公开(公告)号：US3920702A

公开(公告)日：1975-11-18

申请号：US38688873

申请日：1973-08-09

申请人： BAYER AG

发明人： KROCK FRIEDRICH WILHELM ,  NEEFF RUTGER

IPC分类号： C09B1/54 ,  D06P1/90 ,  C07D319/06 ,  C07D317/28 ,  C07D317/72

CPC分类号： D06P1/908 ,  C09B1/503 ,  C09B1/545 ,  Y10S8/921 ,  Y10S8/922

摘要： Anthraquinone dyestuffs of the formula

IN WHICH Y denotes a direct bond or an alkylene group which can be interrupted by hetero-atoms or sulphone groups, A denotes an alkylene group of the formula

B denotes a direct bond or a group of the formula

R1-R7 denotes hydrogen, alkyl or aryl, X1 and X2 denote oxygen or sulphur and Z1 and Z2 denote hydrogen or halogen and their use for the dyeing and printing of synthetic fibre materials. Dyeings obtained are distinguished by good build-up, high colour yield and excellent fastness properties, especially good fastness to light, sublimation and wet processing.

公开(公告)号：US3705178A

公开(公告)日：1972-12-05

申请号：US3705178D

申请日：1969-12-30

申请人： BAYER AG

发明人： PETERS KARL-HEINZ ,  NEEFF RUTGER

IPC分类号： C09B1/32 ,  C07C87/64

CPC分类号： C09B1/32

摘要： A pigment, 1,5-bis-(2-nitroanilino)- anthraquinone has been prepared.

摘要翻译： 已经制备了1,5-双（2-硝基苯胺基） - 蒽醌颜料。

公开(公告)号：US3560491A

公开(公告)日：1971-02-02

申请号：US3560491D

申请日：1967-07-10

申请人： BAYER AG

发明人： NEEFF RUTGER

IPC分类号： C09B1/20 ,  C09B1/58 ,  C09B5/04 ,  C09B5/14 ,  C09B5/16 ,  C07C97/12

CPC分类号： C09B1/205 ,  C09B1/58 ,  C09B5/04 ,  C09B5/14 ,  C09B5/16

摘要： THIS INVENTION CONCERNS ANTHRAQUINONE DYESTUFFS OF THE FORMULA

A(-NH-CH=C(-CN)-CO-N(-R1)-R2)N

WHEREIN A IS AN ANTHRAQUINONE RADICAL, N IS AN INTEGER FROM 1 TO 4 AND R1 AND R2 COMPLETE THE RESIDUE OF ALIPHATIC OF HETEROCYCLIC AMINES. THE DYESTUFFS ARE PREPARED BY REACTION OF THE APPROPRIATE CYANOACETIC ACID AMIDE WITH N-ANTHRAQUINONYL-N-FORMAMIDIUM SALTS. THESE DYESTUFFS ARE USEFUL FOR DYING OR PRINTING OF TEXTILES.

公开(公告)号：US3699126A

公开(公告)日：1972-10-17

申请号：US3699126D

申请日：1969-06-25

申请人： BAYER AG

发明人： PETERS KARL-HEINZ ,  NEEFF RUTGER

IPC分类号： C09B1/36 ,  C09B27/00 ,  C09B43/12 ,  C09B43/124 ,  C09B43/36 ,  C09B56/12 ,  C07C49/68 ,  C07D63/04

CPC分类号： C09B56/12 ,  C09B1/36 ,  C09B27/00 ,  C09B43/12 ,  C09B43/124 ,  C09B43/36

摘要： DYESTUFFS OF THE FORMULAE

1-(R-NH-),4-(Y-NH-),DI((Z)(0-2)-)ANTHRAQUINONE (I)

1-(R-NH-),4-Y1,5,8-DI(X-),DI((Z)(0-2)-)ANTHRAQUINONE (II)

AND 1,4-DI(R-NH-),DI((Z)(O-2)-)ANTHRAQUINONE (III)

WHEREIN Z IS A SUBSTITUENT, ONE X IS A MEMBER NHR AND THE OTHER IS HYDROGEN OR A SUBSTITUTED Z, Y IS AN OPTIONALLY SUBSTITUTED HYDROCARBON RESIDUE OR AN ACYL GROUP, Y1 IS HYDROGEN OR A SUBSTITUENT, AND R IS A MOIETY

CO-B-CO-NH-E

WHERE B IS A BOND, SATURATED OR UNSATURATED ALKYLENE WITH OR WITHOUT HETERO ATOMS AND SUBSTITUENTS, MONO OR POLYNUCLEAR ARYLENE WITH OR WITHOUT SUBSTITUENTS, CYCLOALKYLENE WITH OR WITHOUT SUBSTITUENTS OR HETEROARYLENE WITH OR WITHOUT SUBSTITUENTS AND E IS A RADICAL B OR AN ARALKYL GROUP; AS WELL AS THEIR PREPARATION AND USE AS PIGMENTS THE NOVEL DYESTUFFS ARE PIGMENT DYESTUFFS AND FREE OF SULFONIC ACID AND CARBOXYLIC ACID GROUPS.

公开(公告)号：US3557154A

公开(公告)日：1971-01-19

申请号：US3557154D

申请日：1966-07-29

申请人： BAYER AG

发明人： NEEFF RUTGER ,  GOHRBANDT WILHELM ,  KUTH ROBERT

IPC分类号： C09B1/503 ,  C09B1/54 ,  C09B1/58 ,  C09B1/50 ,  C09B1/52 ,  C09B1/56

CPC分类号： C09B1/503 ,  C09B1/50 ,  C09B1/542 ,  C09B1/58 ,  D06P1/20 ,  D06P3/26 ,  D06P3/42 ,  D06P3/48 ,  D06P3/54 ,  D06P3/72 ,  D06P3/794 ,  Y10S8/922

摘要： 1,4,5-TRIAMINO-8-HYDROXY ANTHRAQUINONE DYESTUFFS FOR POLYESTERS AND POLYAMIDES CONTAINING SUBSTITUTED 2 AND/OR 3 POSITIONS WHEREIN ONE OF SAID POSITIONS CONTAINS A SUBSTITUENT SELECTED FROM THE GROUP CONSISTING OF SUBSTITUTED OR UNSUBSTITUTED ALKYL, ARYL, AND ARALKYL GROUPS LINKED TO THE ANTHROQUINONE NUCLEUS THROUGH A BRIDGE SELECTED FROM THE GROUP CONSISTING OF O, S, SO, AND SO2, ARE PREPARED BY REACTING A CYCLIC SULFAMIDE OR CYCLIC SULFIMIDE ESTER WITH SULPHUR IN OLEUM.

公开(公告)号：US3489773A

公开(公告)日：1970-01-13

申请号：US3489773D

申请日：1966-05-09

申请人： BAYER AG

发明人： NEEFF RUTGER ,  ZENNER KARL-FRIEDRICH ,  GOHRBANDT WILHELM ,  KUTH ROBERT

IPC分类号： C09B1/36 ,  C09B1/38 ,  C09B1/516 ,  C09B1/54 ,  C09B1/58 ,  C09B5/02 ,  C07D63/04 ,  C09B1/56

CPC分类号： C09B5/02 ,  C09B1/36 ,  C09B1/38 ,  C09B1/516 ,  C09B1/542 ,  C09B1/58 ,  Y10S8/921 ,  Y10S8/922

摘要： The invention comprises dyes of formula wherein A is an anthraquinone radical which may be further substituted by a substituent which does not increase water-solubility and which preferably contains up to 4 condensed rings, R is H or CH3 and n is 1 or 2. The dyes are prepared by (a) condensing an aminoanthraquinone with an optionally methyl-substituted N - 3 - tetramethylene - sulphone - carbamic acid chloride or -isocyanate or (b) condensing an N-anthraquinonyl-carbamic acid chloride or -urethane with an optionally methyl -substituted 3 - amino - tetramethylene-sulphone. The dyes are used to colour synthetic fibre materials such as polyamides, polyurethane, polyacrylonitrile, polyester or cellulose ester fibres in yellow, orange, red and blue shades.

公开(公告)号：US3906011A

公开(公告)日：1975-09-16

申请号：US44082974

申请日：1974-02-08

申请人： BAYER AG

发明人： AUGE WOLFGANG ,  THIEM KARL-WERNER ,  NEEFF RUTGER

IPC分类号： C07C205/47 ,  C07C20060101 ,  C07C67/00 ,  C07C201/00 ,  C09B20060101 ,  C09B1/00 ,  C07C79/37

CPC分类号： C07C225/34

摘要： Preparation of 1,5- and/or 1,8-dinitroanthraquinone, characterised in that 1,5-dinitroanthraquinone is directly precipitated from the anthraquinone nitration mixtures by a adjusting the molar fraction of nitric acid to a value of gamma HNO 0.90 to 0.68 at molar ratios of nitric acid: dinitroanthraquinone of 10:1 to 80:1; 1,8-dinitroanthraquinone is then precipitated from the filtrate by adjusting the molar fraction of nitric acid to a value of gamma HNO 0.80 to 0.50 at molar ratios of nitric acid:dinitroanthraquinone of 10:1 to 80:1.

摘要翻译： 1,5-和/或1,8-二硝基蒽醌的制备，其特征在于通过将硝酸的摩尔分数调节至γHNO + 293 = 0.90的值，从蒽醌硝化混合物中直接沉淀出1,5-二硝基蒽醌 至硝酸：二硝基蒽醌的摩尔比为0.68：10：1至80：1; 当硝酸：二硝基蒽醌的摩尔比为10:1至80:1时，通过将硝酸的摩尔分数调节至γHNO + 293 = 0.80至0.50的值，然后从滤液中沉淀出1,8-二硝基蒽醌。

公开(公告)号：US3499896A

公开(公告)日：1970-03-10

申请号：US3499896D

申请日：1967-06-08

申请人： BAYER AG

发明人： NEEFF RUTGER

IPC分类号： C09B1/46 ,  C09B62/06 ,  C07D55/20

CPC分类号： C09B62/06 ,  C09B1/46 ,  Y10S8/922

公开(公告)号：US3489776A

公开(公告)日：1970-01-13

申请号：US3489776D

申请日：1967-01-03

申请人： BAYER AG

发明人： PETERS KARL-HEINZ ,  NEEFF RUTGER

IPC分类号： C09B1/503 ,  C09B1/50

CPC分类号： C09B1/503 ,  Y10S8/922

公开(公告)号：US3907838A

公开(公告)日：1975-09-23

申请号：US49973374

申请日：1974-08-22

申请人： BAYER AG

发明人： THIEM KARL-WERNER ,  AUGE WOLFGANG ,  NEEFF RUTGER

IPC分类号： C07C225/34 ,  C07B20060101 ,  C07C20060101 ,  C09B1/22 ,  C07C97/24

CPC分类号： C07C225/34

摘要： A 1-amino anthraquinone substantially free of diamino anthraquinone is prepared as follows: 1. Nitrating anthraquinone or a mixture which contains anthraquinone with concentrated nitric acid at a temperature of at least -20*C, the mole ratio of nitric acid to anthraquinone being at least 4:1; 2. Stopping the reaction when the anthraquinone conversion is at least 50% by cooling the reaction mixture to below 30*C and/or by adjusting the mole fraction of nitric acid to a value of 0.86 or less; 3. Precipitating 1-nitroanthraquinone by adjusting the mole ratio of nitric acid to a value of from 0.7 to 0.4 and/or by cooling the reaction mixture to a temperature of below 20*C; 4. Converting the precipitated 1-nitroanthraquinone into the corresponding 1-aminoanthraquinone; and 4. Subjecting the reaction product to vacuum distillation.

摘要翻译： 基本上不含二氨基蒽醌的1-氨基蒽醌制备如下：