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公开(公告)号：US11794181B2
公开(公告)日：2023-10-24
申请号：US17271093
申请日：2019-08-27
Applicant: Dow Global Technologies LLC
Inventor： Manish Sharma , Brian W. Goodfellow , David F. Yancey , Andrzej Malek , Eric E. Stangland
IPC: B01J35/00 , B01J23/28 , B01J23/30 , B01J23/34 , B01J23/745 , B01J23/75 , B01J23/888 , B01J35/02 , B01J37/02 , B01J37/08 , C01B3/26 , B01J37/04 , B02C17/24 , C01G45/02 , C01G45/12 , C01G49/06 , C01G51/04
CPC classification number: B01J35/0006 , B01J23/28 , B01J23/30 , B01J23/34 , B01J23/745 , B01J23/75 , B01J23/888 , B01J35/0086 , B01J35/026 , B01J37/0201 , B01J37/0221 , B01J37/04 , B01J37/088 , B02C17/24 , C01B3/26 , C01G45/02 , C01G45/1264 , C01G49/06 , C01G51/04 , C01P2004/04 , C01P2004/84
Abstract: Embodiments of the present disclosure are directed to methods of producing a hydrogen-selective oxygen carrier material comprising combining one or more core material precursors and one or more shell material precursors to from a precursor mixture and heat-treating the precursor mixture at a treatment temperature to form the hydrogen-selective oxygen carrier material. The treatment temperature is greater than or equal to 100° C. less than the melting point of a shell material, and the hydrogen-selective oxygen carrier material comprises a core comprising a core material and a shell comprising the shell material. The shell material may be in direct contact with at least a majority of an outer surface of the core material.
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公开(公告)号：US20230257327A1
公开(公告)日：2023-08-17
申请号：US18307619
申请日：2023-04-26
Applicant: Dow Global Technologies LLC
Inventor： Kevin Blann , Alexey Kirilin , Andrzej Malek , Victor Sussman , Matthew T. Pretz , Brien A. Stears , Barry B. Fish , Eric E. Stangland , Brian W. Goodfellow , Manish Sharma
CPC classification number: C07C5/48 , B01J21/04 , B01J21/06 , B01J21/10 , B01J23/08 , B01J23/26 , B01J23/42 , C07C2521/04 , C07C2521/06 , C07C2521/10 , C07C2523/08 , C07C2523/26 , C07C2523/42
Abstract: According to one or more embodiments described herein, a method for dehydrogenating hydrocarbons may include passing a hydrocarbon feed comprising one or more alkanes or alkyl aromatics into a fluidized bed reactor, contacting the hydrocarbon feed with a dehydrogenation catalyst in the fluidized bed reactor to produce a dehydrogenated product and hydrogen, and contacting the hydrogen with an oxygen-rich oxygen carrier material in the fluidized bed reactor to combust the hydrogen and form an oxygen-diminished oxygen carrier material. In additional embodiments, a dual-purpose material may be utilized which has dehydrogenation catalyst and oxygen carrying functionality.
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公开(公告)号：US12151233B2
公开(公告)日：2024-11-26
申请号：US17271089
申请日：2019-08-27
Applicant: Dow Global Technologies LLC
Inventor： Brian W. Goodfellow , Manish Sharma , David F. Yancey , Andrzej Malek , Eric E. Stangland
IPC: C01G45/12 , B01J23/28 , B01J23/30 , B01J23/34 , B01J23/745 , B01J23/75 , B01J23/888 , B01J35/00 , B01J35/30 , B01J35/50 , B01J37/02 , B01J37/04 , B01J37/08 , B02C17/24 , C01B3/26 , C01G45/02 , C01G49/06 , C01G51/04
Abstract: Embodiments of the present disclosure are directed to hydrogen-selective oxygen carrier materials and methods of using hydrogen-selective oxygen carrier materials. The hydrogen-selective oxygen carrier material may comprise a core material, which includes a redox-active transition metal oxide; a shell material, which includes one or more alkali transition metal oxides; and a support material. The shell material may be in direct contact with at least a majority of an outer surface of the core material. At least a portion of the core material may be in direct contact with the support material. The hydrogen-selective oxygen carrier material may be selective to combust hydrogen in an environment that includes hydrogen and hydrocarbons.
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公开(公告)号：US11724974B2
公开(公告)日：2023-08-15
申请号：US17271139
申请日：2019-08-27
Applicant: Dow Global Technologies LLC
Inventor： Kevin Blann , Alexey Kirilin , Andrzej Malek , Victor Sussman , Matthew T. Pretz , Brien A. Stears , Barry B. Fish , Eric E. Stangland , Brian W. Goodfellow , Manish Sharma
CPC classification number: C07C5/48 , B01J21/04 , B01J21/06 , B01J21/10 , B01J23/08 , B01J23/26 , B01J23/42 , C07C2521/04 , C07C2521/06 , C07C2521/10 , C07C2523/08 , C07C2523/26 , C07C2523/42
Abstract: According to one or more embodiments described herein, a method for dehydrogenating hydrocarbons may include passing a hydrocarbon feed comprising one or more alkanes or alkyl aromatics into a fluidized bed reactor, contacting the hydrocarbon feed with a dehydrogenation catalyst in the fluidized bed reactor to produce a dehydrogenated product and hydrogen, and contacting the hydrogen with an oxygen-rich oxygen carrier material in the fluidized bed reactor to combust the hydrogen and form an oxygen-diminished oxygen carrier material. In additional embodiments, a dual-purpose material may be utilized which has dehydrogenation catalyst and oxygen carrying functionality.
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Patent Agency Ranking
公开(公告)号：US20210317004A1
公开(公告)日：2021-10-14
申请号：US17271089
申请日：2019-08-27
Applicant: Dow Global Technologies LLC
Inventor： Brian W. Goodfellow , Manish Sharma , David F. Yancey , Andrzej Malek , Eric E. Stangland
IPC: C01G45/12 , C01G51/04 , C01G49/06 , C01G45/02 , B02C17/24 , B01J35/00 , B01J37/08 , B01J37/04 , B01J37/02
Abstract: Embodiments of the present disclosure are directed to hydrogen-selective oxygen carrier materials and methods of using hydrogen-selective oxygen carrier materials. The hydrogen-selective oxygen carrier material may comprise a core material, which includes a redox-active transition metal oxide; a shell material, which includes one or more alkali transition metal oxides; and a support material. The shell material may be in direct contact with at least a majority of an outer surface of the core material. At least a portion of the core material may be in direct contact with the support material. The hydrogen-selective oxygen carrier material may be selective to combust hydrogen in an environment that includes hydrogen and hydrocarbons.
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公开(公告)号：US20240051901A1
公开(公告)日：2024-02-15
申请号：US18257895
申请日：2021-12-15
Applicant: Dow Global Technologies LLC
Inventor： Lin Luo , Yang Yang , Adrianus Koeken , Brien Stears , Luis Bollmann , Andrzej Malek , Brian W. Goodfellow
CPC classification number: C07C5/3337 , B01J23/62 , B01J21/04 , B01J23/96 , B01J38/30 , B01J38/02 , C07C2523/62
Abstract: According to one or more embodiments of the present disclosure, a method for producing olefins includes contacting a hydrocarbon-containing feed with a catalyst in a reactor portion of a reactor system to form an olefin-containing effluent, separating at least a portion of the olefin-containing effluent from the catalyst, passing the catalyst to a catalyst-processing portion of the reactor system and processing the catalyst to produce a processed catalyst and a combustion gas, passing the processed catalyst from the catalyst-processing portion to the reactor portion, and introducing a combustion additive to the reactor system when the combustion gas comprises one or more hydrocarbons in an amount greater than 5% of an LFL of the combustion gas at a temperature and pressure of the catalyst processing portion. The catalyst may include from 1 ppmw to 150 ppmw platinum. The combustion additive may include from 150 ppmw to 1,000 ppmw platinum.
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公开(公告)号：US20240050927A1
公开(公告)日：2024-02-15
申请号：US18257908
申请日：2021-12-15
Applicant: Dow Global Technologies LLC
Inventor： Lin Luo , Yang Yang , Adrianus Koeken , Brien Stears , Luis Bollmann , Andrzej Malek , Brian W. Goodfellow
CPC classification number: B01J23/62 , B01J21/04 , C07C5/3337 , C07C2523/42 , C07C2523/08
Abstract: According to one or more embodiments of the present disclosure, a catalyst system useful for dehydrogenation includes from 98 vol. % to 99.95 vol. % of a catalyst and from 0.05 vol. % to 2 vol. % of a combustion additive. The catalyst may include from 1 ppmw to 150 ppmw platinum, gallium, and a support material. The combustion additive may include from 150 ppmw to 1,000 ppmw platinum, gallium, and a support material. The combustion additive may include at least 1.1 times greater platinum than the catalyst.
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公开(公告)号：US20210292259A1
公开(公告)日：2021-09-23
申请号：US17271139
申请日：2019-08-27
Applicant: Dow Global Technologies LLC
Inventor： Kevin Blann , Alexey Kirilin , Andrzej Malek , Victor Sussman , Matthew T. Pretz , Brien A. Stears , Barry B. Fish , Eric E. Stangland , Brian W. Goodfellow , Manish Sharma
Abstract: According to one or more embodiments described herein, a method for dehydrogenating hydrocarbons may include passing a hydrocarbon feed comprising one or more alkanes or alkyl aromatics into a fluidized bed reactor, contacting the hydrocarbon feed with a dehydrogenation catalyst in the fluidized bed reactor to produce a dehydrogenated product and hydrogen, and contacting the hydrogen with an oxygen-rich oxygen carrier material in the fluidized bed reactor to combust the hydrogen and form an oxygen-diminished oxygen carrier material. In additional embodiments, a dual-purpose material may be utilized which has dehydrogenation catalyst and oxygen carrying functionality.
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公开(公告)号：US20210245146A1
公开(公告)日：2021-08-12
申请号：US17271093
申请日：2019-08-27
Applicant: Dow Global Technologies LLC
Inventor： Manish Sharma , Brian W. Goodfellow , David F. Yancey , Andrzej Malek , Eric E. Stangland
IPC: B01J35/00 , B01J23/75 , B01J23/30 , B01J23/745 , B01J23/28 , B01J23/34 , B01J23/888 , B01J35/02 , B01J37/02 , B01J37/08 , C01B3/26
Abstract: Embodiments of the present disclosure are directed to methods of producing a hydrogen- selective oxygen carrier material comprising combining one or more core material precursors and one or more shell material precursors to from a precursor mixture and heat-treating the precursor mixture at a treatment temperature to form the hydrogen-selective oxygen carrier material. The treatment temperature is greater than or equal to 100° C. less than the melting point of a shell material, and the hydrogen- selective oxygen carrier material comprises a core comprising a core material and a shell comprising the shell material. The shell material may be in direct contact with at least a majority of an outer surface of the core material.
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