摘要:
A recording element comprising a support having thereon an image-receiving layer, said recording element containing core-shell particles wherein said core comprises an inorganic or organic particle and said shell comprises an organosilane or a hydrolyzed organosilane derived from a compound having the formula: Si(OR)aZb wherein R is hydrogen, or a substituted or unsubstituted alkyl group having from 1 to about 20 carbon atoms or a substituted or unsubstituted aryl group having from about 6 to about 20 carbon atoms; Z is an alkyl group having from 1 to about 20 carbon atoms or aryl group having from about 6 to about 20 carbon atoms, with at least one of said Z's having at least one primary, secondary, tertiary or quaternary nitrogen atom; a is an integer from 1 to 3; and b is an integer from 1 to 3; with the proviso that a+b=4; and with the further proviso that the amount of organosilane shell material is such that Ratio R, which is the number of micromoles of organosilane used to shell the core particles to the total core particles' surface area (in m2), is greater than 10.
摘要:
A photographic element is described comprising a support bearing one or more hydrophilic colloid layers including at least one photographic silver halide emulsion layer, wherein a photographically useful compound is incorporated into at least one hydrophilic colloid layer in the form of an intercalation composition comprising a layered host material having molecules of the photographically useful compound inserted as guest molecules between the layers of the host material. The invention provide novels materials and a method of incorporating active chemistry compounds such as developers or development inhibitors directly into a photographic imaging element with improved stability and keeping response versus known methods for incorporating active chemistry compounds.
摘要:
The invention relates to a cationic shelled particle comprising a colloidal alumina core having a median diameter of between 20 and 2000 nm and a positive charge, a layer on the surface of said core particle having a negative charge and comprising particles of a median diameter of less than 30% of the median diameter of said core particle, and an outer layer of positive charge.
摘要:
The invention provides a dental curing device comprising a light source having a wavelength capable of inducing polymerization of a photopolymer, and a noncontact thermal detector in alignment with said light source and capable of measuring the temperature or temperature change of the photopolymer upon polymerization.
摘要:
The present invention relates to a system comprising photopolymerizable composites and an associated light polymerization device. The composite comprises a photopolymerizable resin and a luminophore, and optionally inorganic fillers and a photobleaching agent. The polymerization device comprises a light source and a photodetector. The composite and the device are coupled via a feedback loop to indicate the degree of polymerization, or to indicate that polymerization is complete. The invention relates to any photopolymerizable composite or coating including industrial, protective, biomedical and dental composites and coatings.
摘要:
The present invention discloses an ink printing method using an image-recording element, which provides an image having excellent image quality and superior dry time, comprising insoluble cationic core-shell polymeric particles each comprising a core comprising cationic core polymer having at least 10 mole percent of a cationic mordant monomeric unit and a shell comprising hydrophilic shell polymer that is substantially less cationic than the cationic core polymer, wherein the shell is at least 10% by weight of the core.
摘要:
A fluid container and method for inhibiting the growth of microbes in liquid nutrient in a container, the container having an interior surface having a metal-ion sequestering agent for removing a designated metal ion from the liquid nutrient for inhibiting growth of microbes in the liquid nutrient.
摘要:
A silver ion sequester and release agent is described which comprises a silver ion exchangeable material of the formula: M(H1−x−yAgxM′yPO4)2.nH2O; where M is Zr, Ti, Sn, Ge or Hf or any combination thereof; M′ is an Alkali or alkaline earth metal; x is a number from 0.10 to 0.80; y is a number from 0.15 to 0.85; (x+y) is a number from 0.25 to 0.95; and n is a rational number between 0 and 10. Processes for preparing such silver ion sequester and release agent material are also described comprising combining in an aqueous medium a crystalline or amorphous metal hydrogen phosphate ion exchange host material of the formula M(HPO4)2.nH2O with less than 2 molar equivalents of silver ions relative to the amount of ion exchange host material such that silver ions are exchanged for protons in the host material, and adding a base compound to the aqueous medium to achieve a pH of at least 4.4 and sequester at least 95% of the combined silver ions into the host material. Further described are photographic elements comprising a support bearing one or more hydrophilic colloid layers including at least one photographic silver halide emulsion layer, wherein one or more layers contain such a silver ion sequester and release agent which sequesters silver ions prior to photographic processing and releases silver ions upon exposure to photographic processing solutions.
摘要:
A radiation sensitive imaging element is described comprising a support bearing one or more hydrophilic colloid layers, wherein a photographically useful compound is incorporated into at least one hydrophilic colloid layer in the form of a self-assembled composition comprising a substantially homogeneous and ordered array of the photographically useful compound and silver and halide atoms, wherein the average minimum distance from each Ag atom in the composition to an atom of the photographically useful compound in the composition is less than 50 Å. In a particular embodiment, the self-assembled composition is of the general unit cell formula AgaXb(PUC*)c.nH2O where X represents halogen atoms selected from Cl, Br, and I or any combination thereof, and PUC* is a photographically useful compound containing at least one positively charged onium ion group; and wherein a is an integer from 1-10 and b is an integer from 2-18, with the proviso b is greater than a, and the silver and halide atoms form silver halide sublattice structures having a net negative charge; c is an integer such that the onium ion group containing photographically useful compound forms a positively-charged sublattice which stabilizes the negatively charged silver halide sublattice, wherein charge neutrality for the composition is upheld; and n is any number from 0 to 10. The invention provides novel materials and a method of incorporating active chemistry compounds such as developers or development inhibitors directly into a photographic imaging element. The invention further provide materials, and a method for preparing materials, comprising silver halide co-crystallized with photographic useful compound molecules thereby creating a unique crystal lattice. The invention described herein provides materials in which active chemistry and silver halide are present together in an ordered array, or crystal lattice, separated by distances measured on the atomic scale (i.e., in angstroms (Å), where 1 Å=10−4 &mgr;m).
摘要:
A color photographic element is disclosed comprised of a transparent film support and, coated on the support, a red recording layer unit containing the latent image forming silver halide grains in a plurality of emulsion layers with the latent image forming silver halide grains of maximum sensitivity being the first red recording emulsion layer to receive exposing radiation and containing randomly oriented red light scattering silver halide grains free of adsorbed spectral sensitizing dye. An optional layer coated beneath first layer contains tabular silver halide grains to reflect red light. Improvements in imaging speed with improvements or relatively low losses in image sharpness are realized.