THREE-DIMENSIONAL COMPOSITE METALLIC LITHIUM NEGATIVE ELECTRODE, METALLIC LITHIUM BATTERY AND APPARATUS

    公开(公告)号:US20220149353A1

    公开(公告)日:2022-05-12

    申请号:US17583084

    申请日:2022-01-24

    Abstract: A three-dimensional composite metallic lithium negative electrode, a metallic lithium battery and an apparatus are disclosed. The composite metallic lithium negative electrode includes metallic lithium particles and a three-dimensional polymer framework, where the metallic lithium particles are filled in the three-dimensional polymer framework, and the three-dimensional polymer framework includes lithium-philic a fragments, active sites and polymer-containing moieties. The present application improves a volume effect of the metallic lithium negative electrode in charge and discharge process, which can inhibit side reactions of metallic lithium and electrolyte; increase a specific surface area of the metallic lithium negative electrode, and introduce lithium-philic nano-sites, thereby can guide a uniform deposition of the metallic lithium and effectively inhibit generation of lithium dendrites. In addition, the three-dimensional framework coated with active lithium can effectively reduce risks of brittle SEI film faced by traditional solutions.

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