公开(公告)号：US06677418B1

公开(公告)日：2004-01-13

申请号：US10019315

申请日：2002-01-09

Applicant: William James Feast ,  Ezat Khosravi ,  Thanawadee Leejarkpai

Inventor： William James Feast ,  Ezat Khosravi ,  Thanawadee Leejarkpai

IPC: C08F1000

CPC classification number: C08G61/08

Abstract: Process for the catalytic copolymerisation (ROMP) of strained activated cyclic olefins comprising contacting an activated strained mono (poly)cyclic olefin monomer of formula with at least 1 wt % of an activated strained di (poly)cyclic olefin monomer of formula in the presence of a catalyst or an initiating agent wherein the group represents a strained (poly)cyclic olefin, tail Y and spacer X comprise preferably electron withdrawing and property modulating groups whereby the monomers form a copolymer comprising the repeating unit and at least 1 wt % of the unit which is adapted for subsequent cross linking of respective copolymer chains in the presence of heat and catalyst to form an amount of a cross linked copolymer comprising the unit, and polymeric products obtained thereby, novel monomers and intermediates, a method for selecting monomers for reaction a method for the preparation of shaped products by RIM or RTM, and shaped products obtained thereby.

Abstract translation: 应变活性环烯烃的催化共聚（ROMP）方法包括使活化的应变单（聚）环烯烃单体与至少1重量％的活化的应变二（聚）环烯烃单体接触，形成催化剂 或引发剂，其中所述基团表示应变（多）环烯烃，尾部Y和间隔物X优选包含吸电子和性质调节基团，其中单体形成包含重复单元的共聚物和至少1重量％的单位，其适用于随后的交叉 在热和催化剂存在下连接相应的共聚物链以形成一定量的包含该单元的交联共聚物，由此得到的聚合物，新单体和中间体，用于反应的单体的选择方法制备成型方法 RIM或RTM产品，以及由此获得的成型产品。

公开(公告)号：US09487631B2

公开(公告)日：2016-11-08

申请号：US11915122

申请日：2006-05-22

Applicant: Lian Richard Hutchings ,  William James Feast ,  Richard Lewis Thompson ,  Amilcar Pillay-Narrainen

Inventor： Lian Richard Hutchings ,  William James Feast ,  Richard Lewis Thompson ,  Amilcar Pillay-Narrainen

IPC: C08L25/06 ,  C08G83/00 ,  C08L101/00

CPC classification number: C08G83/003 ,  C08L101/005

Abstract: A polymer comprising a bulk polymer or copolymer PB together with an amount of a polymer-dendron additive D-PD of formula (I): is provided, such that the polymer comprises from 0.001 to 50% of dendron-additive D-PD calculated as weight of dendron D in polymers D-PD and PB, wherein: PD is a polymer chain comprising at least one monomer repeat unit and is cyclic (having no ends) or has at least two ends and is linked to group Y in chain or at least one of its ends; Y is a linking group; a and b are each zero or a whole number integer in the range from 1 to 5; A is a branching group; each XZ1 is a functional group independently selected from one or more of OH, halo, amino, cyano, carboxylic acid, ester, thiol, silane, azide, alkyl, alkenyl, alkynyl, oligoalkyl, oligoalkenyl, oligoalkylether or any organometallic group, a linear, branched or cyclic C1-20 alkyl, alkenyl or cycloalkyl group optionally comprising a heteroatom O or S and comprising from 3 to 37 functional groups selected from halo, OH, NR2, CN, COOH, COOR, SR, SiCl3, SiRCl2 SiR2Cl, Si(OR)3, and a combination thereof; Z is O or S; is derived as functional groups as hereinbefore defined; G indicates the Generation of a given dendron, in which both a (where present) and b are in the range 1 to 5.

公开(公告)号：US20100036054A1

公开(公告)日：2010-02-11

申请号：US11915122

申请日：2006-05-22

Applicant: Lian Richard Hutchings ,  William James Feast ,  Richard Lewis Thompson ,  Amilcar Pillay-Narrainen

Inventor： Lian Richard Hutchings ,  William James Feast ,  Richard Lewis Thompson ,  Amilcar Pillay-Narrainen

IPC: C08L25/06

CPC classification number: C08G83/003 ,  C08L101/005

Abstract: A polymer comprising a bulk polymer or copolymer PB together with an amount of a polymer-dendron additive D-PD of formula (I): is provided, such that the polymer comprises from 0.001 to 50% of dendron-additive D-PD calculated as weight of dendron D in polymers D-PD and PB, wherein: PD is a polymer chain comprising at least one monomer repeat unit and is cyclic (having no ends) or has at least two ends and is linked to group Y in chain or at least one of its ends; Y is a linking group; a and b are each zero or a whole number integer in the range from 1 to 5; A is a branching group; each XZ1 is a functional group independently selected from one or more of OH, halo, amino, cyano, carboxylic acid, ester, thiol, silane, azide, alkyl, alkenyl, alkynyl, oligoalkyl, oligoalkenyl, oligoalkylether or any organometallic group, a linear, branched or cyclic C1-20 alkyl, alkenyl or cycloalkyl group optionally comprising a heteroatom O or S and comprising from 3 to 37 functional groups selected from halo, OH, NR2, CN, COOH, COOR, SR, SiCl3, SiRCl2 SiR2Cl, Si(OR)3, and a combination thereof; Z is O or S; is derived as functional groups as hereinbefore defined; G indicates the Generation of a given dendron, in which both a (where present) and b are in the range 1 to 5.

Abstract translation: 提供包含本体聚合物或共聚物PB与一定量的式（I）的聚合物 - 树枝状添加剂D-PD的聚合物，使得聚合物包含0.001至50％的树状添加剂D-PD，计算为 聚合物D-PD和PB中的树枝状D的重量，其中：PD是包含至少一个单体重复单元并且是环状（无末端）或具有至少两个末端的聚合物链，并且与链中的Y或 至少其中一个; Y是连接组; a和b分别为0或1〜5的整数; A是分支组; 每个XZ1是独立地选自OH，卤素，氨基，氰基，羧酸，酯，硫醇，硅烷，叠氮化物，烷基，烯基，炔基，低级烷基，低聚链烯基，低聚烷基醚或任何有机金属基团中的一种或多种的官能团， 任选地包含杂原子O或S并且包含3至37个选自卤素，OH，NR 2，CN，COOH，COOR，SR，SiCl 3，SiRCl 2，SiR 2 Cl，Si的官能团的支链或环状C 1-20烷基，烯基或环烷基 （OR）3及其组合; Z是O或S; 衍生为如上文所定义的官能团; G表示产生给定的树突，其中a（当存在）和b都在1至5的范围内。