公开(公告)号：US10899705B2

公开(公告)日：2021-01-26

申请号：US16614599

申请日：2018-05-23

Applicant: BASF SE

Inventor： Jan Spielmann ,  Michael Zeilinger ,  Juergen Wortmann ,  Frieder Borgmeier

IPC: C07C317/04 ,  C07C315/06 ,  C07C303/06 ,  C07C303/44 ,  C07C309/04

Abstract: The present invention relates to a process for the manufacturing of methane sulfonic acid (MSA) by reaction of a radical initiator composition with methane and sulfur trioxide comprising the steps (a) preparation of the intiator composition by reacting aqueous hydrogen peroxide with the components methane sulfonic acid and methane sulfonic acid anhydride and (b) reaction of the initiator composition from step (a) with sulfur trioxide and methane to form methane sulfonic acid. The invention further relates to the use of methane sulfonic acid anhydride (MSA anhydride) in said process and to methane sulfonic acid manufactured by said process.

公开(公告)号：US10894766B2

公开(公告)日：2021-01-19

申请号：US16618283

申请日：2018-05-23

Applicant: BASF SE

Inventor： Jan Spielmann ,  Juergen Wortmann ,  Frieder Borgmeier ,  Michael Zeilinger ,  Rosario Mazarro Berdonces ,  Bjoern Kaibel

IPC: C07C317/04 ,  C07C315/06 ,  C07C303/06 ,  C07C303/44 ,  C07C309/04

Abstract: The present invention deals with a process for the production of alkanesulfonic acids, in particular methanesulfonic acid, and a method of purification of the raw products.

公开(公告)号：US10214485B2

公开(公告)日：2019-02-26

申请号：US15774722

申请日：2016-11-08

Applicant: BASF SE

Inventor： Jan Spielmann ,  Michael Koch ,  Juergen Wortmann ,  Sabine Weiguny ,  Feelly Ruether ,  Robert Sengpiel

IPC: C07C303/44

Abstract: The invention relates to a method of reprocessing alkanesulfonic acid employed in a chemical process as an agent, catalyst or solvent and comprising the steps of: (a) removing an alkanesulfonic acid-comprising stream from a reaction mixture generated in the chemical process, (b) feeding the alkanesulfonic acid-comprising stream into a melt crystallization as the starting melt to form crystals of the alkanesulfonic acid, of hydrates of the alkanesulfonic acid or of a mixture of both suspended in mother liquor, (c) performing a solid-liquid separation to remove the crystals from the mother liquor, (d) optionally washing the crystals to remove mother liquor adhering to the crystals, (e) recycling the washed or unwashed crystals removed from the mother liquor into the chemical process.

公开(公告)号：US11247967B2

公开(公告)日：2022-02-15

申请号：US16963748

申请日：2019-01-30

Applicant: BASF SE

Inventor： Frieder Borgmeier ,  Jan Spielmann ,  Michael Zeilinger ,  Juergen Wortmann

IPC: C07C303/14 ,  C07C303/44

Abstract: A process for manufacturing of an alkanesulfonic acid, and an alkanesulfonic acid manufactured by the process. Aspects of the process may involve manufacturing an alkanesulfonic acid by reaction of an initiator composition with an alkane and sulfur trioxide by preparing an initiator composition by reacting aqueous hydrogen peroxide with alkanesulfonic acid and/or H2SO4; and reacting the initiator composition with sulfur trioxide and alkane to form an alkanesulfonic acid, wherein an alkane with a purity of at least 98.0 mol-% is used.

公开(公告)号：US10730827B2

公开(公告)日：2020-08-04

申请号：US16605973

申请日：2018-04-18

Applicant: BASF SE

Inventor： Juergen Wortmann ,  Jan Spielmann ,  Katharina Federsel ,  Feelly Ruether

IPC: C07C303/44 ,  C07C303/06

Abstract: A process for purifying alkanesulfonic anhydride that includes feeding a stream containing alkanesulfonic anhydride, sulfuric acid, high boilers and residual low boilers into a melt crystallization to form crystals of the alkanesulfonic anhydride suspended in mother liquor, and solid-liquid separation to remove the crystals from the mother liquor.

公开(公告)号：US10577312B2

公开(公告)日：2020-03-03

申请号：US15774847

申请日：2016-11-08

Applicant: BASF SE

Inventor： Jan Spielmann ,  Michael Koch ,  Juergen Wortmann ,  Feelly Ruether ,  Sabine Weiguny ,  Frieder Borgmeier

IPC: C07C303/44 ,  C07C309/01 ,  C07C309/02 ,  C07C309/03 ,  B01D3/14 ,  B01D9/00 ,  B01D3/00

Abstract: A process comprising: (a) distilling a melt comprising crude alkanesulfonic acid to completely or partly remove low boilers, wherein the low boilers are drawn off at the top of a distillation column or of a one-stage evaporation apparatus and a material stream comprising alkanesulfonic acid, high boilers and residual low boilers is withdrawn at the bottom of the distillation column or of the one-stage evaporation apparatus, (b) sending the stream comprising alkanesulfonic acid, high boilers and residual low boilers into a melt crystallization as the starting melt to obtain crystals formed from the alkanesulfonic acid, hydrates of the alkanesulfonic acid or a mixture of both suspended in mother liquor, (c) performing a solid-liquid separation to remove the crystals from the mother liquor, and (d) optionally washing the crystals to remove mother liquor adhering to the crystals.

公开(公告)号：US10570514B2

公开(公告)日：2020-02-25

申请号：US15779570

申请日：2016-11-29

Applicant: BASF SE

Inventor： Falko Abels ,  David Dominique Schweinfurth ,  Karl Matos ,  Daniel Loeffler ,  Maraike Ahlf ,  Florian Blasberg ,  Thomas Schaub ,  Jan Spielmann ,  Axel Kirste ,  Boris Gaspar

IPC: C23C16/455 ,  C23C16/06 ,  C07F9/6584 ,  C07F9/50 ,  C07F7/10 ,  C07F9/52

Abstract: The present invention is in the field of processes for the generation of thin inorganic films on substrates, in particular atomic layer deposition processes. It relates to a process for preparing metal films comprising (a) depositing a metal-containing compound from the gaseous state onto a solid substrate and (b) bringing the solid substrate with the deposited metal-containing compound in contact with a reducing agent in the gaseous state, wherein the reducing agent is or at least partially forms at the surface of the solid substrate a carbene, a silylene or a phosphor radical.