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公开(公告)号：US4568433A
公开(公告)日：1986-02-04
申请号：US649570
申请日：1984-09-12
申请人： Yasushi Samejima , Minoru Shiga , Toshiji Kano , Kiyoshi Yamada
发明人： Yasushi Samejima , Minoru Shiga , Toshiji Kano , Kiyoshi Yamada
摘要： An electrolytic process using a horizontal electrolytic cell partitioned by a cation exchange membrane into an anode compartment and a cathode compartment is disclosed which is characterized by supplying into the cathode compartment catholyte liquor at a flow rate satisfying the equation;Y.gtoreq.9 log.sub.10 X+11wherein Y is initial linear velocity (cm/sec) of the catholyte liquor containing no cathode gas or containing cathode gas in an extremely small amount, and X is length (m) of a passageway of the catholyte liquor in the cathode compartment.
摘要翻译： 公开了一种使用由阳离子交换膜分隔成阳极室和阴极室的水平电解槽的电解方法，其特征在于以满足该方程式的流量供入阴极室阴极液; Y> / = 9 log 10X + 11其中，Y是不含阴极气体或含有阴极气体的阴极电解液的初始线速度（cm / sec），X是阴极电解液通道的长度（m） 阴极室中的液体。
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2.发明授权Electrolytic process of an aqueous alkali metal halide solution and electrolytic cell used therefor 失效碱金属卤化物水溶液和用于其的电解池的电解过程
公开(公告)号：US4586994A
公开(公告)日：1986-05-06
申请号：US558661
申请日：1983-12-06
摘要： Disclosed is an electrolytic process using a horizontal type cation exchange membrane electrolytic cell in which catholyte liquor is supplied into a cathode compartment with initial linear velocity of at least 8 cm/sec and gas content of at most 0.6 at a catholyte liquor outlet. Also disclosed is an electrolytic cell used for the foregoing process. The invention enables not only conversion of a mercury electrolytic cell to a cation exchange membrane electrolytic cell with low cost, but the long-term and stable operation.
摘要翻译： 公开了一种使用水平型阳离子交换膜电解池的电解方法，其中阴极电解液在阴极电解液出口处以初始线速度至少为8cm / sec，气体含量为0.6以下供入阴极室。 还公开了用于上述方法的电解槽。 本发明不仅能够以低成本将汞电解池转化为阳离子交换膜电解槽，而且能够长期稳定地进行操作。
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公开(公告)号：US4395321A
公开(公告)日：1983-07-26
申请号：US284517
申请日：1981-07-17
CPC分类号： C25B9/08
摘要： A separator electrolytic cell is disclosed which comprises a first electrode compartment surrounded with a releasable wall plate and a glove-shaped finger and a second electrode compartment surrounded with remaining cell walls, a cell top cover and the glove-shaped finger. A sheet-like separator is immediately installed to the cell without any peculiar processing and the cell facilitates assembly and disassembly and provides tight sealing.
摘要翻译： 公开了一种分离器电解池，其包括被可释放的壁板和手套形状的手指包围的第一电极隔室和被剩余的细胞壁包围的第二电极隔室，细胞顶盖和手套形的手指。 片状分离器立即安装到电池上，无需任何特殊处理，电池便于组装和拆卸，并提供紧密的密封。
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4.发明授权Electrolytic process of an aqueous alkali metal halide solution and electrolytic cell 失效碱金属卤化物水溶液和电解池的电解过程
公开(公告)号：US4370208A
公开(公告)日：1983-01-25
申请号：US208843
申请日：1980-11-20
申请人： Tokuzo Iijima , Yasushi Samejima , Kazuo Kishimoto , Toshiji Kano , Kiyoshi Yamada , Yoshio Hatta
发明人： Tokuzo Iijima , Yasushi Samejima , Kazuo Kishimoto , Toshiji Kano , Kiyoshi Yamada , Yoshio Hatta
摘要： An electrolytic process is provided for the electrolysis of an aqueous alkali metal halide solution, which comprises effecting the electrolysis in a cell being separated by a cation exchange membrane into an anode compartment and a cathode compartment, wherein washing liquid is supplied into a liquid seal pot provided at a cathode gas outlet of a cathode compartment and cathode gas evolved from the cell is contacted with the washing liquid in the liquid seal pot.
摘要翻译： 提供一种用于电解碱金属卤化物水溶液的电解方法，该方法包括在由阳离子交换膜分离的电池中进行电解，进入阳极室和阴极室，其中将洗涤液体供应到液体密封罐 设置在阴极室的阴极气体出口处，并且从电池放出的阴极气体与液体密封罐中的洗涤液接触。
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公开(公告)号：US4278526A
公开(公告)日：1981-07-14
申请号：US104773
申请日：1979-12-18
CPC分类号： C25B1/46
摘要： Apparatus for the electrolysis of an aqueous alkali metal chloride solution using a cation exchange membrane, wherein the apparatus is designed so that gas-liquid interface, at which halogen gas is separated, is maintained larger than the sum total of the cross section area of the unit anode chambers opposing to cathodes, and further, higher than the upper end of the cation exchange membrane. The invention has numerous advantages including substantial absence of halogen gas, operation at a low voltage, a high pure product, simplification of operation control and the like.
摘要翻译： 用于使用阳离子交换膜电解碱金属氯化物水溶液的装置，其中所述装置被设计成使得卤素气体被分离的气液界面保持大于所述阴离子交换膜的截面面积的总和 单元阳极室与阴极相对，并且还高于阳离子交换膜的上端。 本发明具有许多优点，包括基本上不存在卤素气体，在低电压下操作，高纯度产品，简化操作控制等。
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公开(公告)号：US4268372A
公开(公告)日：1981-05-19
申请号：US971429
申请日：1978-12-20
CPC分类号： C25B9/08 , C25B13/00 , F16B5/0635
摘要： Method and apparatus of installation of a membrane to a finger type electrolytic cell are provided, which comprise covering the horizontal surfaces of a cathode not opposing an anode with a membrane installation frame having a collar, positioning the membrane substantially parallel to the vertical surfaces of the cathode, and installing and securing the membrane to the collar by clipping. Not only is operation efficiency for the membrane installation to the electrolytic cell markedly improved, but also, in the case of an ion exchange membrane, an alkali metal hydroxide liquor hardly containing an alkali metal chloride is produced. According to the invention, a conventional asbestos diaphragm finger type electrolytic cell is advantageously converted to an ion exchange membrane electrolytic cell.
摘要翻译： 提供了将膜安装到手指式电解池的方法和装置，其包括用不带阳极的阴极覆盖水平表面，其中膜安装框架具有一个套环，将膜基本上平行于垂直表面 阴极，并通过剪切将膜安装和固定到套环。 不仅膜电解槽的安装操作效率显着提高，而且在离子交换膜的情况下，也产生几乎不含碱金属氯化物的碱金属氢氧化物液体。 根据本发明，传统的石棉隔膜指型电解槽有利地被转换成离子交换膜电解槽。
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公开(公告)号：US4240883A
公开(公告)日：1980-12-23
申请号：US104774
申请日：1979-12-18
CPC分类号： C25B1/46
摘要： Method for electrolysis of an aqueous alkali metal chloride solution is provided, wherein an aqueous alkali metal chloride solution is electrolyzed by maintaining a temperature of an aqueous alkali metal hydroxide liquor in a cathode compartment lower than that of the aqueous alkali metal chloride solution in an anode compartment, using an electrolytic cell which is separated by a cation exchange membrane into the anode compartment and the cathode compartment. Not only is current efficiency improved without adverse effects on voltage, thus enabling a long period operation with low electric power consumption, but also high purity alkali metal hydroxide containing a reduced amount of chloride ion is produced.
摘要翻译： 提供碱金属氯化物水溶液的电解方法，其中碱金属氯化物水溶液通过将阴极室中的碱金属氢氧化物水溶液的温度维持在阳极中的碱金属氯化物水溶液的温度以下来进行电解 使用由阳离子交换膜分离成阳极室和阴极室的电解池。 不仅电流效率提高而对电压没有不利影响，从而能够在低功耗的情况下实现长时间运行，而且产生含有减少量的氯离子的高纯度碱金属氢氧化物。
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公开(公告)号：US4643808A
公开(公告)日：1987-02-17
申请号：US657545
申请日：1984-10-04
申请人： Yasushi Samejima , Minoru Shiga , Toshiji Kano , Takamichi Kishi
发明人： Yasushi Samejima , Minoru Shiga , Toshiji Kano , Takamichi Kishi
摘要： A method for controlling chlorates in an aqueous alkali metal hydroxide liquor produced by an ion exchange membrane electrolysis is provided, which comprises adding a reducing agent to brine to keep the concentration of chlorates to a specified value or less. The present invention provides an alkali metal hydroxide liquor with low content of chlorates.
摘要翻译： 提供了一种通过离子交换膜电解产生的碱金属氢氧化物水溶液中氯酸盐的控制方法，其包括向盐水中加入还原剂以将氯酸盐的浓度保持在规定值以下。 本发明提供具有低含量氯酸盐的碱金属氢氧化物液体。
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公开(公告)号：US4596639A
公开(公告)日：1986-06-24
申请号：US434737
申请日：1982-10-18
申请人： Tsutomu Nishio , Yasushi Samejima , Minoru Shiga , Toshiji Kano , Koji Saiki
发明人： Tsutomu Nishio , Yasushi Samejima , Minoru Shiga , Toshiji Kano , Koji Saiki
摘要： Disclosed is an electrolysis process which is characterized by carrying out the electrolysis of an aqueous alkali metal halide solution while supplying a cathode liquor into a cathode compartment formed between a cation exchange membrane positioned substantially horizontal and a cathode plate of gas-liquid impermeability, with which the membrane is wetted, then a mixed stream of the cathode liquor and cathode gas being removed from the cathode compartment.Also disclosed is an electrolytic cell which is comprised of an upper anode compartment and a lower cathode compartment partitioned by a cation exchange membrane positioned substantially horizontal, said anode compartment having therein substantially horizontal anodes and an anolyte solution inlet and outlet, and said cathode compartment having a cathode plate with gas-liquid impermeability and a cathode liquor inlet and an outlet of a mixed stream of the cathode liquor and cathode gas.
摘要翻译： 公开了一种电解方法，其特征在于，在将碱性金属卤化物水溶液进行电解的同时，将阴极液供给到形成在基本水平的阳离子交换膜和气液不透性的阴极板之间的阴极室中， 将膜浸湿，然后从阴极室除去阴极液体和阴极气体的混合物流。 还公开了一种电解池，其由上阳极室和由阳离子交换膜分隔开的下阴极室组成，阳离子交换膜位于基本上水平的位置，所述阳极室具有基本上水平的阳极和阳极电解液入口和出口，所述阴极室具有 具有气液不透性的阴极板和阴极液入口以及阴极液和阴极气体的混合流的出口。
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公开(公告)号：US4574037A
公开(公告)日：1986-03-04
申请号：US566931
申请日：1983-12-30
摘要： Disclosed is a vertical type electrolytic cell partitioned by an ion exchange membrane into an anode compartment and a cathode compartment, the cathode compartment being divided by a non-perforated cathode plate into a cathode gas generation room and a cathode gas separation room. Also disclosed is an electrolytic process using the electrolytic cell wherein the catholyte is circulated between the two rooms as a result of a gas lift effect produced by the cathode gas.
摘要翻译： 公开了一种由离子交换膜分隔成阳极室和阴极室的垂直型电解槽，阴极室由非穿孔阴极板分成阴极气体发生室和阴极气体分离室。 还公开了使用电解池的电解方法，其中阴极气体由于由阴极气体产生的气举效应而在两个房间之间循环。
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