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1.发明授权Additive and method for in situ surface modification of injection molded polymers 失效注塑聚合物的原位表面改性的添加剂和方法
公开(公告)号：US5820808A
公开(公告)日：1998-10-13
申请号：US784326
申请日：1997-01-16
CPC分类号： B29C45/0025 , B29C45/0013 , B29C2045/0015
摘要： A method for forming an injection molded component from a host polymer (18) uses a very small quantity of an additive (32) that is efficiently driven to the surface of the component during the injection molding process. The additive exists in the host polymer at a very low concentration in the bulk, much lower than would be necessary to achieve the modification in a homogeneous blend. The additive is an insoluble liquid in the host polymer under the temperature and pressure conditions of injection molding. The additive is driven to the flow front surface (22) during injection molding and then translated to the surface (24) of the component by fountain flow and is distributed on the surface in a thin layer, producing the desired surface modification, without altering the properties of the bulk polymer, and eliminating post processing steps from the manufacturing process.
摘要翻译： 从主体聚合物（18）形成注塑成分的方法使用非常少量的在注射成型过程中有效地驱动到部件表面的添加剂（32）。 该添加剂在本体中以非常低的浓度存在于主体聚合物中，远远低于在均匀共混物中实现改性所必需的。 在注射成型的温度和压力条件下，添加剂是主体聚合物中的不溶性液体。 添加剂在注射成型期间被驱动到流动前表面（22），然后通过喷泉流转移到部件的表面（24），并且以薄层分布在表面上，产生所需的表面改性，而不改变 本体聚合物的性质，以及消除制造过程中的后处理步骤。
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公开(公告)号：US5276102A
公开(公告)日：1994-01-04
申请号：US1596
申请日：1993-01-07
IPC分类号： C08F8/00
CPC分类号： C08F8/00
摘要： Electrically conductive polythiopheneamine polymer networks are provided comprising conjugated crosslinks between polythiopheneamine polymer segments of the network. The network can be formed by crosslinking amine functional polythiopheneamine polymers, such as by crosslinking condensation reaction with conjugated polyketone crosslinkers. The amine functional polythiopheneamine polymers can be prepared by polymerization, such as by electropolymerization of amine functional thiophene monomers (the amine functionality generally being protected during polymerization) and, optionally, suitable conjugated copolymerization monomers such as thiophene, pyrrole and/or amine functional pyrrole.
摘要翻译： 提供导电聚噻吩胺聚合物网络，其包括网络的聚噻吩胺聚合物链段之间的共轭交联。 该网络可以通过交联胺官能聚噻吩胺聚合物形成，例如通过与共轭聚酮交联剂交联缩合反应。 胺官能聚噻吩胺聚合物可以通过聚合制备，例如通过胺官能化噻吩单体的电聚合（通常在聚合期间保护的胺官能团）和任选的合适的共轭共聚单体如噻吩，吡咯和/或胺官能的吡咯。
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公开(公告)号：US4448941A
公开(公告)日：1984-05-15
申请号：US328278
申请日：1981-12-07
IPC分类号： C08F299/02 , C08G59/64 , C08G59/16
CPC分类号： C08G59/64 , C08F299/026
摘要： Free-radical curable amino vinyl ester resin binder compositions for fiber reinforced composite materials with improved interlaminar shear strength and accelerated cure rate. The composition comprises about 80 to about 20 weight percent of amino vinyl prepolymer and about 20 to about 80 weight percent of a crosslinkable diluent, wherein the prepolymer consists essentially of the reaction product of epoxy-amino alcohol adduct and unsaturated monomer having a terminal vinyl group and a hydroxy reactive functionality capable of reacting with the hydroxyl groups of the adduct. The polyepoxide and amino alcohol, preferably a diethanol amine, are reacted in a ratio of about 1:1-1.2 equivalents of epoxide to amine groups, so as to react essentially all of the epoxide groups. Subsequently, between about 0.3-1.0 of the hydroxyl groups of the adduct are reacted with the vinyl monomer.
摘要翻译： 具有改善层间剪切强度和加速固化速率的纤维增强复合材料的自由基可固化氨基乙烯基酯树脂粘合剂组合物。 组合物包含约80至约20重量％的氨基乙烯基预聚物和约20至约80重量％的可交联稀释剂，其中预聚物基本上由环氧 - 氨基醇加合物和具有末端乙烯基的不饱和单体的反应产物 以及能够与加合物的羟基反应的羟基反应性官能团。 多环氧化物和氨基醇，优选二乙醇胺以约1:1-1.2当量的环氧化物与胺基的比例反应，以使基本上所有的环氧基团反应。 随后，约0.3-1.0的加合物的羟基与乙烯基单体反应。
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公开(公告)号：US5328961A
公开(公告)日：1994-07-12
申请号：US1708
申请日：1993-01-07
CPC分类号： C08G61/126
摘要： Electrically conductive polythiophenecarbonyl polymer networks are provided comprising conjugated crosslinks between polythiophenecarbonyl polymer segments of the network. The network can be formed by crosslinking carbonyl functional polythiophenecarbonyl polymers, such as by self-crosslinking condensation reaction or crosslinking condensation reaction with conjugated diylide and/or conjugated polyamine. The carbonyl functional polythiophenecarbonyl polymers can be prepared by polymerization, such as by electropolymerization of carbonyl functional thiophene monomers (the carbonyl functionality generally being protected during polymerization) and, optionally, suitable conjugated copolymerization monomers such as thiophene, pyrrole and/or carbonyl functional pyrrole.
摘要翻译： 提供导电聚噻吩羰基聚合物网络，其包括网络的聚噻吩羰基聚合物链段之间的共轭交联。 该网络可以通过交联羰基官能聚噻吩羰基聚合物形成，例如通过自交联缩合反应或与共轭二酰亚胺和/或共轭多胺进行交联缩合反应。 羰基官能聚噻吩羰基聚合物可以通过聚合制备，例如通过羰基官能化噻吩单体的电聚合（通常在聚合期间被保护的羰基官能团）和任选的合适的共轭共聚单体如噻吩，吡咯和/或羰基官能吡咯。
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公开(公告)号：US5254627A
公开(公告)日：1993-10-19
申请号：US1604
申请日：1993-01-07
CPC分类号： C08G61/123 , H01B1/127
摘要： Electrically conductive polyaminopyrrole polymer networks are provided comprising conjugated crosslinks between polyaminopyrrole polymer segments of the network. The network can be formed by crosslinking amine functional polyaminopyrrole polymers, such as by crosslinking condensation reaction with conjugated polyketone crosslinkers. The amine functional polyaminopyrrole polymers can be prepared by polymerization, such as by electropolymerization of amine functional pyrrole monomers (the amine functionality generally being protected during polymerization) and, optionally, suitable conjugated copolymerization monomers such as thiophene, pyrrole and/or amine functional thiophene.
摘要翻译： 提供导电聚氨基吡咯聚合物网络，其包括网络的聚氨基吡咯聚合物链段之间的共轭交联。 可以通过交联胺官能聚氨基吡咯聚合物形成网络，例如通过与共轭聚酮交联剂交联缩合反应。 胺官能聚氨基吡咯聚合物可以通过聚合制备，例如通过胺官能化吡咯单体的电聚合（通常在聚合期间保护的胺官能团）和任选的合适的共轭共聚单体如噻吩，吡咯和/或胺官能噻吩。
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6.发明授权
公开(公告)号：US4181785A
公开(公告)日：1980-01-01
申请号：US945031
申请日：1978-09-22
CPC分类号： C09D133/10 , C08G59/3209 , C08G59/4071 , C09D5/38 , C08L61/20 , Y10S525/913
摘要： A fast curing, high solids coating composition that is adapted for use as an automotive topcoat and which upon curing forms a hard, glossy, durable coating exhibiting excellent resistance to solvent and water. The coating composition contains greater than about 60 percent by weight of nonvolatile solids and, exclusive of pigments, solvents and other nonreactive components, consists essentially of:(A) a bifunctional copolymer bearing hydroxy functionality and pendant epoxy functionality, having a number average molecular weight (M.sub.n) of between about 1500 and about 10,000 and a glass transition temperature (Tg) of between about -25.degree. and about 70.degree. C.;(B) at least one organophosphate ester selected from certain mono- and diesters of phosphoric acid;(C) an amine-aldehyde resin crosslinking agent; and(D) optionally a hydroxy functional additive.The organophosphate ester is included in the composition in an amount sufficient to provide between about 0.67 and about 1.4 equivalents of acid functionality for each equivalent of pendant epoxy functionality of the copolymer of (A), and the amino crosslinking agent is included in the composition in an amount sufficient to provide at least about 0.67 equivalents of nitrogen crosslinking functionality for each equivalent of hydroxy functionality included in the composition (i) as a hydroxyl group on said optional hydroxy functional additive, (ii) as a hydroxyl group on said bifunctional copolymer or (iii) as a result of esterification of the pendent epoxy functionality of said bifunctional copolymer during curing of the composition.
摘要翻译： 适合用作汽车顶涂层的快速固化，高固含量涂料组合物，并且其在固化时形成表现出优异的耐溶剂性和耐水性的硬质，有光泽，耐久的涂料。 涂料组合物含有大于约60重量％的不挥发固体，除颜料，溶剂和其它非反应性组分外，其组成基本上由以下组成：（A）具有数均分子量的具有羟基官能度和侧链环氧官能度的双官能共聚物 （Mn）为约1500至约10,000，玻璃化转变温度（Tg）为约-25至约70℃; （B）选自磷酸的某些单酯和二酯的至少一种有机磷酸酯; （C）胺 - 醛树脂交联剂; 和（D）任选的羟基官能添加剂。 有机磷酸酯以足以为（A）的共聚物的每当量侧链环氧官能度提供约0.67至约1.4当量的酸官能度的量包含在组合物中，并且氨基交联剂包括在组合物中 足以为所述组合物（i）中包含的每当量羟基官能团提供至少约0.67当量的氮交联官能团的量作为所述任选的羟基官能添加剂上的羟基，（ii）作为所述双功能共聚物上的羟基或 （iii）作为组合物固化期间所述双功能共聚物的侧链环氧官能团的酯化的结果。
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公开(公告)号：US5274046A
公开(公告)日：1993-12-28
申请号：US1926
申请日：1993-01-07
CPC分类号： C08F8/00
摘要： Electrically conductive polypyrrolecarbonyl polymer networks are provided comprising conjugated crosslinks between polypyrrolecarbonyl polymer segments of the network. The network can be formed by crosslinking carbonyl functional polypyrrolecarbonyl polymers, such as by self-crosslinking condensation reaction or crosslinking condensation reaction with conjugated diylide and/or conjugated polyamine. The carbonyl functional polypyrrolecarbonyl polymers can be prepared by polymerization, such as by electropolymerization of carbonyl functional pyrrole monomers (the carbonyl functionality generally being protected during polymerization) and, optionally, suitable conjugated copolymerization monomers such as thiophene, pyrrole and/or carbonyl functional thiophene.
摘要翻译： 提供了导电聚吡咯基聚合物网络，其包括网络的聚吡咯羰基聚合物链段之间的共轭交联。 该网络可以通过交联羰基官能聚吡咯基聚合物形成，例如通过自交联缩合反应或与共轭二酰亚胺和/或共轭多胺进行交联缩合反应。 羰基官能聚吡咯基聚合物可以通过聚合制备，例如通过羰基官能化吡咯单体的电聚合（通常在聚合期间被保护的羰基官能团）和任选的合适的共轭共聚单体如噻吩，吡咯和/或羰基官能噻吩。
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公开(公告)号：US5023284A
公开(公告)日：1991-06-11
申请号：US390955
申请日：1989-08-09
申请人： Mo-Fung Cheung , Amos Golovoy , Henk van Oene
发明人： Mo-Fung Cheung , Amos Golovoy , Henk van Oene
摘要： This invention is directed to a stabilizer useful to retard transesterification in moldable polymer blends containing polyester(s) during processing of the blends at elevated temperatures, particularly at high temperatures above about 285.degree. C. More particularly, the stabilizer comprises a phosphate-epoxy adduct. The stabilizer may optionally further comprise a reactive functionality component comprising a compound having a imide or oxazoline functionality and/or a hindered phenol component. The invention is also directed to a composition comprising the stabilizer and a particularly defined polymer blend.
摘要翻译： 本发明涉及一种稳定剂，其用于在高温下特别是高于约285℃的高温下处理共混物时，在含有聚酯的可模制聚合物共混物中阻断酯交换反应。更具体地说，稳定剂包括磷酸酯 - 环氧加合物 。 稳定剂可以任选地进一步包含反应性官能组分，其包含具有酰亚胺或恶唑啉官能团的化合物和/或受阻酚组分。 本发明还涉及包含稳定剂和特别限定的聚合物共混物的组合物。
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公开(公告)号：US4983654A
公开(公告)日：1991-01-08
申请号：US138255
申请日：1987-12-28
申请人： Mo-Fung Cheung , Amos Golovoy , Henk van Oene
发明人： Mo-Fung Cheung , Amos Golovoy , Henk van Oene
摘要： This invention is directed to a stabilizer useful to retard transesterification in moldable polymer blends containing polyester(s) during processing of the blends at elevated temperatures, particularly at high temperatures above about 285.degree. C. More particularly, the stabilizer comprises a phosphate-epoxy adduct. The stabilizer may optionally further comprise a reactive functionality component comprising a compound having a imide or oxazoline functionality and/or a hindered phenol component. The invention is also directed to a composition comprising the stabilizer and a particularly defined polymer blend.
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10.发明授权
公开(公告)号：US4477327A
公开(公告)日：1984-10-16
申请号：US369943
申请日：1982-04-19
IPC分类号： C08F299/02 , C08F299/06 , C09D4/06 , C08G18/00
CPC分类号： C08F299/065 , C08F299/024 , C09D4/06 , Y10S522/911
摘要： A low dosage radiation polymerizable protective and decorative coating composition or paint, coated articles bearing such a protective coating and processess for preparing such articles. The radiation polymerizable coating composition comprises an organic resin/monomer mixture of:(A) between about 97 and about 3 weight percent alpha-beta olefinically unsaturated organic resin containing between about 0.5 and about 5 vinyl unsaturation units per 1000 molecular weight of said resin, and(B) between about 3 and about 97 weight percent vinyl monomers polymerizable with said resin upon exposure to radiation, characterized in that said vinyl monomers include N-vinyl-2-pyrrolidone in an amount of from about 3 and up to about 10 weight percent based on the total weight of (A) and (B).The flexible coating exhibits excellent physical qualtities and good adhesion to a variety of substrates being particularly suitable for use on vinyl chloride fabric, wherein it is discoloration resistant after heat aging. Preferred articles bearing such a coating, which may comprise large amounts of pigment, are preferably cured by exposure to electron beam radiation.
摘要翻译： 低剂量可辐射聚合的保护和装饰涂料组合物或涂料，具有这种保护涂层和无机物的涂覆制品用于制备这种制品。 可辐射聚合涂层组合物包含有机树脂/单体混合物：（A）在约97至约3重量％的α-β烯属不饱和有机树脂之间，每1000分子量的所述树脂含有约0.5至约5个乙烯基不饱和单元， 和（B）约3至约97重量％的乙烯基单体在暴露于辐射时可与所述树脂可聚合，其特征在于所述乙烯基单体包括约3至约10重量％的N-乙烯基-2-吡咯烷酮 （A）和（B）的总重量的百分比。 柔性涂层表现出优异的物理质量和对各种基材的良好粘合性，特别适用于氯乙烯织物，其中在热老化后它具有耐变色性。 优选的含有大量颜料的涂层的制品优选通过暴露于电子束辐射来固化。
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