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    Metal Fluoride Electrode Protection Layer and Method of Making Same
    1.
    发明申请
    Metal Fluoride Electrode Protection Layer and Method of Making Same 审中-公开
    金属氟化物电极保护层及其制作方法

    公开(公告)号：US20140234536A1

    公开(公告)日：2014-08-21

    申请号：US14263713

    申请日：2014-04-28

    申请人： Battelle Memorial Institute

    发明人： Wu Xu ,  Wei Wang ,  Zhenguo Yang ,  Jiguang Zhang ,  Daiwon Choi

    IPC分类号： H01M4/04 ,  H01M4/36 ,  H01M4/485

    CPC分类号： H01M4/0471 ,  H01M4/04 ,  H01M4/13 ,  H01M4/366 ,  H01M4/386 ,  H01M4/387 ,  H01M4/485 ,  H01M4/626 ,  H01M4/628 ,  H01M10/0525

    摘要： Modifications to the surface of an electrode and/or the surfaces of the electrode material can improve battery performance. For example, the modifications can improve the capacity, rate capability and long cycle stability of the electrode and/or may minimize undesirable catalytic effects. In one instance, metal-ion batteries can have an anode that is coated, at least in part, with a metal fluoride protection layer. The protection layer is preferably less than 100 nm in thickness. The anode material is fabricated according to methods that result in improved anode performance.

    摘要翻译： 对电极表面和/或电极材料的表面的修改可以提高电池性能。 例如，这些修改可以提高电极的容量，速率能力和长周期稳定性和/或可以最小化不期望的催化作用。 在一种情况下，金属离子电池可以具有至少部分地用金属氟化物保护层涂覆的阳极。 保护层的厚度优选小于100nm。 根据导致阳极性能改善的方法制造阳极材料。

    Iron-Sulfide Redox Flow Batteries
    5.
    发明申请
    Iron-Sulfide Redox Flow Batteries 有权
    铁硫化物氧化还原液流电池

    公开(公告)号：US20140079976A1

    公开(公告)日：2014-03-20

    申请号：US14079135

    申请日：2013-11-13

    申请人： BATTELLE MEMORIAL INSTITUTE

    发明人： Guanguang Xia ,  Zhenguo Yang ,  Liyu Li ,  Soowhan Kim ,  Jun Liu ,  Gordon L. Graff

    IPC分类号： H01M8/18 ,  H01M8/20

    CPC分类号： H01M8/188 ,  H01M2/1653 ,  H01M4/9083 ,  H01M4/926 ,  H01M4/96 ,  H01M8/18 ,  H01M8/20 ,  Y02E60/528

    摘要： Iron-sulfide redox flow battery (RFB) systems can be advantageous for energy storage, particularly when the electrolytes have pH values greater than 6. Such systems can exhibit excellent energy conversion efficicency and stability and can utilize low-cost materials that are relatively safer and more environmentally friendly. One example of an iron-sulfide RFB is characterized by a positive electrolyte that comprises Fe(III) and/or Fe(II) in a positive electrolyte supporting solution, a negative electrolyte that comprises S2− and/or S in a negative electrolyte supporting solution, and a membrane, or a separator, that separates the positive electrolyte and electrode from the negative electrolyte and electrode.

    摘要翻译： 硫化铁氧化还原液流电池（RFB）系统对于能量储存可能是有利的，特别是当电解质具有大于6的pH值时，这些系统可表现出优异的能量转换效率和稳定性，并且可以利用相对更安全的低成本材料 更环保。 硫化铁RFB的一个实例的特征在于在正电解质支持溶液中包含Fe（III）和/或Fe（II）的正电解质，负电解质，其包含负电解质支持中的S2-和/或S 溶液以及将正电解质和电极与负电解质和电极分离的膜或隔膜。

    Method of preparing graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes
    7.
    发明授权
    Method of preparing graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes 有权
    制备用于可再充电锂硫电池电极的石墨烯 - 硫磺纳米复合材料的方法

    公开(公告)号：US08999574B2

    公开(公告)日：2015-04-07

    申请号：US14225561

    申请日：2014-03-26

    申请人： Battelle Memorial Institute

    发明人： Jun Liu ,  John P. Lemmon ,  Zhenguo Yang ,  Yuliang Cao ,  Xiaolin Li

    IPC分类号： H01M4/04 ,  B82Y30/00 ,  H01M4/136 ,  H01M4/1397 ,  H01M4/58 ,  H01M4/62 ,  H01M10/052

    CPC分类号： H01M4/049 ,  B82Y30/00 ,  H01M4/136 ,  H01M4/1397 ,  H01M4/5815 ,  H01M4/623 ,  H01M10/052 ,  Y02E60/122 ,  Y10S977/734 ,  Y10S977/773 ,  Y10S977/84

    摘要： A method of preparing a graphene-sulfur nanocomposite for a cathode in a rechargeable lithium-sulfur battery comprising thermally expanding graphite oxide to yield graphene layers, mixing the graphene layers with a first solution comprising sulfur and carbon disulfide, evaporating the carbon disulfide to yield a solid nanocomposite, and grinding the solid nanocomposite to yield the graphene-sulfur nanocomposite. Rechargeable-lithium-sulfur batteries having a cathode that includes a graphene-sulfur nanocomposite can exhibit improved characteristics. The graphene-sulfur nanocomposite can be characterized by graphene sheets with particles of sulfur adsorbed to the graphene sheets. The sulfur particles have an average diameter of less than 50 nm.

    摘要翻译： 一种制备用于可再充电锂硫电池中的阴极的石墨烯 - 硫磺纳米复合材料的方法，包括热膨胀石墨烯氧化物以产生石墨烯层，将石墨烯层与包含硫和二硫化碳的第一溶液混合，蒸发二硫化碳，产生 固体纳米复合材料，研磨固体纳米复合材料，得到石墨烯 - 硫磺纳米复合材料。 具有包含石墨烯 - 硫磺纳米复合材料的阴极的可充电锂硫电池可以表现出改进的特性。 石墨烯 - 硫磺纳米复合材料可以用石墨烯片表征，其中硫的颗粒吸附到石墨烯片上。 硫颗粒的平均直径小于50nm。

    Iron-sulfide redox flow batteries
    10.
    发明授权
    Iron-sulfide redox flow batteries 有权
    硫化铁氧化还原液电池

    公开(公告)号：US09368824B2

    公开(公告)日：2016-06-14

    申请号：US14079135

    申请日：2013-11-13

    申请人： BATTELLE MEMORIAL INSTITUTE

    发明人： Guanguang Xia ,  Zhenguo Yang ,  Liyu Li ,  Soowhan Kim ,  Jun Liu ,  Gordon L Graff

    IPC分类号： H01M8/18 ,  H01M2/16 ,  H01M4/90 ,  H01M4/92 ,  H01M4/96 ,  H01M8/20

    CPC分类号： H01M8/188 ,  H01M2/1653 ,  H01M4/9083 ,  H01M4/926 ,  H01M4/96 ,  H01M8/18 ,  H01M8/20 ,  Y02E60/528

    摘要： Iron-sulfide redox flow battery (RFB) systems can be advantageous for energy storage, particularly when the electrolytes have pH values greater than 6. Such systems can exhibit excellent energy conversion efficiency and stability and can utilize low-cost materials that are relatively safer and more environmentally friendly. One example of an iron-sulfide RFB is characterized by a positive electrolyte that comprises Fe(III) and/or Fe(II) in a positive electrolyte supporting solution, a negative electrolyte that comprises S2− and/or S in a negative electrolyte supporting solution, and a membrane, or a separator, that separates the positive electrolyte and electrode from the negative electrolyte and electrode.

    摘要翻译： 硫化铁氧化还原液流电池（RFB）系统对于储能可能是有利的，特别是当电解质的pH值大于6时，这种系统可表现出优异的能量转换效率和稳定性，并且可以利用相对更安全的低成本材料， 更环保。 硫化铁RFB的一个实例的特征在于在正电解质支持溶液中包含Fe（III）和/或Fe（II）的正电解质，负电解质，其包含负电解质支持中的S2-和/或S 溶液以及将正电解质和电极与负电解质和电极分离的膜或隔膜。