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公开(公告)号:US11104823B2
公开(公告)日:2021-08-31
申请号:US15783038
申请日:2017-10-13
Applicant: HENKEL AG & CO. KGAA
Inventor: Donald Robb Vonk , Thomas Sullivan Smith, II , Alvaro Bobadilla
Abstract: Anti-corrosion metal pretreatment compositions comprising a Group IVB metal, a Group IB metal and polyamidoamine polymers; replenisher compositions for the metal pretreatment compositions; methods of making the metal pretreatment compositions; methods of forming an anti-corrosion Group IVB oxide coating on at least one metal substrate surface by contacting the surface with the metal pretreatment composition; and coated metal substrates having anti-corrosion coatings deposited on the metal substrates from chrome VI free, anti-corrosion metal pretreatment compositions having enhanced corrosion resistance of the Group IVB metal oxide coatings and adhesion of the anti-corrosion and primer coating layers to metal substrates.
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公开(公告)号:US20180037770A1
公开(公告)日:2018-02-08
申请号:US15783038
申请日:2017-10-13
Applicant: HENKEL AG & CO. KGAA
Inventor: Donald Robb Vonk , Thomas Sullivan Smith, II , Alvaro Bobadilla
IPC: C09D177/08 , C23C22/34 , C09D5/08
Abstract: Anti-corrosion metal pretreatment compositions comprising a Group IVB metal, a Group IB metal and polyamidoamine polymers; replenisher compositions for the metal pretreatment compositions; methods of making the metal pretreatment compositions; methods of forming an anti-corrosion Group IVB oxide coating on at least one metal substrate surface by contacting the surface with the metal pretreatment composition; and coated metal substrates having anti-corrosion coatings deposited on the metal substrates from chrome VI free, anti-corrosion metal pretreatment compositions having enhanced corrosion resistance of the Group IVB metal oxide coatings and adhesion of the anti-corrosion and primer coating layers to metal substrates.
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公开(公告)号:US20210388231A1
公开(公告)日:2021-12-16
申请号:US17461100
申请日:2021-08-30
Applicant: Henkel AG & Co. KGaA
Inventor: Donald Robb Vonk , Thomas Sullivan Smith, II , Alvaro Bobadilla
IPC: C09D177/08 , C09D5/08 , C23C22/34
Abstract: Anti-corrosion metal pretreatment compositions comprising a Group IVB metal, a Group IB metal and polyamidoamine polymers; replenisher compositions for the metal pretreatment compositions; methods of making the metal pretreatment compositions; methods of forming an anti-corrosion Group IVB oxide coating on at least one metal substrate surface by contacting the surface with the metal pretreatment composition; and coated metal substrates having anti-corrosion coatings deposited on the metal substrates from chrome VI free, anti-corrosion metal pretreatment compositions having enhanced corrosion resistance of the Group IVB metal oxide coatings and adhesion of the anti-corrosion and primer coating layers to metal substrates.
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公开(公告)号:US20190292402A1
公开(公告)日:2019-09-26
申请号:US16437113
申请日:2019-06-11
Applicant: Henkel AG & Co. KGaA
Inventor: Donald Robb Vonk , Louis Patrick Rector
IPC: C09D179/02 , C23C22/82
Abstract: The corrosion resistance of conversion-coated metal substrate surfaces is further enhanced by treating such surfaces with aqueous mixtures of preformed reaction products obtained by reacting catechol compounds, such as dopamine or a dopamine salt, and functionalized co-reactant compounds, such as a polyethyleneimine.
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公开(公告)号:US12227668B2
公开(公告)日:2025-02-18
申请号:US16437072
申请日:2019-06-11
Applicant: Henkel AG & Co. KGaA
Inventor: Donald Robb Vonk , Louis Patrick Rector
IPC: C09D179/02 , B32B15/04 , B32B15/08 , C23C22/05 , C23C22/06 , C23C22/07 , C23C22/50 , C23C22/56 , C23C22/60 , C23C22/73 , C23C22/76 , C23C22/82 , C23F11/04
Abstract: The tendency of a bare metal surface to oxidize (e.g., flash-rust) may be alleviated by contacting the bare metal surface with an aqueous mixture of at least one preformed reaction product obtained by reaction of at least one catechol compound, such as dopamine or a salt thereof, with at least one co-reactant compound functionalized with one or more functional groups reactive with the at least one catechol compound, such as (meth)acryl, primary amino, secondary amino, thiol and/or hydroxyl groups, with polyethyleneimine being an example of a suitable co-reactant compound. Such a rinsing procedure does not interfere with subsequent conversion coating of the metal surface.
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公开(公告)号:US20220364240A1
公开(公告)日:2022-11-17
申请号:US17815607
申请日:2022-07-28
Applicant: Henkel AG & Co. KGaA
Inventor: Donald Robb Vonk , Brian J. Marvin , John L. Zimmerman
Abstract: Provided are bismuth conversion coating compositions that deposit bismuth conversion coatings on a variety of metal substrates, methods of making bismuth conversion coating compositions, methods of depositing bismuth conversion coatings on metal substrates and articles of manufacture having metal surfaces comprising a bismuth conversion coating.
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公开(公告)号:US20190292665A1
公开(公告)日:2019-09-26
申请号:US16437072
申请日:2019-06-11
Applicant: Henkel AG & Co. KGaA
Inventor: Donald Robb Vonk , Louis Patrick Rector
Abstract: The tendency of a bare metal surface to oxidize (e.g., flash-rust) may be alleviated by contacting the bare metal surface with an aqueous mixture of at least one preformed reaction product obtained by reaction of at least one catechol compound, such as dopamine or a salt thereof, with at least one co-reactant compound functionalized with one or more functional groups reactive with the at least one catechol compound, such as (meth)acryl, primary amino, secondary amino, thiol and/or hydroxyl groups, with polyethyleneimine being an example of a suitable co-reactant compound. Such a rinsing procedure does not interfere with subsequent conversion coating of the metal surface.
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公开(公告)号:US11891534B2
公开(公告)日:2024-02-06
申请号:US16437113
申请日:2019-06-11
Applicant: Henkel AG & Co. KGaA
Inventor: Donald Robb Vonk , Louis Patrick Rector
IPC: C09D179/02 , B32B15/04 , B32B15/08 , C23C22/05 , C23C22/06 , C23C22/50 , C23C22/56 , C23C22/60 , C23C22/73 , C23C22/76 , C23C22/82 , C23F11/04 , C08K5/105 , C09D133/00 , C09D5/00 , C09D7/63 , C23C22/34 , C23C22/48 , C23C22/53 , C23C22/78 , C23C22/83 , C23F11/173 , C08G73/02 , B05D7/00 , C23C22/07
CPC classification number: C09D179/02 , B32B15/04 , B32B15/08 , C23C22/05 , C23C22/06 , C23C22/07 , C23C22/50 , C23C22/56 , C23C22/60 , C23C22/73 , C23C22/82 , C23F11/04
Abstract: The corrosion resistance of conversion-coated metal substrate surfaces is further enhanced by treating such surfaces with aqueous mixtures of preformed reaction products obtained by reacting catechol compounds, such as dopamine or a dopamine salt, and functionalized co-reactant compounds, such as a polyethyleneimine.
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公开(公告)号:US11407921B2
公开(公告)日:2022-08-09
申请号:US16437008
申请日:2019-06-11
Applicant: Henkel AG & Co. KGaA
Inventor: Louis Patrick Rector , Donald Robb Vonk
IPC: C09D179/02 , B32B15/04 , B32B15/08 , C23C22/05 , C23C22/06 , C23C22/50 , C23C22/56 , C23C22/60 , C23C22/73 , C23C22/76 , C23C22/82 , C23F11/04
Abstract: An aqueous, acidic, anti-corrosion conversion coating composition (in particular, an aqueous, acidic Group IV metal-containing anti-corrosion conversion coating composition) for metal substrates comprising as an additive a catechol compound and/or the reaction products of at least one catechol compound and at least one co-reactant compound having one or more functional groups reactive with the at least one catechol compound, desirably the reaction product of a catechol and an polyamine (e.g., a polyethyleneimine), that enhances the anti-corrosion effects of the conversion coating composition; methods of making and applying the conversion coating compositions and coated metal substrates. The catechol-containing conversion coating composition can be applied to metal substrate surfaces at temperatures as low as below 40° C. and with exposure times of 5 minutes or less. The catechol compound or reaction product thereof can become incorporated into the conversion coating formed on the metal substrate.
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公开(公告)号:US20190301023A1
公开(公告)日:2019-10-03
申请号:US16437008
申请日:2019-06-11
Applicant: Henkel AG & Co. KGaA
Inventor: Louis Patrick Rector , Donald Robb Vonk
Abstract: An aqueous, acidic, anti-corrosion conversion coating composition (in particular, an aqueous, acidic Group IV metal-containing anti-corrosion conversion coating composition) for metal substrates comprising as an additive a catechol compound and/or the reaction products of at least one catechol compound and at least one co-reactant compound having one or more functional groups reactive with the at least one catechol compound, desirably the reaction product of a catechol and an polyamine (e.g., a polyethyleneimine), that enhances the anti-corrosion effects of the conversion coating composition; methods of making and applying the conversion coating compositions and coated metal substrates. The catechol-containing conversion coating composition can be applied to metal substrate surfaces at temperatures as low as below 40° C. and with exposure times of 5 minutes or less. The catechol compound or reaction product thereof can become incorporated into the conversion coating formed on the metal substrate.
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