Abstract:
Aromatic sulphinic acids and their salts are used as activators for lowering the decomposition temperature of azodicarbonamide, which have a higher activity than the conventional auxiliary blowing agents. Moreover, no premature liberation of gas takes place.
R REPRESENTS AN ALKYL RADICAL OPTIONALLY SUBSTITUTED BY CHLORINE, A CYCLOALKYL RADICAL, AN ARYL RADICAL OPTIONALLY SUBSTITUTED BY AT LEAST ONE ALKYL GROUP AND/OR CHLORINE ATOM, AN ARALKYL RADICAL OR A DIALKYLAMINO GROUP, R1 REPRESENTS AN ARYL RADICAL OPTIONALLY SUBSTITUTED BY AT LEAST ONE ALKYL GROUP AND/OR CHLORINE ATOM, AND X REPRESENTS CHLORINE OR FLORINE ARE USED AS VULCANIZATION RETARDERS INNATURAL AND/OR SYNTHETIC RUBBER MIXTURES. ONE OF THESE VULCANIZATION RETARDERS OF THE AFOREMENTIONED GENERAL FORMULA IS NPHENYL - N -(TRICHLOROMETHYLSULPHENYL) - METHYLSULPHONAMIDE.
Abstract:
N,N''-thio-bis-carbamic acid amides, their preparation by reacing at least 2 mols of a carboxylic acid amide with 1 mol of sulphur dichloride in the presence of an acid binding agent and their utility as rubber vulcanization retarders.