-type ligand and a metal bound to each other, and exhibiting high reactivity and stability during a variety of bonding activation reactions. T-shaped complexes can be prepared from acriPNP(4,5-bis(diisopropylphosphino)-2,7,9,9-tetramethyl-9H-acrid in-10-ide), which is a pincer-type PNP ligand having an acridane structure, and metal complexes, which can be structurally rigid and thus exhibit excellent reactivity and stability based on minimized structural change thereof, can be prepared by introducing an acridane structure into the backbone thereof. The PNP ligand is structurally stable and has novel chemical properties, as compared to conventional similar ligands, and thus can be utilized in a wide range of catalytic reactions and material chemistry.
Abstract:
An organometallic complex represented by Formula 1-1 or Formula 1-2 is provided: wherein in Formulae 1-1 and 1-2, descriptions of R1 to R7, X1, X2, Y1 to Y4, rings A, B, C, and a to e are understood by referring to the description provided herein. An organic light-emitting device includes a first electrode, a second electrode facing the first electrode, and an organic layer that is disposed between the first electrode and the second electrode and includes an emission layer, wherein the organic layer includes at least one organometallic complex represented by Formula 1-1 or Formula 1-2.