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公开(公告)号：US20160115095A1
公开(公告)日：2016-04-28
申请号：US14878753
申请日：2015-10-08
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Jihad M. Dakka , Lorenzo C. DeCaul , Gregory J. De Martin , Michael Salciccioli , Neeraj Sangar , Aaron B. Pavlish , Ali A. Kheir , Gary D. Mohr
IPC: C07C5/367
CPC classification number: C07C5/367 , B01J23/626 , B01J29/7476 , B01J37/0205 , B01J37/18 , B01J2229/186 , B01J2229/42 , C07C2/74 , C07C2521/04 , C07C2521/08 , C07C2523/14 , C07C2523/42 , C07C2523/62 , C07C2529/74 , C07C2601/14 , C07C15/14 , C07C13/28
Abstract: In a process for dehydrogenating cyclohexylbenzene and/or alkyl-substituted cyclohexylbenzene compounds, a dehydrogenation catalyst comprising at least one Group 10 metal compound on a support is heated in the presence of hydrogen from a first temperature from 0° C. to 200° C. to a second, higher temperature from 60° C. to 500° C. at a ramp rate no more than 100° C./hour. The dehydrogenation catalyst is contacted with hydrogen at the second temperature for a time from 3 to 300 hours to produce an activated dehydrogenation catalyst. A feed comprising cyclohexylbenzene and/or an alkyl-substituted cyclohexylbenzene compound is then contacted with hydrogen in the presence of the activated dehydrogenation catalyst under conditions effective to produce a dehydrogenation reaction product comprising biphenyl and/or an alkyl-substituted biphenyl compound.
Abstract translation: 在环己基苯和/或烷基取代的环己基苯化合物脱氢的方法中，在载体上包含至少一种第10族金属化合物的脱氢催化剂在0℃至200℃的第一温度下在氢气存在下加热。 到第二个更高的温度，从60℃到500℃，升温速率不超过100℃/小时。 脱氢催化剂在第二温度下与氢气接触3至300小时，以产生活化脱氢催化剂。 然后在有效产生包含联苯和/或烷基取代的联苯化合物的脱氢反应产物的条件下，在活化的脱氢催化剂存在下，将包含环己基苯和/或烷基取代的环己基苯化合物的进料与氢气接触。
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公开(公告)号：US09688602B2
公开(公告)日：2017-06-27
申请号：US14201284
申请日：2014-03-07
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Jihad M. Dakka , Chuansheng Bai , James J. Tanke , Gregory J. De Martin , Mary T. Van Nostrand , Michael Salciccioli , Ali A. Kheir , Neeraj Sangar
CPC classification number: C07C67/08 , C07C2/74 , C07C5/367 , C07C2521/04 , C07C2521/08 , C07C2521/18 , C07C2523/42 , C07C2523/62 , C07C2529/76 , C07C2601/14 , C07C69/76 , C07C15/14 , C07C13/28
Abstract: In a process for producing a methyl-substituted biphenyl compound, at least one methyl-substituted cyclohexylbenzene compound of the formula: wherein each of m and n is independently an integer from 1 to 3, is contacted with a dehydrogenation catalyst under conditions effective to produce a dehydrogenation reaction product comprising at least one methyl-substituted biphenyl compound. The dehydrogenation catalyst comprises an element or compound thereof from Group 10 of the Periodic Table of Elements deposited on a refractory support, such as alumina.
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公开(公告)号：US09758447B2
公开(公告)日：2017-09-12
申请号：US14878753
申请日：2015-10-08
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Jihad M. Dakka , Lorenzo C. DeCaul , Gregory J. De Martin , Michael Salciccioli , Neeraj Sangar , Aaron B. Pavlish , Ali A. Kheir , Gary D. Mohr
CPC classification number: C07C5/367 , B01J23/626 , B01J29/7476 , B01J37/0205 , B01J37/18 , B01J2229/186 , B01J2229/42 , C07C2/74 , C07C2521/04 , C07C2521/08 , C07C2523/14 , C07C2523/42 , C07C2523/62 , C07C2529/74 , C07C2601/14 , C07C15/14 , C07C13/28
Abstract: In a process for dehydrogenating cyclohexylbenzene and/or alkyl-substituted cyclohexylbenzene compounds, a dehydrogenation catalyst comprising at least one Group 10 metal compound on a support is heated in the presence of hydrogen from a first temperature from 0° C. to 200° C. to a second, higher temperature from 60° C. to 500° C. at a ramp rate no more than 100° C./hour. The dehydrogenation catalyst is contacted with hydrogen at the second temperature for a time from 3 to 300 hours to produce an activated dehydrogenation catalyst. A feed comprising cyclohexylbenzene and/or an alkyl-substituted cyclohexylbenzene compound is then contacted with hydrogen in the presence of the activated dehydrogenation catalyst under conditions effective to produce a dehydrogenation reaction product comprising biphenyl and/or an alkyl-substituted biphenyl compound.
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4.发明申请Methyl-Substituted Biphenyl Compounds, Their Production and Their Use in the Manufacture of Plasticizers 有权甲基取代的联苯化合物，其生产及其在增塑剂的制造中的应用公开(公告)号：US20140275607A1
公开(公告)日：2014-09-18
申请号：US14201284
申请日：2014-03-07
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Jihad M. Dakka , Chuansheng Bai , James J. Tanke , Gregory J. De Martin , Mary T. Van Nostrand , Michael Salciccioli , Ali A. Kheir , Neeraj Sangar
CPC classification number: C07C67/08 , C07C2/74 , C07C5/367 , C07C2521/04 , C07C2521/08 , C07C2521/18 , C07C2523/42 , C07C2523/62 , C07C2529/76 , C07C2601/14 , C07C69/76 , C07C15/14 , C07C13/28
Abstract: In a process for producing a methyl-substituted biphenyl compound, at least one methyl-substituted cyclohexylbenzene compound of the formula: wherein each of m and n is independently an integer from 1 to 3, is contacted with a dehydrogenation catalyst under conditions effective to produce a dehydrogenation reaction product comprising at least one methyl-substituted biphenyl compound. The dehydrogenation catalyst comprises an element or compound thereof from Group 10 of the Periodic Table of Elements deposited on a refractory support, such as alumina.
Abstract translation: 在制备甲基取代的联苯化合物的方法中，至少一种下式的甲基取代的环己基苯化合物：其中m和n各自独立地为1至3的整数在有效产生的条件下与脱氢催化剂接触 包含至少一种甲基取代的联苯化合物的脱氢反应产物。 脱氢催化剂包含沉积在耐火载体如氧化铝上的元素周期表第10族元素或其化合物。
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