SINGLE CRYSTAL DOPED CATHODE MATERIALS FROM RECYCLED LITHIUM-ION BATTERIES

    公开(公告)号:US20250062341A1

    公开(公告)日:2025-02-20

    申请号:US18940387

    申请日:2024-11-07

    Abstract: In a battery recycling process, a recycling stream including charge material metals from exhausted Li-ion batteries is aggregated or otherwise comminuted to generate recycled battery charge material having comparable or improved cycle life as well as recycled charge material precursor having fewer cracking defects using doping substances in both a coprecipitation phase and a sintering phase of the recycling sequence. Prior to coprecipitation of a cathode material precursor, a leach solution of comingled charge material metals is produced, the ratio of the charge material metals is adjusted based on recycled battery specifications, and a relatively small quantity of a first dopant is added. The doped precursor, a lithium salt, and a second dopant are combined and sintered to form a doped cathode material having a single crystal morphology and a higher tap density than the doped cathode precursor.

    MULTI-STAGE LITHIATION FOR CATHODE MATERIAL

    公开(公告)号:US20250054964A1

    公开(公告)日:2025-02-13

    申请号:US18230938

    申请日:2023-08-07

    Abstract: A Li-ion cathode material is prepared by a multi-stage lithiation process that separates a total amount of lithium called for by the recycled battery to be used in a series of sintering stages. A leaching, ratio adjustment and coprecipitation sequence forms a cathode precursor having a predetermined ratio of metallic elements from a comingled recycling stream of Li-ion batteries. The precursor is sintered with a lithium salt in a sequence of stages, each having a portion of the total lithium quantity, for a predetermined duration and temperature. The initial sintering stage tends to define the crystallinity of the resulting active cathode material and has a particle size determined at least in part by the portion of lithium at each stage.

    MICROSTRUCTURE TUNING OF CATHODE MATERIAL
    6.
    发明公开

    公开(公告)号:US20240287645A1

    公开(公告)日:2024-08-29

    申请号:US18113312

    申请日:2023-02-23

    CPC classification number: C22B7/007 C22B3/22 C22B3/42 H01M10/54

    Abstract: A recycling process for Lithium-ion (Li-ion) batteries includes a selective leach of charge material metals followed by impurity control for effecting microstructures such as a pore volume and surface area for optimal structures and charge performance. Particle characteristics having a favorable effect on performance correlate with soluble impurities in a recycling leach solution formed from spent charge material in a battery recycling stream. Spent batteries yield a black mass of agitated, comingled cathode material, anode material and current collectors. Leaching of the black mass yields a recycling solution of charge material metals and impurities. Selective adjustment of these impurities through adding and/or separating soluble ions in the solution drives formation of internal voids, surface area and pore volume in the resulting cathode material.

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