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1.发明授权Process for producing synthetic fuel gas by reacting liquid hydrocarbons with hydrogen 失效通过使液体烃与氢气反应生产合成燃料气体的方法
公开(公告)号：US4302219A
公开(公告)日：1981-11-24
申请号：US213505
申请日：1980-12-05
CPC分类号： B01J35/10 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , C10G2400/26
摘要： Process for producing synthetic fuel gas from either naturally occurring or synthetic liquid hydrocarbons by reacting the liquid hydrocarbons with hydrogen in the presence of a catalyst to produce methane. The catalyst comprises an interspersed mixture of metals selected from Groups IV(B), V(B), or VI(B) in combination with two Group VIII metals, composited with an inorganic refractory oxide support.
摘要翻译： 通过在催化剂存在下使液态烃与氢气反应产生甲烷，从天然或合成液态烃生产合成燃料气体的方法。 该催化剂包含与IV族（B），V（B）或VI（B）组合的金属与两种与无机耐火氧化物载体复合的Ⅷ族金属的散置混合物。
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公开(公告)号：US4284531A
公开(公告)日：1981-08-18
申请号：US72662
申请日：1979-09-05
CPC分类号： B01J35/10 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , C10G2400/26
摘要： Methanation catalysts and process for preparing and using the same are disclosed; said methanation catalysts being especially suitable for producing synthetic fuel gas, from either naturally occurring liquid hydrocarbons or synthetic liquid hydrocarbons produced from solid carbonaceous materials, the product gas having substantially the same heating value and density as natural gas and which may be intermingled therewith and distributed through the same pipe lines.The methanation catalyst comprises an interspersed mixture of metals selected from Groups IV(B), V(B), VI(B) and VIII metals of the Periodic Table, composited with an inorganic refractory oxide support or matrix.
摘要翻译： 公开了甲烷化催化剂及其制备和使用方法; 所述甲烷化催化剂特别适用于从天然存在的液体烃或由固体碳质材料生产的合成液体烃生产合成燃料气体，所述产物气体具有与天然气基本上相同的热值和密度并且可以与天然气混合并分布 通过相同的管道。 甲烷化催化剂包含与无机难熔氧化物载体或基质复合的选自元素周期表IV（B），V（B），VI（B）和VIII族金属的金属的散置混合物。
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公开(公告)号：US4325936A
公开(公告)日：1982-04-20
申请号：US233888
申请日：1981-02-12
申请人： Hugh W. Gowdy , Donald M. Fenton
发明人： Hugh W. Gowdy , Donald M. Fenton
摘要： A hydrogen sulfide removal and conversion method in which a hydrogen sulfide-containing gas stream is contacted with a regenerable washing solution containing solubilized vanadium thiocyanate ions, a carboxylate complexing agent and one or more water-soluble quinones capable of solubilizing tetravalent vanadium. The molar ratio of vanadium to quinone(s) in the washing solution is selected to substantially reduce or eliminate the formation of contaminant sulfate salts. The absorbed hydrogen sulfide is converted to elemental sulfur which, after oxidative regeneration of the washing solution, is separated from the regenerated solution.
摘要翻译： 一种硫化氢去除和转化方法，其中使含硫化氢的气流与含有溶解的硫氰酸钒离子的可再生洗涤溶液，羧酸盐络合剂和能够溶解四价钒的一种或多种水溶性醌接触。 选择洗涤溶液中钒与醌的摩尔比以显着减少或消除硫酸盐污染物的形成。 将吸收的硫化氢转化为元素硫，其在洗涤溶液的氧化再生后与再生溶液分离。
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公开(公告)号：US4530752A
公开(公告)日：1985-07-23
申请号：US622638
申请日：1984-06-20
摘要： Oil shale solids are pyrolyzed or retorted by contact with a non-oxidizing recycle gas in a first retorting zone to produce an effluent containing pyrolysis products and pyrolyzed oil shale solids. Liquid and gaseous product hydrocarbons are recovered from the effluent of the first retorting zone. The pyrolyzed oil shale solids are contacted with an oxygen-containing gas in a combustion zone under conditions such that at least a portion of the organic material in the pyrolyzed solids is burned to produce hot, decarbonized solids and a hot flue gas. At least a portion of the gases in the effluent from the first retorting zone is contacted in the substantial absence of molecular oxygen with a portion of the hot, decarbonized solids produced in the combustion zone in the presence of added hydrocarbon-containing fines, preferably oil shale fines, in a second retorting zone such that the gases are heated and the fines are pyrolyzed to produce pyrolyzed fines and pyrolysis products containing gases and vapors. The gases and vapors in the effluent from the second retorting zone are then recycled to the first retorting zone where they serve as the hot, non-oxidizing recycle gas.
摘要翻译： 油页岩固体通过与第一蒸馏区中的非氧化循环气体接触而被热解或蒸馏以产生含有热解产物和热解油页岩固体的流出物。 从第一蒸煮区的流出物回收液态和气态产物烃。 在使得热解固体中的至少一部分有机材料燃烧以产生热脱碳固体和热烟道气的条件下，使热解油页岩固体与燃烧区中的含氧气体接触。 在基本不存在分子氧的情况下，来自第一蒸馏区的流出物中的至少一部分气体在燃烧区中产生的一部分热的脱碳固体在加入的含烃微粒存在下接触，优选为油 页岩细碎在第二个蒸煮区，使得气体被加热并且细粉被热解以产生含有气体和蒸气的热解的细粉和热解产物。 然后将来自第二蒸馏区的流出物中的气体和蒸气再循环到第一蒸馏区，在那里它们用作热的非氧化循环气体。
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5.发明授权Method for improving the long-term stability of H.sub.2 S absorption-oxidation process solutions 失效改善H2S吸收 - 氧化工艺溶液长期稳定性的方法
公开(公告)号：US5102635A
公开(公告)日：1992-04-07
申请号：US244180
申请日：1988-09-14
申请人： Dennis D. Delaney , Hugh W. Gowdy
发明人： Dennis D. Delaney , Hugh W. Gowdy
CPC分类号： B01D53/1468 , B01D53/1437 , C01B17/05 , C01B17/168
摘要： The long term stability of process solutions used in H.sub.2 S-to-sulfur absorption/oxidation process, wherein the incoming hydrogen sulfide-containing gas stream is contaminated with hydrocarbons and/or organic oxygenated compounds and the process is generating an excessive amount of thiosulfate in the process solution, is improved by a method comprising contacting the gas stream and/or the process solution with charcoal to remove both the contamination and at least a portion of the thiosulfate therefrom.
摘要翻译： 用于H2S-硫吸收/氧化过程的工艺溶液的长期稳定性，其中进入的含硫化氢的气流被烃和/或有机氧化的化合物污染，并且该过程产生过量的硫代硫酸盐 工艺溶液通过包括使气体流和/或处理溶液与木炭接触的方法得到改进，以从其中除去污染物和至少一部分硫代硫酸盐。
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6.发明授权
公开(公告)号：US4892723A
公开(公告)日：1990-01-09
申请号：US243460
申请日：1988-09-12
申请人： Dennis D. Delaney , Hugh W. Gowdy
发明人： Dennis D. Delaney , Hugh W. Gowdy
CPC分类号： C01B17/168 , B01D53/1437 , B01D53/1468 , C01B17/05
摘要： The long term stability of process solutions used in H.sub.2 S-to-sulfur absorption/oxidation process, wherein the incoming hydrogen sulfide-containing gas stream is contaminated with hydrocarbons and/or organic oxygenated compounds and the process is generating an excessive amount of thiosulfate in the process solution, is improved by a method comprising contacting the gas stream and/or the process solution with charcoal to remove both the contamination and at least a portion of the thiosulfate therefrom.
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公开(公告)号：US4432962A
公开(公告)日：1984-02-21
申请号：US433027
申请日：1982-10-06
申请人： Hugh W. Gowdy , Donald M. Fenton
发明人： Hugh W. Gowdy , Donald M. Fenton
摘要： A hydrogen sulfide removal and conversion method in which a hydrogen sulfide-containing gas stream is contacted with a regenerable washing solution having a pH between about 5 and about 10 and containing solubilized vanadium, thiocyanate ions, a carboxylate complexing agent, one or more water-soluble quinones and one or more water-soluble nonquinone aromatic compounds capable of solubilizing tetravalent vanadium. The absorbed hydrogen sulfide is converted to elemental sulfur which, after oxidative regeneration of the washing solution, is separated from the regenerated solution.
摘要翻译： 一种硫化氢去除和转化方法，其中使含硫化氢的气流与pH约5至约10的可再生洗涤溶液接触，并含有溶解的钒，硫氰酸根离子，羧酸酯络合剂，一种或多种水溶性聚合物， 可溶性醌和一种或多种能够溶解四价钒的水溶性非醌芳族化合物。 将吸收的硫化氢转化为元素硫，其在洗涤溶液的氧化再生后与再生溶液分离。
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公开(公告)号：US4283379A
公开(公告)日：1981-08-11
申请号：US50192
申请日：1979-06-20
申请人： Donald M. Fenton , Hugh W. Gowdy
发明人： Donald M. Fenton , Hugh W. Gowdy
摘要： A hydrogen sulfide removal and conversion method in which a hydrogen sulfide-containing gas stream is contacted with a substantially quinone-free aqueous washing solution containing, inter alia, solubilized vanadium, thiocyanate ions, and one or more water-soluble nonquinone aromatic compounds capable of solubilizing tetravalent vanadium. The absorbed hydrogen sulfide is converted to elemental sulfur which, after oxidative regeneration of the washing solution, is separated from the regenerated solution.
摘要翻译： 一种硫化氢去除和转化方法，其中使含硫化氢的气流与基本上无醌的含水洗涤溶液接触，该洗涤溶液尤其包含溶解的钒，硫氰酸根离子和一种或多种水溶性非醌芳族化合物，其能够 溶解四价钒。 将吸收的硫化氢转化为元素硫，其在洗涤溶液的氧化再生后与再生溶液分离。
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