公开(公告)号：US08048948B2

公开(公告)日：2011-11-01

申请号：US12118677

申请日：2008-05-09

申请人： Hiroshi Shimizu ,  Yongjin Li ,  Li Zhao

发明人： Hiroshi Shimizu ,  Yongjin Li ,  Li Zhao

IPC分类号： C08K3/34 ,  C08L67/04

CPC分类号： B29B7/90 ,  B29B7/14

摘要： A melt-kneading method for filling material-containing resin or elastomer includes: a step of preparing a filling material as a filler and a resin or elastomer comprising an incompatible blend; and a step of introducing the filling material-containing resin or elastomer into a material feed part provided at an end of a cylindrical melt-kneading part having a heater and provided with a screw, and then melt-kneading the filling material-containing resin or elastomer under conditions where the rotation speed of the screw is about 600 rpm to about 3,000 rpm and its shear rate is about 900 to about 4,500 sec−1, thereby forming a co-continuous structure comprising the incompatible blend.

摘要翻译： 用于填充含材料的树脂或弹性体的熔融捏合方法包括：制备作为填料的填充材料的步骤和包含不相容的共混物的树脂或弹性体; 以及将含有填充材料的树脂或弹性体引入设置在具有加热器的圆筒形熔融混炼部件的端部的材料供给部分中，并且设置有螺杆，然后将含有填充材料的树脂或 弹性体，其中螺杆的旋转速度为约600rpm至约3,000rpm，其剪切速率为约900至约4,500sec -1，由此形成包含不相容共混物的共连续结构。

公开(公告)号：US07935417B2

公开(公告)日：2011-05-03

申请号：US12028213

申请日：2008-02-08

申请人： Hiroshi Shimizu ,  Yongjin Li

发明人： Hiroshi Shimizu ,  Yongjin Li

IPC分类号： B32B5/16 ,  B29B7/90

CPC分类号： C08J3/201 ,  C08J3/005 ,  C08J2321/00 ,  C08J2327/16 ,  Y10S977/742 ,  Y10S977/773 ,  Y10T428/25

摘要： A melt-kneading method for filling material and elastomer or resin, characterized in that a filling material constituted by a filler, and an elastomer or resin (thermoplastic resin or thermosetting resin), are introduced from a material introduction part at the end of a melt-kneading part having a cylinder with a screw and a heater, and the molten elastomer or resin and filling material constituted by a filler are kneaded under the conditions of 1000 to 3000 rpm in the rotation speed of the screw and 1500 to 4500 sec−1 in shear speed to feed the mixture from the rear edge to tip of the screw to be trapped in a space provided at the tip of the screw, after which the mixture is moved from the space to the rear edge of the screw through a hole provided at the center of the screw, with the cycle process performed for a specified period based on recirculation using the screw.

摘要翻译： 一种用于填充材料和弹性体或树脂的熔融捏合方法，其特征在于，由填料构成的填充材料和弹性体或树脂（热塑性树脂或热固性树脂）在熔体末端的材料导入部分引入 - 具有螺杆和加热器的圆筒的中空部件和由填料构成的熔融弹性体或树脂和填充材料在螺杆的旋转速度为1000〜3000rpm的条件下混炼，并且在1500〜4500秒-1 在剪切速度下将混合物从后边缘到螺杆的尖端进入，以将其捕获在设置在螺钉尖端处的空间中，之后混合物通过提供的孔从螺钉的空间移动到后边缘 在螺杆的中心处，循环过程基于使用螺杆的循环进行一段指定的时间段。

公开(公告)号：US09199393B2

公开(公告)日：2015-12-01

申请号：US13147925

申请日：2010-02-02

申请人： Hiroshi Shimizu ,  Yongjin Li ,  Yukio Yoshizawa ,  Takayuki Takahashi ,  Ken-ichi Toyoshima

发明人： Hiroshi Shimizu ,  Yongjin Li ,  Yukio Yoshizawa ,  Takayuki Takahashi ,  Ken-ichi Toyoshima

IPC分类号： B29B7/28 ,  B29B7/14 ,  B29B7/88

CPC分类号： B29B7/28 ,  B29B7/14 ,  B29B7/88

摘要： A high-shear melt-kneader includes a high-shear unit (20) having an internal feedback-type screw (23) configured to apply high-shear stress to a melted resin, resin pressure sensors (33) for configured to detect a front portion resin pressure in the vicinity of an inlet of the internal feedback-type screw and a rear portion resin pressure in the vicinity of an outlet, and a control device configured to appropriately control a material supplying amount, a material temperature, a kneading time, and a screw rotation speed according to pressure values detected by the sensors. The control device controls the conditions such that waveforms with the lapse of time of the front and rear portion resin pressures are similar to each other and show variation to a steady state after formation of a predetermined peak value, and the front and rear portion resin pressures form a predetermined pressure difference with the lapse of time. According to the high-shear melt-kneader, it is possible to improve high-shear efficiency, increase precision of nano dispersion of a material, and stably and finely disperse/mix internal structures of immiscible polymer blend-based, polymer/filler-based and polymer blend/filler-based materials to a nano level.

摘要翻译： 高剪切熔融捏合机包括具有内部反馈型螺杆（23）的高剪切单元（20），该内部反馈型螺杆（23）被配置为向熔融树脂施加高剪切应力;树脂压力传感器（33），用于检测前端 在内反馈型螺杆的入口附近的部分树脂压力和出口附近的后部树脂压力，以及控制装置，其被配置为适当地控制材料供给量，材料温度，混炼时间， 以及根据由传感器检测的压力值的螺杆转速。 控制装置控制使得前后树脂压力经过时间的波形彼此相似的条件，并且在形成预定峰值之后显示到稳定状态的变化，并且前部和后部树脂压力 随着时间的流逝形成预定的压力差。 根据高剪切熔融捏合机，可以提高高剪切效率，提高材料的纳米分散体的精度，并且可以稳定和细分散/混合不混溶聚合物共混物，基于聚合物/填料的内部结构 和聚合物共混物/填料基材料达到纳米级。

公开(公告)号：US08937126B2

公开(公告)日：2015-01-20

申请号：US13127530

申请日：2009-11-05

申请人： Hiroshi Shimizu ,  Yongjin Li

发明人： Hiroshi Shimizu ,  Yongjin Li

IPC分类号： C08L33/08 ,  C08L33/10 ,  C08L69/00 ,  C08G64/02 ,  C08J3/00 ,  C08G64/32 ,  C08L25/02 ,  C08L67/00

CPC分类号： C08G64/32 ,  C08J3/005 ,  C08J2369/00 ,  C08L25/02 ,  C08L33/10 ,  C08L67/00 ,  C08L69/00 ,  C08L2666/02 ,  C08L2666/04

摘要： Disclosed is a novel ternary aliphatic polycarbonate blend derived from carbon dioxide, which is mainly composed of an aliphatic polycarbonate. Also disclosed is a process for producing the ternary aliphatic polycarbonate blend. A methacrylic resin or an aliphatic polyester is incorporated, as a second component, into an aliphatic polycarbonate to produce a blend, and a vinyl resin is added, as a third component, to the blend at a specified ratio, thereby producing a novel ternary aliphatic polycarbonate blend derived from carbon dioxide and having excellent mechanical properties that cannot be achieved by binary blends.

摘要翻译： 公开了一种由二氧化碳衍生的新型三元脂肪族聚碳酸酯共混物，其主要由脂肪族聚碳酸酯构成。 还公开了一种生产三元脂族聚碳酸酯共混物的方法。 将甲基丙烯酸系树脂或脂肪族聚酯作为第二成分加入到脂肪族聚碳酸酯中以制备共混物，并以特定比例将乙烯基树脂作为第三成分添加到共混物中，从而制备新颖的三元脂族 衍生自二氧化碳的聚碳酸酯共混物具有优异的机械性能，不能通过二元共混物实现。

公开(公告)号：US20080318318A1

公开(公告)日：2008-12-25

申请号：US12118677

申请日：2008-05-09

申请人： Hiroshi Shimizu ,  Yongjin Li ,  Li Zhao

发明人： Hiroshi Shimizu ,  Yongjin Li ,  Li Zhao

IPC分类号： C12N5/02

CPC分类号： B29B7/90 ,  B29B7/14

摘要： A melt-kneading method for filling material-containing resin or elastomer includes: a step of preparing a filling material as a filler and a resin or elastomer comprising an incompatible blend; and a step of introducing the filling material-containing resin or elastomer into a material feed part provided at an end of a cylindrical melt-kneading part having a heater and provided with a screw, and then melt-kneading the filling material-containing resin or elastomer under conditions where the rotation speed of the screw is about 600 rpm to about 3,000 rpm and its shear rate is about 900 to about 4,500 sec−1, thereby forming a co-continuous structure comprising the incompatible blend.

摘要翻译： 用于填充含材料的树脂或弹性体的熔融捏合方法包括：制备作为填料的填充材料的步骤和包含不相容的共混物的树脂或弹性体; 以及将含有填充材料的树脂或弹性体引入设置在具有加热器的圆筒形熔融混炼部件的端部的材料供给部分中，并且设置有螺杆，然后将含有填充材料的树脂或 弹性体，其中螺杆的旋转速度为约600rpm至约3,000rpm，其剪切速率为约900至约4,500sec -1，由此形成包含不相容共混物的共连续结构。

公开(公告)号：US08415423B2

公开(公告)日：2013-04-09

申请号：US13014570

申请日：2011-01-26

申请人： Hiroshi Shimizu ,  Yongjin Li

发明人： Hiroshi Shimizu ,  Yongjin Li

IPC分类号： B32B5/16 ,  B29B7/90

CPC分类号： C08J3/201 ,  C08J3/005 ,  C08J2321/00 ,  C08J2327/16 ,  Y10S977/742 ,  Y10S977/773 ,  Y10T428/25

摘要： A melt-kneaded product includes: a disperse medium selected from an a rubber, elastomer, thermoplastic resin, or thermosetting resin; and a filling material constituted by nano-size filler particles having a mutually aggregating nature, said nano-size filler particles being uniformly dispersed in the disperse medium.

摘要翻译： 熔融捏合产物包括：选自橡胶，弹性体，热塑性树脂或热固性树脂的分散介质; 以及由具有相互聚集性质的纳米尺寸填料颗粒构成的填充材料，所述纳米尺寸填料颗粒均匀地分散在分散介质中。

公开(公告)号：US08349953B2

公开(公告)日：2013-01-08

申请号：US11505288

申请日：2006-08-17

申请人： Hiroshi Shimizu ,  Yongjin Li ,  Toshiyuki Imoto

发明人： Hiroshi Shimizu ,  Yongjin Li ,  Toshiyuki Imoto

IPC分类号： C08K3/34 ,  C08L67/04 ,  C08L77/00

CPC分类号： B29B7/42 ,  B29C47/385 ,  B29C47/6087 ,  B29C47/661 ,  C08L27/16 ,  C08L67/02 ,  C08L67/04 ,  C08L69/00 ,  C08L2666/04

摘要： The invention provides a method of obtaining a compatible resin blend from at least two incompatible resins which are not conventionally blended with each other. The blend of an incompatible resins is dissolved at a molecular level by being melted and sheared under a high shearing rate by rotating a screw without adding a compatibilizer or the like.

摘要翻译： 本发明提供从至少两种不相容的树脂获得相容性树脂共混物的方法，所述不相容树脂通常不彼此混合。 不相容树脂的混合物通过在不添加增容剂等的情况下旋转螺杆而以高剪切速率熔融和剪切而以分子水平溶解。

公开(公告)号：US20120053282A1

公开(公告)日：2012-03-01

申请号：US13127530

申请日：2009-11-05

申请人： Hiroshi Shimizu ,  Yongjin Li

发明人： Hiroshi Shimizu ,  Yongjin Li

IPC分类号： C08L69/00 ,  C08K3/36 ,  C08J3/00 ,  C08K3/34

CPC分类号： C08G64/32 ,  C08J3/005 ,  C08J2369/00 ,  C08L25/02 ,  C08L33/10 ,  C08L67/00 ,  C08L69/00 ,  C08L2666/02 ,  C08L2666/04

摘要： Disclosed is a novel ternary aliphatic polycarbonate blend derived from carbon dioxide, which is mainly composed of an aliphatic polycarbonate. Also disclosed is a process for producing the ternary aliphatic polycarbonate blend.A methacrylic resin or an aliphatic polyester is incorporated, as a second component, into an aliphatic polycarbonate to produce a blend, and a vinyl resin is added, as a third component, to the blend at a specified ratio, thereby producing a novel ternary aliphatic polycarbonate blend derived from carbon dioxide and having excellent mechanical properties that cannot be achieved by binary blends.

摘要翻译： 公开了一种由二氧化碳衍生的新型三元脂肪族聚碳酸酯共混物，其主要由脂肪族聚碳酸酯构成。 还公开了一种生产三元脂族聚碳酸酯共混物的方法。 将甲基丙烯酸系树脂或脂肪族聚酯作为第二成分加入到脂肪族聚碳酸酯中以制备共混物，并以特定比例将乙烯基树脂作为第三成分添加到共混物中，从而制备新颖的三元脂族 衍生自二氧化碳的聚碳酸酯共混物具有优异的机械性能，不能通过二元共混物实现。

公开(公告)号：US20110292756A1

公开(公告)日：2011-12-01

申请号：US13147925

申请日：2010-02-02

申请人： Hiroshi Shimizu ,  Yongjin Li ,  Yukio Yoshizawa ,  Takayuki Takahashi ,  Ken-ichi Toyoshima

发明人： Hiroshi Shimizu ,  Yongjin Li ,  Yukio Yoshizawa ,  Takayuki Takahashi ,  Ken-ichi Toyoshima

IPC分类号： B29B7/82

CPC分类号： B29B7/28 ,  B29B7/14 ,  B29B7/88

摘要： A high-shear melt-kneader includes a high-shear unit (20) having an internal feedback-type screw (23) configured to apply high-shear stress to a melted resin, resin pressure sensors (33) for configured to detect a front portion resin pressure in the vicinity of an inlet of the internal feedback-type screw and a rear portion resin pressure in the vicinity of an outlet, and a control device configured to appropriately control a material supplying amount, a material temperature, a kneading time, and a screw rotation speed according to pressure values detected by the sensors. The control device controls the conditions such that waveforms with the lapse of time of the front and rear portion resin pressures are similar to each other and show variation to a steady state after formation of a predetermined peak value, and the front and rear portion resin pressures form a predetermined pressure difference with the lapse of time. According to the high-shear melt-kneader, it is possible to improve high-shear efficiency, increase precision of nano dispersion of a material, and stably and finely disperse/mix internal structures of immiscible polymer blend-based, polymer/filler-based and polymer blend/filler-based materials to a nano level.

摘要翻译： 高剪切熔融捏合机包括具有内部反馈型螺杆（23）的高剪切单元（20），该内部反馈型螺杆（23）被配置为向熔融树脂施加高剪切应力;树脂压力传感器（33），用于检测前端 在内反馈型螺杆的入口附近的部分树脂压力和出口附近的后部树脂压力，以及控制装置，其被配置为适当地控制材料供给量，材料温度，混炼时间， 以及根据由传感器检测的压力值的螺杆转速。 控制装置控制使得前后树脂压力经过时间的波形彼此相似的条件，并且在形成预定峰值之后显示到稳定状态的变化，并且前部和后部树脂压力 随着时间的流逝形成预定的压力差。 根据高剪切熔融捏合机，可以提高高剪切效率，提高材料的纳米分散体的精度，并且可以稳定和细分散/混合不混溶聚合物共混物，基于聚合物/填料的内部结构 和聚合物共混物/填料基材料达到纳米级。

公开(公告)号：US20100283000A1

公开(公告)日：2010-11-11

申请号：US12667769

申请日：2008-07-07

申请人： Hiroshi Shimizu ,  Yongjin Li

发明人： Hiroshi Shimizu ,  Yongjin Li

IPC分类号： C08L77/00 ,  C08K3/34 ,  C08K5/541 ,  C08K3/22 ,  H01B1/12 ,  H01B1/20 ,  H01B1/24 ,  C09K5/00 ,  H01M4/88

CPC分类号： B29B7/42 ,  B29C48/397 ,  B29C48/82 ,  B29C48/845 ,  B29C48/92 ,  C08K3/04 ,  C08K3/041 ,  C08K7/26 ,  C08L27/16 ,  C08L77/00 ,  C08L77/02 ,  C08L101/00 ,  H01M4/8652 ,  H01M8/0213 ,  H01M8/0215 ,  H01M8/0221 ,  H01M8/0226 ,  Y02P70/56 ,  C08L2666/22 ,  C08L2666/04

摘要： The present invention provides a novel structure in which a filling material that is a filler is dispersed in an incompatible resin selected from a thermoplastic resin or a thermosetting resin and/or an incompatible elastomer; and use of the novel structure. In a cocontinuous structure formed from a binary system that is selected from an incompatible resin selected from a thermoplastic resin or a thermosetting resin and/or an incompatible elastomer, a filling material that is a filler is dispersed selectively and uniformly in one of the incompatible resin selected from the thermoplastic resin or the thermosetting resin and/or the incompatible elastomer. The structure is obtained by putting the filling material and the resin and/or the elastomer in a cylinder having a screw through a put-in part provided at an end of a melt-kneading part having a heating part; processing the resin or elastomer under the conditions where a rotation speed of the screw is 100 rpm to 3000 rpm and a shear rate is 150 to 4500 sec−1; confining the resin or elastomer in a gap at a front end of the screw; and conducting circulation of moving the resin or elastomer from the gap to a rear end of the screw.

摘要翻译： 本发明提供了一种新型结构，其中作为填料的填充材料分散在选自热塑性树脂或热固性树脂和/或不相容弹性体的不相容树脂中; 并使用新颖的结构。 在由选自热塑性树脂或热固性树脂和/或不相容弹性体的不相容树脂的二元系统形成的共连续结构中，作为填料的填充材料选择性均匀地分散在不相容的树脂之一中 选自热塑性树脂或热固性树脂和/或不相容的弹性体。 通过将填充材料和树脂和/或弹性体放入具有螺杆的圆筒中，通过设置在具有加热部分的熔融捏合部分的端部的插入部分来获得该结构， 在螺杆的转速为100rpm〜3000rpm，剪切速度为150〜4500sec -1的条件下进行树脂或弹性体的加工; 将树脂或弹性体限制在螺杆前端的间隙中; 并且使所述树脂或弹性体从所述间隙移动到所述螺杆的后端的循环。