公开(公告)号：US20160152510A1

公开(公告)日：2016-06-02

申请号：US14997780

申请日：2016-02-15

Applicant: Corning Incorporated

Inventor： Brian Lee Harper ,  Rostislav Radiyevich Khrapko ,  Snigdharaj Kumar Mishra ,  Sonya Marie Raney ,  Pushkar Tandon

IPC: C03B37/014

CPC classification number: C03B37/01446 ,  C03B37/014 ,  C03B37/01453 ,  C03B2201/08 ,  C03B2201/12 ,  C03B2201/20 ,  C03B2201/31 ,  C03B2203/22 ,  C03B2203/23 ,  C03B2203/26 ,  C03C13/045 ,  C03C2201/11 ,  C03C2201/20

Abstract: One embodiment of the disclosure relates to a method of making an optical fiber comprising the steps of: (i) exposing a silica based preform with at least one porous glass region having soot density of ρ to a gas mixture comprising SiCl4 having SiCl4 mole fraction ySiCl4 at a doping temperature Tdop such that parameter X is larger than 0.03 to form the chlorine treated preform, wherein X = 1 1 + [ ( ρ ρ s - ρ )  0.209748   T dop  Exp  [ - 5435.33 / T dop ] y SiCl   4 3 / 4 ] and ρs is the density of the fully densified soot layer; and (ii) exposing the chlorine treated preform to temperatures above 1400° C. to completely sinter the preform to produce sintered optical fiber preform with a chlorine doped region; and (iii) drawing an optical fiber from the sintered optical preform.

Abstract translation: 本公开的一个实施方案涉及一种制造光纤的方法，包括以下步骤：（i）将二氧化硅基预型体暴露于具有烟炱密度的至少一个多孔玻璃区域; 在掺杂温度Tdop下将SiCl 4的SiCl 4摩尔分数为ySiCl4的气体混合物混合，使得参数X大于0.03以形成经氯处理的预制件，其中X = 11 + [（＆rgr; s - ＆rgr;））0.209748 实验表明，完全致密的煤烟层的密度为 和（ii）将氯处理的预制件暴露于高于1400℃的温度下，以完全烧结预成型件，以制备具有氯掺杂区域的烧结光纤预制件; 和（iii）从烧结的光学预型件拉制光纤。

公开(公告)号：US09676658B2

公开(公告)日：2017-06-13

申请号：US14997780

申请日：2016-02-15

Applicant: Corning Incorporated

Inventor： Brian Lee Harper ,  Rostislav Radiyevich Khrapko ,  Snigdharaj Kumar Mishra ,  Sonya Marie Raney ,  Pushkar Tandon

IPC: C03C13/04 ,  C03B37/014

CPC classification number: C03B37/01446 ,  C03B37/014 ,  C03B37/01453 ,  C03B2201/08 ,  C03B2201/12 ,  C03B2201/20 ,  C03B2201/31 ,  C03B2203/22 ,  C03B2203/23 ,  C03B2203/26 ,  C03C13/045 ,  C03C2201/11 ,  C03C2201/20

Abstract: One embodiment of the disclosure relates to a method of making an optical fiber comprising the steps of: (i) exposing a silica based preform with at least one porous glass region having soot density of ρ to a gas mixture comprising SiCl4 having SiCl4 mole fraction ySiCl4 at a doping temperature Tdop such that parameter X is larger than 0.03 to form the chlorine treated preform, wherein X = 1 1 + [ ( ρ ρ s - ρ ) ⁢ 0.209748 ⁢ ⁢ T dop ⁢ Exp ⁡ [ - 5435.33 / T dop ] y SiCl ⁢ ⁢ 4 3 / 4 ] and ρs is the density of the fully densified soot layer; and (ii) exposing the chlorine treated preform to temperatures above 1400° C. to completely sinter the preform to produce sintered optical fiber preform with a chlorine doped region; and (iii) drawing an optical fiber from the sintered optical preform.

公开(公告)号：US10146008B2

公开(公告)日：2018-12-04

申请号：US15702961

申请日：2017-09-13

Applicant: Corning Incorporated

Inventor： Dana Craig Bookbinder ,  Paul Andrew Chludzinski ,  Brian Lee Harper ,  Ming-Jun Li ,  Snigdharaj Kumar Mishra ,  Sonya Marie Raney ,  Pushkar Tandon

IPC: G02B6/028 ,  G02B6/036 ,  C03B37/014 ,  C03B37/018 ,  G02B6/02 ,  C03B37/025

Abstract: An optical fiber with low attenuation and methods of making same are disclosed. The optical fiber has a core, an inner cladding surround the core, and an outer cladding surrounding the inner cladding. The outer cladding is chlorine-doped such that the relative refractive index varies as a function of radius. The radially varying relative refractive index profile of the outer cladding reduces excess stress in the core and inner cladding, which helps lower fiber attenuation while also reducing macrobend and microbend loss. A process of fabricating the optical fiber includes doping an overclad soot layer of a soot preform with chlorine and then removing a portion of the chlorine dopant from an outermost region of the overclad soot layer. The soot preform with the modified chlorine dopant profile is then sintered to form a glass preform, which can then be used for drawing the optical fiber.

公开(公告)号：US09290405B2

公开(公告)日：2016-03-22

申请号：US14467369

申请日：2014-08-25

Applicant: Corning Incorporated

Inventor： Brian Lee Harper ,  Rostislav Radiyevich Khrapko ,  Snigdharaj Kumar Mishra ,  Sonya Marie Raney ,  Pushkar Tandon

IPC: C03C13/04 ,  C03B37/014

CPC classification number: C03B37/01446 ,  C03B37/014 ,  C03B37/01453 ,  C03B2201/08 ,  C03B2201/12 ,  C03B2201/20 ,  C03B2201/31 ,  C03B2203/22 ,  C03B2203/23 ,  C03B2203/26 ,  C03C13/045 ,  C03C2201/11 ,  C03C2201/20

Abstract: One embodiment of the disclosure relates to a method of making an optical fiber comprising the steps of: (i) exposing a silica based preform with at least one porous glass region having soot density of ρ to a gas mixture comprising SiCl4 having SiCl4 mole fraction ySiCl4 at a doping temperature Tdop such that parameter X is larger than 0.03 to form the chlorine treated preform, wherein X = 1 1 + [ ( ρ ρ s - ρ ) ⁢ 0.209748 ⁢ T dop ⁢ Exp ⁡ [ - 5435.33 / T dop ] y SiCl ⁢ ⁢ 4 3 / 4 ] and ρs is the density of the fully densified soot layer; and (ii) exposing the chlorine treated preform to temperatures above 1400° C. to completely sinter the preform to produce sintered optical fiber preform with a chlorine doped region; and (iii) drawing an optical fiber from the sintered optical preform.

Abstract translation: 本公开的一个实施方案涉及一种制造光纤的方法，包括以下步骤：（i）将二氧化硅基预型体暴露于具有烟炱密度的至少一个多孔玻璃区域; 涉及在掺杂温度Tdop下包括具有SiCl 4摩尔分数ySiCl 4的SiCl 4的气体混合物，使得参数X大于0.03以形成经氯处理的预成型体，其中X = 11 + [（＆rgr; s - ＆rgr;）0.209748 T dop Exp] [ - 5435.33 / T dop] y SiClü务4 3/4]和＆rgr; s是完全致密的烟灰层的密度; 和（ii）将氯处理的预制件暴露于高于1400℃的温度下，以完全烧结预成型件，以制备具有氯掺杂区域的烧结光纤预制件; 和（iii）从烧结的光学预型件拉制光纤。

公开(公告)号：US11125937B2

公开(公告)日：2021-09-21

申请号：US16124775

申请日：2018-09-07

Applicant: Corning Incorporated

Inventor： Dana Craig Bookbinder ,  Paul Andrew Chludzinski ,  Brian Lee Harper ,  Ming-Jun Li ,  Snigdharaj Kumar Mishra ,  Sonya Marie Raney ,  Pushkar Tandon

IPC: C03B37/014 ,  C03B37/018 ,  C03B37/025 ,  G02B6/028 ,  G02B6/02 ,  G02B6/036

Abstract: An optical fiber with low attenuation and methods of making same are disclosed. The optical fiber has a core, an inner cladding surround the core, and an outer cladding surrounding the inner cladding. The outer cladding is chlorine-doped such that the relative refractive index varies as a function of radius. The radially varying relative refractive index profile of the outer cladding reduces excess stress in the core and inner cladding, which helps lower fiber attenuation while also reducing macrobend and microbend loss. A process of fabricating the optical fiber includes doping an overclad soot layer of a soot preform with chlorine and then removing a portion of the chlorine dopant from an outermost region of the overclad soot layer. The soot preform with the modified chlorine dopant profile is then sintered to form a glass preform, which can then be used for drawing the optical fiber.

公开(公告)号：US20190004245A1

公开(公告)日：2019-01-03

申请号：US16124775

申请日：2018-09-07

Applicant: Corning Incorporated

Inventor： Dana Craig Bookbinder ,  Paul Andrew Chludzinski ,  Brian Lee Harper ,  Ming-Jun Li ,  Snigdharaj Kumar Mishra ,  Sonya Marie Raney ,  Pushkar Tandon

IPC: G02B6/028 ,  C03B37/014 ,  C03B37/018 ,  G02B6/02 ,  G02B6/036 ,  C03B37/025

Abstract: An optical fiber with low attenuation and methods of making same are disclosed. The optical fiber has a core, an inner cladding surround the core, and an outer cladding surrounding the inner cladding. The outer cladding is chlorine-doped such that the relative refractive index varies as a function of radius. The radially varying relative refractive index profile of the outer cladding reduces excess stress in the core and inner cladding, which helps lower fiber attenuation while also reducing macrobend and microbend loss. A process of fabricating the optical fiber includes doping an overclad soot layer of a soot preform with chlorine and then removing a portion of the chlorine dopant from an outermost region of the overclad soot layer. The soot preform with the modified chlorine dopant profile is then sintered to form a glass preform, which can then be used for drawing the optical fiber.

公开(公告)号：US20180079677A1

公开(公告)日：2018-03-22

申请号：US15702961

申请日：2017-09-13

Applicant: Corning Incorporated

Inventor： Dana Craig Bookbinder ,  Paul Andrew Chludzinski ,  Brian Lee Harper ,  Ming-Jun Li ,  Snigdharaj Kumar Mishra ,  Sonya Marie Raney ,  Pushkar Tandon

IPC: C03B37/014 ,  C03B37/018 ,  G02B6/036 ,  G02B6/028 ,  G02B6/02

CPC classification number: G02B6/0286 ,  C03B37/01413 ,  C03B37/01446 ,  C03B37/01466 ,  C03B37/018 ,  C03B37/025 ,  C03B2201/08 ,  C03B2201/20 ,  C03B2207/70 ,  G02B6/02214 ,  G02B6/0283 ,  G02B6/03627 ,  G02B6/03644

Abstract: An optical fiber with low attenuation and methods of making same are disclosed. The optical fiber has a core, an inner cladding surround the core, and an outer cladding surrounding the inner cladding. The outer cladding is chlorine-doped such that the relative refractive index varies as a function of radius. The radially varying relative refractive index profile of the outer cladding reduces excess stress in the core and inner cladding, which helps lower fiber attenuation while also reducing macrobend and microbend loss. A process of fabricating the optical fiber includes doping an overclad soot layer of a soot preform with chlorine and then removing a portion of the chlorine dopant from an outermost region of the overclad soot layer. The soot preform with the modified chlorine dopant profile is then sintered to form a glass preform, which can then be used for drawing the optical fiber.

公开(公告)号：US20150225280A1

公开(公告)日：2015-08-13

申请号：US14467369

申请日：2014-08-25

Applicant: Corning Incorporated

Inventor： Brian Lee Harper ,  Rostislav Radiyevich Khrapko ,  Snigdharaj Kumar Mishra ,  Sonya Marie Raney ,  Pushkar Tandon

IPC: C03B37/014

CPC classification number: C03B37/01446 ,  C03B37/014 ,  C03B37/01453 ,  C03B2201/08 ,  C03B2201/12 ,  C03B2201/20 ,  C03B2201/31 ,  C03B2203/22 ,  C03B2203/23 ,  C03B2203/26 ,  C03C13/045 ,  C03C2201/11 ,  C03C2201/20

Abstract: One embodiment of the disclosure relates to a method of making an optical fiber comprising the steps of: (i) exposing a silica based preform with at least one porous glass region having soot density of ρ to a gas mixture comprising SiCl4 having SiCl4 mole fraction ySiCl4 at a doping temperature Tdop such that parameter X is larger than 0.03 to form the chlorine treated preform, wherein X = 1 1 + [ ( ρ ρ s - ρ )  0.209748  T dop  Exp  [ - 5435.33 / T dop ] y SiCl   4 3 / 4 ] and ρs is the density of the fully densified soot layer; and (ii) exposing the chlorine treated preform to temperatures above 1400° C. to completely sinter the preform to produce sintered optical fiber preform with a chlorine doped region; and (iii) drawing an optical fiber from the sintered optical preform.

Abstract translation: 本公开的一个实施方案涉及一种制造光纤的方法，包括以下步骤：（i）将二氧化硅基预型体暴露于具有烟炱密度的至少一个多孔玻璃区域; 在掺杂温度Tdop下将SiCl 4的SiCl 4摩尔分数为ySiCl4的气体混合物混合，使得参数X大于0.03以形成经氯处理的预制件，其中X = 11 + [（＆rgr; s - ＆rgr;））0.209748 [... 5435.33 / T dop] y SiCl 4 3/4]和＆rgr; s是完全致密的烟灰层的密度; 和（ii）将氯处理的预制件暴露于高于1400℃的温度下，以完全烧结预成型件，以制备具有氯掺杂区域的烧结光纤预制件; 和（iii）从烧结的光学预型件拉制光纤。