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公开(公告)号:US20110034353A1
公开(公告)日:2011-02-10
申请号:US12536076
申请日:2009-08-05
IPC分类号: C07D407/02 , C10M129/20 , C09K8/60
CPC分类号: C07F15/025 , C07D273/02 , C07D413/12 , C07D498/08 , C09K8/58 , C09K2208/10 , C10M133/06 , C10M159/18 , C10M2215/042 , C10M2227/09 , C10N2230/12 , C10N2210/08
摘要: A stabilized nano-Fe6-iron-crown ether complex is formed by preparing a solution of an iron salt and an olygomer crown compound in dialkylamine or diethylamine. Sodium tetrahydroboron (NaBH4) and dialkylamine or ethylendiamine are added at a temperature of 0-10° C. The mixture is heated to room temperature and boiled, thereby converting the formed iron (II)-borhydride complex (Fe(BH4)2) to a crown ether—iron-hydride complex [CWFe06].(2H)6. At higher temperature this last complex is converted to the Fe06-crown nanocomposite complex.
摘要翻译: 通过在二烷基胺或二乙胺中制备铁盐和乙二醇化合物冠化合物的溶液形成稳定的纳米Fe 6 - 铁 - 冠醚络合物。 在0-10℃的温度下加入四氢硼酸钠(NaBH 4)和二烷基胺或乙二胺。将混合物加热至室温并煮沸,从而将形成的铁(II) - 硼氢化物络合物(Fe(BH 4)2)转化为 冠醚 - 氢化铁络合物[CWFe06](2H)6。 在较高温度下,最后的复合物转化为Fe06-冠纳米复合物。