公开(公告)号：US06337370B1

公开(公告)日：2002-01-08

申请号：US09585866

申请日：2000-06-01

申请人： Byeong Soo Bae ,  Yoon Ki Choi ,  Young Joo Eo ,  Oun Ho Park

发明人： Byeong Soo Bae ,  Yoon Ki Choi ,  Young Joo Eo ,  Oun Ho Park

IPC分类号： C08G7708

CPC分类号： C09D183/10 ,  C08F8/42 ,  C08G77/442 ,  C08G77/58 ,  C08F16/06

摘要： Disclosed are inorganic-organic copolymers and their preparation using polyvinylalcohol-silane coupling agents. The inorganic-organic copolymers can be prepared through the reaction of silane-coupling agents containing hydroxy groups and silane groups with organic metal compounds. The inorganic-organic copolymers are of high transparency as well as shows superb moisture barrier characteristics and hydrophilicity and can be applied as resins or film coatings for many fields, including anti-fogging agents, anti-foaming agents, lubricants, paints, anti-corrosive coatings, water-resistant coatings, plastic or metal-protective coatings.

摘要翻译： 公开了无机 - 有机共聚物及其使用聚乙烯醇 - 硅烷偶联剂的制备方法。 无机 - 有机共聚物可以通过含有羟基和硅烷基团的硅烷偶联剂与有机金属化合物的反应来制备。 无机 - 有机共聚物具有高透明度，并具有极好的防潮性和亲水性，可用作多种领域的树脂或薄膜涂料，包括防雾剂，消泡剂，润滑剂，油漆，防腐剂 涂料，防水涂料，塑料或金属保护涂料。

公开(公告)号：US06465671B1

公开(公告)日：2002-10-15

申请号：US09480302

申请日：2000-01-10

申请人： Byeong Soo Bae ,  Yoon Ki Choi ,  Young Joo Eo ,  Oun Ho Park

发明人： Byeong Soo Bae ,  Yoon Ki Choi ,  Young Joo Eo ,  Oun Ho Park

IPC分类号： C07F710

CPC分类号： C07F7/1804

摘要： Disclosed herein are a silane coupling agent and a method of preparing the same useful for a composite organic-inorganic material. The silane coupling agent is represented by the formula of R1R2R3Si—X, wherein R1, R2, and R3, respectively, represent straight or branched alkyl having 4 to 22 carbon atoms, alkoxy, phenyl, phenyl alkoxy, benzyloxy or phenyl alkyl group. The method comprises the steps of: dissolving a vinyl derivative in a solvent under a nitrogen or argon atmosphere; and reacting the resulting solution with an alkoxysilane derivative at a temperature of 20 to 200° C. for 1 to 72 hours in the presence of a metal catalyst. Alternatively, the method comprises the steps of: dissolving alkylmagnesium halide in a solvent under a nitrogen or argon; and reacting the resulting solution with haloalkoxysilane at a temperature of −78° C. to 50° C. for 0.1 to 5 hours.

摘要翻译： 本文公开了一种硅烷偶联剂及其制备方法，可用于复合有机 - 无机材料。 硅烷偶联剂由式R 1 R 2 R 3 Si-X表示，其中R 1，R 2和R 3分别表示具有4至22个碳原子的直链或支链烷基，烷氧基，苯基，苯基烷氧基，苄氧基或苯基烷基。 该方法包括以下步骤：在氮气或氩气氛下将乙烯基衍生物溶解在溶剂中; 并使所得溶液与烷氧基硅烷衍生物在20〜200℃的温度下在金属催化剂存在下反应1〜72小时。 或者，该方法包括以下步骤：在氮气或氩气下将烷基卤化镁溶解在溶剂中; 并将所得溶液与卤代烷氧基硅烷在-78℃至50℃的温度下反应0.1至5小时。