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公开(公告)号：US20160244402A1
公开(公告)日：2016-08-25
申请号：US15027327
申请日：2014-10-02
IPC分类号： C07C209/36
CPC分类号： C07C209/36 , C07C211/50
摘要： The invention relates to an industrial-scale method for the vapor-phase hydrogenation of dinitrotoluene (DNT). According to said method, a stream containing DNT is sprayed into a carrier-gas stream containing hydrogen, optionally in the presence of an atomizing gas, unevaporated liquid droplets are extracted from the substantially gaseous stream that is obtained and the resultant gas stream is catalytically hydrogenated to form diaminotoluene.
摘要翻译： 本发明涉及用于二硝基甲苯（DNT）的气相氢化的工业规模的方法。 根据所述方法，任选地在雾化气体存在下，将含有DNT的料流喷入含有氢气的载气流中，从得到的基本气态物流中提取未蒸发的液滴，并将所得气流催化氢化 形成二氨基甲苯。
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公开(公告)号：US10731187B2
公开(公告)日：2020-08-04
申请号：US15119825
申请日：2015-02-19
发明人： Gernot Jaeger , Jorgen Magnus , Amgad Salah Moussa , Guenter Olf , Giulio Lolli , Swantje Behnken , Jung-Won Youn , Mohammad Yalfani , Georg Sprenger
IPC分类号： C12P13/00 , C12P13/02 , C12P13/04 , C12N15/78 , C12N15/77 , C12N15/70 , C12N9/90 , C12N9/10 , C12N15/52
摘要： The invention provides a recombinant microbial host cell capable of converting a raw material comprising a fermentable carbon substrate to o-aminobenzoate biologically. The invention further provides a method for producing aniline, comprising the steps of: a) producing o-aminobenzoate by fermentation of a raw material comprising at least one fermentable carbon substrate using the recombinant microbial host cell of the capable of converting said raw material comprising at least one fermentable carbon substrate to o-aminobenzoate biologically, wherein said o-aminobenzoate comprises anthranilate anion, b) converting said o-aminobenzoate from said anthranilate anion to anthranilic acid by acid protonation, c) recovering said anthranilic acid by precipitation or by dissolving in an organic solvent, and d) converting said anthranilic acid to aniline by thermal decarboxylation in an organic solvent.
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公开(公告)号：US09518006B2
公开(公告)日：2016-12-13
申请号：US15027327
申请日：2014-10-02
IPC分类号： C07C209/36
CPC分类号： C07C209/36 , C07C211/50
摘要： The invention relates to an industrial-scale method for the vapor-phase hydrogenation of dinitrotoluene (DNT). According to said method, a stream containing DNT is sprayed into a carrier-gas stream containing hydrogen, optionally in the presence of an atomizing gas, unevaporated liquid droplets are extracted from the substantially gaseous stream that is obtained and the resultant gas stream is catalytically hydrogenated to form diaminotoluene.
摘要翻译： 本发明涉及用于二硝基甲苯（DNT）的气相氢化的工业规模的方法。 根据所述方法，任选地在雾化气体存在下，将含有DNT的料流喷入含有氢气的载气流中，从得到的基本气态物流中提取未蒸发的液滴，并将所得气流催化氢化 形成二氨基甲苯。
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公开(公告)号：US11155844B2
公开(公告)日：2021-10-26
申请号：US16062706
申请日：2016-12-14
发明人： Gernot Jäger , Amgad Salah Moussa , Simon Klaffl , Thomas Hamedinger , Wolf Kloeckner , Swantje Behnken
摘要： The present invention relates to the production of o-aminobenzoic acid from fermentable substrates using yeast cells.
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公开(公告)号：US10703709B2
公开(公告)日：2020-07-07
申请号：US16311205
申请日：2017-06-27
IPC分类号： C07C209/68 , C07C209/78 , C12P13/00
摘要： The invention relates to a method for producing aniline or products that are obtained by further chemical reaction of aniline (aniline derivatives), involving decarboxylation of aminobenzoic acid, particularly ortho-aminobenzoic acid, in which one portion of the previously formed crude aniline is recirculated in the decarboxylation step. The aminobenzoic acid is obtained enzymatically or chemically, preferably enzymatically.
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公开(公告)号：US20170152535A1
公开(公告)日：2017-06-01
申请号：US15119825
申请日：2015-02-19
发明人： Gernot Jaeger , Jorgen Magnus , Amgad Salah Moussa , Guenter Olf , Giulio Lolli , Swantje Behnken , Jung-Won Youn , Mohammad Yalfani , Georg Sprenger
CPC分类号： C12P13/001 , C12N9/1077 , C12N9/90 , C12N15/52 , C12N15/70 , C12N15/77 , C12N15/78 , C12P13/02 , C12P13/04 , C12Y204/02018 , C12Y504/99005
摘要： The invention provides a recombinant microbial host cell capable of converting a raw material comprising a fermentable carbon substrate to o-aminobenzoate biologically. The invention further provides a method for producing aniline, comprising the steps of: a) producing o-aminobenzoate by fermentation of a raw material comprising at least one fermentable carbon substrate using the recombinant microbial host cell of the capable of converting said raw material comprising at least one fermentable carbon substrate to o-aminobenzoate biologically, wherein said o-aminobenzoate comprises anthranilate anion, b) converting said o-aminobenzoate from said anthranilate anion to anthranilic acid by acid protonation, c) recovering said anthranilic acid by precipitation or by dissolving in an organic solvent, and d) converting said anthranilic acid to aniline by thermal decarboxylation in an organic solvent.
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公开(公告)号：US11168341B2
公开(公告)日：2021-11-09
申请号：US15776113
申请日：2016-11-17
发明人： Gernot Jäger , Wolfgang Beckmann , Amgad Salah Moussa , Guenter Olf , Guido Becker , Hasan Akyildiz , Andreas Damm , Thomas Hamedinger , Wolf Kloeckner , Swantje Behnken
摘要： The invention relates to a method for producing aminobenzoic acid or a aminobenzoic acid derivative via the fermentation of a suitable raw material under the influence of suitable microorganisms and obtaining a fermentation broth containing aminobenzoate and/or aminobenzoic acid. In particular, the invention relates to the step of obtaining the aminobenzoic acid from the fermentation broth, wherein the crystallisation of aminobenzoic acid is carried out via a simple one-stage acid treatment in the presence of seed crystals. The aminobenzoic acid crystallised in this simple manner can be easily separated from the mother liquor, further cleaned if necessary, and then supplied to the different applications.
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公开(公告)号：US10968466B2
公开(公告)日：2021-04-06
申请号：US16469746
申请日：2017-12-18
IPC分类号： C12P13/00 , C07C209/78 , C07C227/40 , C07C231/02 , C07C245/02 , C08G12/08 , C08G73/02
摘要： The present invention relates to a process for preparing aminobenzoic acid or an aminobenzoic acid conversion product, comprising the steps of: (I) providing an aqueous solution of aminobenzoic acid using a fermentation process; (II) adsorbing aminobenzoic acid; (III) desorbing aminobenzoic acid at a pH in the range from −0.8 to 3.0, preferably −0.5 to 3.0, more preferably 0.1 to 3.0, very preferably 0.5 to 2.5, very exceptionally preferably 1.0 to 2.0; (IV) obtaining the aminobenzoic acid from the desorbate obtained in step (III); (V) optionally further converting the aminobenzoic acid obtained in step (IV) to an aminobenzoic acid conversion product.
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公开(公告)号：US20170066713A1
公开(公告)日：2017-03-09
申请号：US15120163
申请日：2015-02-19
发明人： Gernot Jaeger , Jorgen Magnus , Amgad Salah Moussa
IPC分类号： C07C263/10 , C12P13/00 , C07C209/68 , C07C209/78 , C07C209/84
CPC分类号： C07C263/10 , C07C209/68 , C07C209/78 , C07C209/84 , C12P7/40 , C12P13/00 , C12P13/001
摘要： The invention relates to a method for producing aniline, comprising the steps of: a) providing o-aminobenzoate, wherein said o-aminobenzoate comprises anthranilate anion and a suitable cation, b) converting said anthranilate anion to aniline by thermal decarboxylation in the presence or absence of a catalyst, c) extracting the aniline produced in step b) in an organic solvent at least once, and d) purifying the aniline produced in steps b) and c) by distillation, wherein said distillation produces aniline and a water phase.
摘要翻译： 本发明涉及一种制备苯胺的方法，包括以下步骤：a）提供邻氨基苯甲酸酯，其中所述邻氨基苯甲酸酯包含邻氨基苯甲酸酯阴离子和合适的阳离子，b）在存在或不存在下通过热脱羧将所述邻氨基苯甲酸酯阴离子转化为苯胺 不存在催化剂，c）将有机溶剂中产生的苯胺在有机溶剂中萃取至少一次，和d）通过蒸馏纯化步骤b）和c）中产生的苯胺，其中所述蒸馏产生苯胺和水相。
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公开(公告)号：US10173969B2
公开(公告)日：2019-01-08
申请号：US15120163
申请日：2015-02-19
发明人： Gernot Jaeger , Jorgen Magnus , Amgad Salah Moussa
IPC分类号： C12P7/40 , C12P13/00 , C07C209/68 , C07C209/78 , C07C209/84 , C07C263/10
摘要： The invention relates to a method for producing aniline, comprising the steps of: a) providing o-aminobenzoate, wherein said o-aminobenzoate comprises anthranilate anion and a suitable cation, b) converting said anthranilate anion to aniline by thermal decarboxylation in the presence or absence of a catalyst, c) extracting the aniline produced in step b) in an organic solvent at least once, and d) purifying the aniline produced in steps b) and c) by distillation, wherein said distillation produces aniline and a water phase.
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