GLASS FIBER COMPOSITION, GLASS FIBER AND COMPOSITE MATERIAL THEREFROM

    公开(公告)号:US20170283309A1

    公开(公告)日:2017-10-05

    申请号:US15511582

    申请日:2014-12-29

    CPC classification number: C03C13/00 C03B37/075 C03C3/087 C03C3/091 C03C3/095

    Abstract: The present invention provides a glass fiber composition, glass fiber and composite material therefrom. The glass fiber composition comprises the following components expressed as percentage by weight: 56-64% SiO2, 12-18% Al2O3, 0.1-1% Na2O, 0.1-1% K2O, 0.1-1% Fe2O3, 0.05-1% Li2O+Bi2O3, 19-25% CaO+MgO+SrO, 0.1-1.5% TiO2 and 0-1% CeO2, wherein a weight percentage ratio C1=Li2O/Bi2O3 is greater than 1, and a weight percentage ratio C2=(MgO+SrO)/CaO is 0.4-1, and a weight percentage ratio C3=MgO/(MgO+SrO) is greater than 0.7. Said composition reduces the amount of bubbles, viscosity and crystallization risk of the glass, thereby making it more suitable for large-scale production with refractory-lined furnaces.

    HIGH MODULUS GLASS FIBRE COMPOSITION, AND GLASS FIBRE AND COMPOSITE MATERIAL THEREOF

    公开(公告)号:US20180179103A1

    公开(公告)日:2018-06-28

    申请号:US15738563

    申请日:2016-03-07

    CPC classification number: C03C13/00 C03C3/095 C03C2213/00

    Abstract: The present invention provides a high-modulus glass fiber composition, a glass fiber and a composite material therefrom. The glass fiber composition comprises the following components expressed as percentage by weight: 55-64% SiO2, 13-24% Al2O3, 0.1-6% Y2O3, 3.4-10.9% CaO, 8-14% MgO, lower than 22% CaO+MgO+SrO, lower than 2% Li2O+Na2O+K2O, lower than 2% TiO2, lower than 1.5% Fe2O3, 0-1.2% La2O3, wherein the range of the weight percentage ratio C1=(Li2O+Na2O+K2O)/(Y2O3+La2O3) is greater than 0.26. Said composition can significantly increase the glass elastic modulus, effectively inhibit the crystallization tendency of glass, decrease the liquidus temperature, secure a desirable temperature range (ΔT) for fiber formation and enhance the fining of molten glass, thus making it particularly suitable for production of high-modulus glass fiber with refractory-lined furnaces.

    LOW-DENSITY HIGH-PERFORMANCE GLASS FIBER COMPOSITION, GLASS FIBER AND COMPOSITE MATERIAL THEREOF

    公开(公告)号:US20240391821A1

    公开(公告)日:2024-11-28

    申请号:US18267682

    申请日:2023-04-10

    Abstract: The present disclosure provides a low-density high-performance glass fiber composition, and a glass fiber and a composite. The glass fiber composition comprises the following components expressed as percentage by weight: SiO2: 58.1%-61.9%, Al2O3: >19.8% and ≤23%, MgO: 9.6%-12.7%, CaO: 4.1%-7.9%, SrO+Li2O: 0.05%-2.2%, SrO: 0%-2%, Li2O: 0%-0.39%, Na2O: 0.05%-1.0%, R2O-Na2O+K2O+Li2O: 0.2%-1.6%, Fe2O3: 0.05%-1%, TiO2: 0.01%-2%, B2O3: 0%-2%, ZrO2: 0%-2%, and SiO2+Al2O3: 78%-84%. The components have a total content of greater than or equal to 98.5%; a weight percentage ratio C1=SiO2/(CaO+Li2O) is greater than or equal to 7.05, a weight percentage ratio C2=(R2O+SrO)/Al2O3 is greater than or equal to 0.012, and a weight percentage ratio C3=(MgO+SrO)/CaO is greater than or equal to 1.22. The glass fiber composition has the characteristics of low density and high modulus, and has higher specific modulus and specific strength, better lightweight level, and cost advantages.

    GLASS FIBER COMPOSITION, GLASS FIBER AND COMPOSITE MATERIAL THEREOF

    公开(公告)号:US20210206688A1

    公开(公告)日:2021-07-08

    申请号:US16073131

    申请日:2017-11-21

    Abstract: A composition for producing a glass fiber, including the following components with corresponding percentage amounts by weight: SiO2: 57.4-60.9%; Al2O3: greater than 17% and less than or equal to 19.8%; MgO: greater than 9% and less than or equal to 12.8%; CaO: 6.4-11.8%; SrO: 0-1.6%; Na2O+K2O: 0.1-1.1%; Fe2O3: 0.05-1%; TiO2: lower than 0.8%; and SiO2+Al2O3: lower than or equal to 79.4%. The total weight percentage of the above components in the composition is greater than 99%. The weight percentage ratio of Al2O3+MgO to SiO2 is between 0.43 and 0.56, and the weight percentage ratio of CaO+MgO to SiO2+Al2O3 is greater than 0.205. The composition can significantly increase the glass modulus, effectively reduce the glass crystallization rate, secure a desirable temperature range (ΔT) for fiber formation and enhance the refinement of molten glass, thus making it particularly suitable for high performance glass fiber production with refractory-lined furnaces.

    HIGH-MODULUS GLASS FIBER COMPOSITION, GLASS FIBER AND COMPOSITE MATERIAL THEREFROM

    公开(公告)号:US20190169066A1

    公开(公告)日:2019-06-06

    申请号:US16269379

    申请日:2019-02-06

    Abstract: The present invention provides a high-modulus glass fiber composition, a glass fiber and a composite material therefrom. The glass fiber composition comprises the following components expressed as percentage by weight: 55-64% SiO2, 13-24% Al2O3, 0.1-6% Y2O3, 3.4-10.9% CaO, 8-14% MgO, lower than 22% CaO+MgO+SrO, lower than 2% Li2O+Na2O+K2O, lower than 2% TiO2, lower than 1.5% Fe2O3, 0-1.2% La2O3, wherein the range of the weight percentage ratio C1=(Li2O+Na2O+K2O)/(Y2O3+La2O3) is greater than 0.26. Said composition can significantly increase the glass elastic modulus, effectively inhibit the crystallization tendency of glass, decrease the liquidus temperature, secure a desirable temperature range (ΔT) for fiber formation and enhance the fining of molten glass, thus making it particularly suitable for production of high-modulus glass fiber with refractory-lined furnaces.

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