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    Process for derivatizing carbon nanotubes with diazonium species
    1.
    发明授权
    Process for derivatizing carbon nanotubes with diazonium species 有权
    用重氮化物衍生碳纳米管的方法

    公开(公告)号：US07250147B2

    公开(公告)日：2007-07-31

    申请号：US10470517

    申请日：2002-01-29

    申请人： James M. Tour ,  Jeffrey L. Bahr ,  Jiping Yang

    发明人： James M. Tour ,  Jeffrey L. Bahr ,  Jiping Yang

    IPC分类号： D01F9/12

    CPC分类号： B82Y30/00 ,  B82Y40/00 ,  C01B32/174 ,  C01B2202/02 ,  C01B2202/06 ,  C01B2202/36 ,  C01P2002/72 ,  C01P2002/82 ,  C01P2002/84 ,  C01P2002/88 ,  C01P2004/04 ,  C01P2004/13 ,  C07C245/20 ,  C07C321/26 ,  C07C321/28 ,  C08K9/04 ,  C09C1/48 ,  C09C1/56 ,  C09C1/565 ,  H01G11/36 ,  Y02E60/13 ,  Y10S977/788 ,  Y10S977/847 ,  Y10T428/13 ,  Y10T428/30

    摘要： The invention incorporates new processes for the chemical modification of carbon nanotubes. Such processes involve the derivatization of multi- and single-wall carbon nanotubes, including small diameter (ca. 0.7 nm) single-wall carbon nanotubes, with diazonium species. The method allows the chemical attachment of a variety of organic compounds to the side and ends of carbon nanotubes. These chemically modified nanotubes have applications in polymer composite materials, molecular electronic applications and sensor devices. The methods of derivatization include electrochemical induced reactions thermally induced reactions (via in-situ generation of diazonium compounds or pre-formed diazonium compounds), and photochemically induced reactions. The derivatization causes significant changes in the spectroscopic properties of the nanotubes. The estimated degree of functionality is ca. 1 out of every 20 to 30 carbons in a nanotube bearing a functionality moiety. Such electrochemical reduction processes can be adapted to apply site-selective chemical functionalization of nanotubes. Moreover, when modified with suitable chemical groups, the derivatized nanotubes are chemically compatible with a polymer matrix, allowing transfer of the properties of the nanotubes (such as, mechanical strength or electrical conductivity) to the properties of the composite material as a whole. Furthermore, when modified with suitable chemical groups, the groups can be polymerized to form a polymer that includes carbon nanotubes

    摘要翻译： 本发明包括用于碳纳米管的化学改性的新方法。 这种方法涉及多壁碳纳米管和单壁碳纳米管的衍生，包括小直径（约0.7nm）的单壁碳纳米管与重氮物质。 该方法允许将各种有机化合物化学连接到碳纳米管的侧面和末端。 这些化学改性的纳米管可用于聚合物复合材料，分子电子应用和传感器装置。 衍生化的方法包括电化学诱导反应热诱导反应（通过原位产生重氮化合物或预形成的重氮化合物）和光化学诱导反应。 衍生化导致纳米管的光谱性质的显着变化。 估计功能的程度约为 在具有功能部分的纳米管中每20至30个碳中有1个。 这种电化学还原方法可适用于纳米管的位点选择性化学官能化。 此外，当用合适的化学基团改性时，衍生的纳米管与聚合物基质化学相容，允许将纳米管的性质（例如机械强度或电导率）转移到复合材料的整体性能上。 此外，当用合适的化学基团改性时，基团可以聚合形成包括碳纳米管的聚合物

    Process for derivatizing carbon nanotubes with diazonium species and compositions thereof
    2.
    发明授权
    Process for derivatizing carbon nanotubes with diazonium species and compositions thereof 有权
    用重氮化物衍生碳纳米管的方法及其组合物

    公开(公告)号：US07892517B2

    公开(公告)日：2011-02-22

    申请号：US11840433

    申请日：2007-08-17

    申请人： James M. Tour ,  Jeffrey L. Bahr ,  Jiping Yang

    发明人： James M. Tour ,  Jeffrey L. Bahr ,  Jiping Yang

    IPC分类号： D01F9/12

    CPC分类号： B82Y30/00 ,  B82Y40/00 ,  C01B32/174 ,  C01B2202/02 ,  C01B2202/06 ,  C01B2202/36 ,  C01P2002/72 ,  C01P2002/82 ,  C01P2002/84 ,  C01P2002/88 ,  C01P2004/04 ,  C01P2004/13 ,  C07C245/20 ,  C07C321/26 ,  C07C321/28 ,  C08K9/04 ,  C09C1/48 ,  C09C1/56 ,  C09C1/565 ,  H01G11/36 ,  Y02E60/13 ,  Y10S977/788 ,  Y10S977/847 ,  Y10T428/13 ,  Y10T428/30

    摘要： Methods for the chemical modification of carbon nanotubes involve the derivatization of multi- and single-wall carbon nanotubes, including small diameter (ca. 0.7 nm) single-wall carbon nanotubes, with diazonium species. The method allows the chemical attachment of a variety of organic compounds to the side and ends of carbon nanotubes. These chemically modified nanotubes have applications in polymer composite materials, molecular electronic applications, and sensor devices. The methods of derivatization include electrochemical induced reactions, thermally induced reactions, and photochemically induced reactions. Moreover, when modified with suitable chemical groups, the derivatized nanotubes are chemically compatible with a polymer matrix, allowing transfer of the properties of the nanotubes (such as, mechanical strength or electrical conductivity) to the properties of the composite material as a whole. Furthermore, when modified with suitable chemical groups, the groups can be polymerized to form a polymer that includes carbon nanotubes.

    摘要翻译： 用于碳纳米管的化学修饰的方法涉及包括小直径（约0.7nm）单壁碳纳米管与重氮物质的多壁和单壁碳纳米管的衍生化。 该方法允许将各种有机化合物化学连接到碳纳米管的侧面和末端。 这些化学改性的纳米管可用于聚合物复合材料，分子电子应用和传感器装置。 衍生化的方法包括电化学诱导反应，热诱导反应和光化学诱导反应。 此外，当用合适的化学基团改性时，衍生的纳米管与聚合物基质化学相容，允许将纳米管的性质（例如机械强度或电导率）转移到复合材料的整体性能上。 此外，当用合适的化学基团改性时，基团可以聚合形成包括碳纳米管的聚合物。

    PROCESS FOR DERIVATIZING CARBON NANOTUBES WITH DIAZONIUM SPECIES AND COMPOSITIONS THEREOF
    3.
    发明申请
    PROCESS FOR DERIVATIZING CARBON NANOTUBES WITH DIAZONIUM SPECIES AND COMPOSITIONS THEREOF 有权
    用二氧化碳衍生碳纳米管的方法及其组合物

    公开(公告)号：US20090301896A1

    公开(公告)日：2009-12-10

    申请号：US11840433

    申请日：2007-08-17

    申请人： James M. Tour ,  Jeffrey L. Bahr ,  Jiping Yang

    发明人： James M. Tour ,  Jeffrey L. Bahr ,  Jiping Yang

    IPC分类号： C25B3/00 ,  B82B3/00

    CPC分类号： B82Y30/00 ,  B82Y40/00 ,  C01B32/174 ,  C01B2202/02 ,  C01B2202/06 ,  C01B2202/36 ,  C01P2002/72 ,  C01P2002/82 ,  C01P2002/84 ,  C01P2002/88 ,  C01P2004/04 ,  C01P2004/13 ,  C07C245/20 ,  C07C321/26 ,  C07C321/28 ,  C08K9/04 ,  C09C1/48 ,  C09C1/56 ,  C09C1/565 ,  H01G11/36 ,  Y02E60/13 ,  Y10S977/788 ,  Y10S977/847 ,  Y10T428/13 ,  Y10T428/30

    摘要： Methods for the chemical modification of carbon nanotubes involve the derivatization of multi- and single-wall carbon nanotubes, including small diameter (ca. 0.7 nm) single-wall carbon nanotubes, with diazonium species. The method allows the chemical attachment of a variety of organic compounds to the side and ends of carbon nanotubes. These chemically modified nanotubes have applications in polymer composite materials, molecular electronic applications, and sensor devices. The methods of derivatization include electrochemical induced reactions, thermally induced reactions, and photochemically induced reactions. Moreover, when modified with suitable chemical groups, the derivatized nanotubes are chemically compatible with a polymer matrix, allowing transfer of the properties of the nanotubes (such as, mechanical strength or electrical conductivity) to the properties of the composite material as a whole. Furthermore, when modified with suitable chemical groups, the groups can be polymerized to form a polymer that includes carbon nanotubes.

    摘要翻译： 用于碳纳米管的化学修饰的方法涉及包括小直径（约0.7nm）单壁碳纳米管与重氮物质的多壁和单壁碳纳米管的衍生化。 该方法允许将各种有机化合物化学连接到碳纳米管的侧面和末端。 这些化学改性的纳米管可用于聚合物复合材料，分子电子应用和传感器装置。 衍生化的方法包括电化学诱导反应，热诱导反应和光化学诱导反应。 此外，当用合适的化学基团改性时，衍生的纳米管与聚合物基质化学相容，允许将纳米管的性质（例如机械强度或电导率）转移到复合材料的整体性能上。 此外，当用合适的化学基团改性时，基团可以聚合形成包括碳纳米管的聚合物。

    Carbon nanotubes derivatized with diazonium species
    5.
    发明授权
    Carbon nanotubes derivatized with diazonium species 有权
    用重氮化物衍生的碳纳米管

    公开(公告)号：US07691359B2

    公开(公告)日：2010-04-06

    申请号：US10632419

    申请日：2003-08-01

    申请人： James M. Tour ,  Jeffrey L. Bahr ,  Jiping Yang

    发明人： James M. Tour ,  Jeffrey L. Bahr ,  Jiping Yang

    IPC分类号： B82B1/00

    CPC分类号： B82Y30/00 ,  B82Y40/00 ,  C01B32/174 ,  C01B2202/02 ,  C01B2202/06 ,  C01B2202/36 ,  C01P2002/72 ,  C01P2002/82 ,  C01P2002/84 ,  C01P2002/88 ,  C01P2004/04 ,  C01P2004/13 ,  C07C245/20 ,  C07C321/26 ,  C07C321/28 ,  C08K9/04 ,  C09C1/48 ,  C09C1/56 ,  C09C1/565 ,  H01G11/36 ,  Y02E60/13 ,  Y10S977/788 ,  Y10S977/847 ,  Y10T428/13 ,  Y10T428/30

    摘要： The invention incorporates new processes for the chemical modification of carbon nanotubes. Such processes involve the derivatization of multi- and single-wall carbon nanotubes, including small diameter (ca. 0.7 nm) single-wall carbon nanotubes, with diazonium species. The method allows the chemical attachment of a variety of organic compounds to the side and ends of carbon nanotubes. These chemically modified nanotubes have applications in polymer composite materials, molecular electronic applications, and sensor devices. The methods of derivatization include electrochemical induced reactions, thermally induced reactions (via in-situ generation of diazonium compounds or pre-formed diazonium compounds), and photochemically induced reactions. The derivatization causes significant changes in the spectroscopic properties of the nanotubes. The estimated degree of functionality is ca. 1 out of every 20 to 30 carbons in a nanotube bearing a functionality moiety. Such electrochemical reduction processes can be adapted to apply site-selective chemical functionalization of nanotubes. Moreover, when modified with suitable chemical groups, the derivatized nanotubes are chemically compatible with a polymer matrix, allowing transfer of the properties of the nanotubes (such as, mechanical strength or electrical conductivity) to the properties of the composite material as a whole. Furthermore, when modified with suitable chemical groups, the groups can be polymerized to form a polymer that includes carbon nanotubes.

    摘要翻译： 本发明包括用于碳纳米管的化学改性的新方法。 这种方法涉及多壁碳纳米管和单壁碳纳米管的衍生，包括小直径（约0.7nm）的单壁碳纳米管与重氮物质。 该方法允许将各种有机化合物化学连接到碳纳米管的侧面和末端。 这些化学改性的纳米管可用于聚合物复合材料，分子电子应用和传感器装置。 衍生化的方法包括电化学诱导反应，热诱导反应（通过原位产生重氮化合物或预形成的重氮化合物）和光化学诱导反应。 衍生化导致纳米管的光谱性质的显着变化。 估计功能的程度约为 在具有功能部分的纳米管中每20至30个碳中有1个。 这种电化学还原方法可适用于纳米管的位点选择性化学官能化。 此外，当用合适的化学基团改性时，衍生的纳米管与聚合物基质化学相容，允许将纳米管的性质（例如机械强度或电导率）转移到复合材料的整体性能上。 此外，当用合适的化学基团改性时，基团可以聚合形成包括碳纳米管的聚合物。

    Process for making polymers comprising derivatized carbon nanotubes and compositions thereof
    6.
    发明授权
    Process for making polymers comprising derivatized carbon nanotubes and compositions thereof 有权
    制备包含衍生碳纳米管的聚合物及其组合物的方法

    公开(公告)号：US07304103B2

    公开(公告)日：2007-12-04

    申请号：US10632284

    申请日：2003-08-01

    申请人： James M. Tour ,  Jeffrey L. Bahr ,  Jiping Yang

    发明人： James M. Tour ,  Jeffrey L. Bahr ,  Jiping Yang

    IPC分类号： C08K3/04 ,  C08L23/06 ,  C08L23/12 ,  C08L25/06 ,  C08L63/00

    CPC分类号： B82Y30/00 ,  B82Y40/00 ,  C01B32/174 ,  C01B2202/02 ,  C01B2202/06 ,  C01B2202/36 ,  C01P2002/72 ,  C01P2002/82 ,  C01P2002/84 ,  C01P2002/88 ,  C01P2004/04 ,  C01P2004/13 ,  C07C245/20 ,  C07C321/26 ,  C07C321/28 ,  C08K9/04 ,  C09C1/48 ,  C09C1/56 ,  C09C1/565 ,  H01G11/36 ,  Y02E60/13 ,  Y10S977/788 ,  Y10S977/847 ,  Y10T428/13 ,  Y10T428/30

    摘要： The present invention incorporates new processes for blending derivatized carbon nanotubes into polymer matrices to create new polymer/composite materials. When modified with suitable chemical groups using diazonium chemistry, the nanotubes can be made chemically compatible with a polymer matrix, allowing transfer of the properties of the nanotubes (such as mechanical strength) to the properties of the composite material as a whole. To achieve this, the derivatized (modified) carbon nanotubes are physically blended with the polymeric material, and/or, if desired, allowed to react at ambient or elevated temperature. These methods can be utilized to append functionalities to the nanotubes that will further covalently bond to the host polymer matrix, or directly between two tubes themselves. Furthermore, the nanotubes can be used as a generator of polymer growth, wherein the nanotubes are derivatized with a functional group that is an active part of a polymerization process, which would also result in a composite material in which the carbon nanotubes are chemically involved.

    摘要翻译： 本发明包含将衍生的碳纳米管混合到聚合物基质中以产生新的聚合物/复合材料的新方法。 当用合适的化学基团使用重氮化学法进行改性时，纳米管可以与聚合物基质化学相容，允许将纳米管的性质（如机械强度）转移到复合材料的整体性能上。 为了实现这一点，衍生的（改性的）碳纳米管与聚合物材料物理共混，和/或如果需要，允许在环境温度或升高的温度下反应。 这些方法可以用于将功能性附加到纳米管上，该纳米管将进一步共价键合到主体聚合物基质，或直接在两个管本身之间。 此外，纳米管可以用作聚合物生长的发生器，其中纳米管用作为聚合方法的活性部分的官能团衍生，这也将导致碳纳米管化学参与的复合材料。

    Pretreatment method for coating
    8.
    发明授权
    Pretreatment method for coating 有权
    涂层预处理方法

    公开(公告)号：US08075708B2

    公开(公告)日：2011-12-13

    申请号：US10743387

    申请日：2003-12-23

    申请人： Masahiko Matsukawa ,  Kazuhiro Makino ,  Toshiaki Shimakura ,  Masanobu Futsuhara ,  Jiping Yang

    发明人： Masahiko Matsukawa ,  Kazuhiro Makino ,  Toshiaki Shimakura ,  Masanobu Futsuhara ,  Jiping Yang

    IPC分类号： C23C22/50

    CPC分类号： C23C22/34 ,  C23C2222/20

    摘要： It is an object of the present invention to provide a pretreatment method for coating, which does not limit a coating method, places a less burden on the environment and can apply good chemical conversion treatment to all metals such as iron, zinc, aluminum and so on.A pretreatment method for coating comprising treating a substance to be treated by a chemical conversion coating agent to form a chemical conversion coat,wherein the chemical conversion coating agent comprises: at least one kind selected from the group consisting of zirconium, titanium and hafnium; fluorine; and at least one kind selected from the group consisting of amino group-containing silane coupling agents, hydrolysates thereof and polymers thereof.

    摘要翻译： 本发明的目的是提供一种涂布方法，其不会限制涂布方法，对环境的负担较小，并且可以对诸如铁，锌，铝等所有金属进行良好的化学转化处理 上。 一种涂布预处理方法，包括用化学转化涂层剂处理待处理的物质以形成化学转化涂层，其中化学转化涂层剂包括：选自锆，钛和铪中的至少一种; 氟; 和选自由含氨基的硅烷偶联剂，其水解物和聚合物组成的组中的至少一种。