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公开(公告)号：US20180072873A1
公开(公告)日：2018-03-15
申请号：US15565618
申请日：2016-04-04
发明人： Sebastian HÖEROLD , Elke SCHLOSSER
CPC分类号： C08K13/04 , C08K5/5313 , C08K5/5317 , C08K5/5399 , C09K21/12 , C08K5/0066 , C08L77/00
摘要： The invention relates to a flame-retardant polyamide composition comprising as component A) 1 to 96 wt % of one or more thermoplastic polyamides, as component B) 2 to 25 wt % of a dialkylphosphinic salt of the formula (I), and/or of a diphosphinic salt of the formula (II), and/or of polymers thereof, in which R1 and R2 are identical or different and are C1-C6-alkyl, linear, or branched, or H; R3 is C1-C10-alkylene, linear, or branched, C6-C10-arylene, C7-C20-alkylarylene, or C7-C20-arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; x is 1 to 4, as component C) 1 to 20 wt % of a salt of phosphorous acid, as component D) 1 to 20 wt % of a phosphazene, as component E) 0 to 50 wt % of filler or reinforcing agent, as component F) 0 to 1 wt % of a phosphonite or of a mixture of a phosphonite and a phosphite, and as component G) 0 to 1 wt % of an ester or salt of long-chain aliphatic carboxylic acids (fatty acids), which typically have chain lengths of C14 to C40, the sum of the components always being 100 wt %.
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公开(公告)号：US20180072865A1
公开(公告)日：2018-03-15
申请号：US15560459
申请日：2016-03-18
IPC分类号： C08K5/00 , C09K21/12 , C08K5/5313 , C07F9/30
CPC分类号： C08K5/0066 , C07F9/301 , C07F9/305 , C08J2300/22 , C08J2300/24 , C08K5/5313 , C08K2201/014 , C08L2201/02 , C09K21/12
摘要： Flame retardant mixtures comprising as component (A) 30% to 99.9% by weight of dialkylphosphinic salts of the formula (II), a and b may be the same or different and are each independently 1 to 9, and where the carbon chains may be linear, branched or cyclic and M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base and m is 1 to 4, as component (B) 0.1% to 70% by weight of alkyl hydroxyalkylphosphinyl organylcarboxylic acid salts and/or ester salts of the formula (I) where R1CyH2y+1 with y=2 to 8, R2, R3, R4, R5, R6 are the same or different and are each independently H, CxH2x+1, CxH2x−1, CxH2x−3, CxH2xCO2X, CxH2x−2CO2X, CxH2x−4CO2X, (C2H3CO2X)u and u=0 to 1000000, CO2X, CxH2x(P(O)(OM)R1), CxH2x−2(P(O)(OM)R1)(CO2X) and/or CH2CO2X, where, in the R1, R2, R3, R4, R5 and R6 groups, the carbon chains may be linear, branched or cyclic, M′ is Mg, Ca, Al, Sb, Sn, Ge, Fe, Ti, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na, K, H and/or N-containing cations, x is 1 to 25, X is H, M, CzH2z+1 and z is 1 to 8, with the proviso that at least one of the R2, R3, R4, R5, R6 groups is not H, and the compounds of formula (II) and formula (I) are different compounds.
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