公开(公告)号：US06066682A

公开(公告)日：2000-05-23

申请号：US774016

申请日：1996-12-26

申请人： Kimihiko Noda ,  Satoshi Sasaki ,  Tsuyoshi Tomosada

发明人： Kimihiko Noda ,  Satoshi Sasaki ,  Tsuyoshi Tomosada

IPC分类号： C08J9/06

CPC分类号： C08J9/06 ,  C08J2333/02

摘要： A foam comprising a metal salt-crosslinked cellular (co)polymer (A) obtained by polymerizing a monomer charge comprising an .alpha., .beta.-unsaturated carboxylic acid and optionally one or more other vinyl monomers, wherein at least part of said monomer charge is concurrently foamed and polymerized in the presence of a metal salt of carbonic acid, and processes for producing them. Low-density foams that are benign to the environment and can be easily produced can be provided.

摘要翻译： 一种泡沫，其包含通过聚合包含α，β-不饱和羧酸和任选的一种或多种其它乙烯基单体的单体电荷获得的金属盐交联的细胞（共）聚合物（A），其中所述单体电荷的至少一部分同时 在碳酸金属盐的存在下发泡和聚合，以及制备它们的方法。 可以提供对环境良好并且可以容易地生产的低密度泡沫。

公开(公告)号：US06610756B1

公开(公告)日：2003-08-26

申请号：US09462043

申请日：1999-12-30

申请人： Tomokazu Shimizu ,  Tadaaki Yamazaki ,  Shinzo Kaida ,  Tsuyoshi Tomosada

发明人： Tomokazu Shimizu ,  Tadaaki Yamazaki ,  Shinzo Kaida ,  Tsuyoshi Tomosada

IPC分类号： C08J908

CPC分类号： C08G18/10 ,  C04B28/34 ,  C04B38/00 ,  C04B38/02 ,  C08G2101/00 ,  C08K3/24 ,  C08K3/38 ,  C04B35/447 ,  C04B38/0022 ,  C04B22/0013 ,  C04B22/10 ,  C04B24/282 ,  C04B26/16 ,  C04B22/141 ,  C04B22/142 ,  C04B22/165 ,  C08G18/3895

摘要： An inorganic/organic composite foam that has a foam structure obtained from a combination of a phosphoric acid compound and/or a sulfuric acid compound with a blowing agent therefor, has reduced brittleness due to a cured material of an urethane prepolymer having NCO groups, and contains a powdery boric acid compound, and a process for producing the same. The foam is not only reduced in brittleness but also improved in foam strength after combustion due to the incorporation of the powdery boric acid compound while retaining inherent foam properties and inherent low quantities of heat of combustion and smoking in combustion. It is used in exterior wall panels, heat insulating materials, sound insulating materials, fireproof covering materials, lightweight aggregates, filling materials for cavities, and the like, which are required to have fire-proofing performance.

摘要翻译： 具有由磷酸化合物和/或硫酸化合物与发泡剂的组合获得的泡沫结构的无机/有机复合泡沫体由于具有NCO基团的氨基甲酸酯预聚物的固化物而具有降低的脆性，以及 含有粉末状硼酸化合物及其制造方法。 由于掺入粉末状硼酸化合物同时保持固有的泡沫性能和固有的低燃烧热和燃烧热量，泡沫不仅脆性降低，而且燃烧后的泡沫强度也得到改善。 用于要求具有防火性能的外墙板，绝热材料，隔音材料，防火覆盖材料，轻质骨料，空腔填充材料等。

公开(公告)号：US06455606B1

公开(公告)日：2002-09-24

申请号：US09402303

申请日：1999-10-01

申请人： Motonao Kaku ,  Yasushi Kumagai ,  Toru Nakanishi ,  Tatsuroh Yanagi ,  Tsuyoshi Tomosada ,  Kunikiyo Yoshio ,  Hajime Akiyama ,  Sadao Kubota ,  Jiro Ryugo ,  Yuichi Sasatani

发明人： Motonao Kaku ,  Yasushi Kumagai ,  Toru Nakanishi ,  Tatsuroh Yanagi ,  Tsuyoshi Tomosada ,  Kunikiyo Yoshio ,  Hajime Akiyama ,  Sadao Kubota ,  Jiro Ryugo ,  Yuichi Sasatani

IPC分类号： C08G1804

CPC分类号： C08G18/4072 ,  C08G18/67 ,  C08G18/6705 ,  C08G18/673 ,  C08G18/6795 ,  C08G2101/0008 ,  C08G2101/0025 ,  C08G2101/005 ,  C08G2101/0083 ,  C08J2205/10

摘要： A polyurethane foam which is obtained by reacting an addition-polymerizable active hydrogen component comprising a compound having a group containing active hydrogen and an addition-polymerizable functional group or comprising both this compound and a compound containing at least 2.5 groups (on the average) containing active hydrogen and not containing addition-polymerizable functional groups with an organic polyisocyanate in the presence or absence of at least one auxiliary selected from the group consisting of foaming agents and additives to polymerize the addition-polymerizable functional group and simultaneously form a polyurethane, and which has a structure in which the chains formed by the addition polymerization have been cross-linked to the polyurethane chains. The polyurethane foam is useful as a rigid polyurethane foam excellent in hardness, dimensional stability, etc. and usable as a heat insulator, shock-absorbing material, synthetic wood, etc., or is useful as a soft polyurethane foam reduced in compression set and usable as a cushioning material, shock-absorbing material, sound insulating/absorbing material, etc.

摘要翻译： 一种聚氨酯泡沫体，其通过使包含具有含活性氢基团的化合物和可加成聚合官能团的可加成聚合活性氢成分或包含该化合物和含有至少2.5个（平均）的化合物）（包含 在存在或不存在选自由发泡剂和添加剂组成的组中的至少一种的助剂存在或不存在的情况下，不含有有机多异氰酸酯的加成聚合官能团，并且聚合可加聚官能团并同时形成聚氨酯，并且其中 具有通过加成聚合形成的链已经与聚氨酯链交联的结构。 聚氨酯泡沫可用作硬度，尺寸稳定性等优异的硬质聚氨酯泡沫，并且可用作隔热材料，减震材料，合成木材等，或者可用作减小压缩永久变形的软质聚氨酯泡沫， 可用作缓冲材料，减震材料，隔音/吸收材料等

公开(公告)号：US4820743A

公开(公告)日：1989-04-11

申请号：US130656

申请日：1987-12-09

申请人： Isao Ishikawa ,  Tsuyoshi Tomosada

发明人： Isao Ishikawa ,  Tsuyoshi Tomosada

IPC分类号： C08G18/50 ,  C08G18/62 ,  C08G18/63 ,  C08G18/65 ,  C08G18/14

CPC分类号： C08G18/657 ,  C08G18/63 ,  C08G2120/00 ,  C08G2125/00

摘要： Polymer/polyol compositions, obtained by polymerizing one or more ethylenically unsaturated monomers in situ in a blend of a polyether polyol and a polyamine, are of suitably high reactivity. The polymer/polyol compositions provide, by reaction with a polyisocyanate, polyurethanes having improved moldability and physical properties along with self-mold-release characteristics, and are particularly suitable for producing polyurethane by RIM process.

摘要翻译： 通过在聚醚多元醇和多胺的共混物中原位聚合一种或多种烯属不饱和单体获得的聚合物/多元醇组合物具有合适的高反应性。 聚合物/多元醇组合物通过与多异氰酸酯反应提供具有改进的成型性和物理性质以及自脱模特性的聚氨酯，并且特别适用于通过RIM方法生产聚氨酯。

公开(公告)号：US06756414B2

公开(公告)日：2004-06-29

申请号：US10463644

申请日：2003-06-17

申请人： Tetsuji Kawamoto ,  Tomio Kawazoe ,  Kiyoshi Ikeda ,  Munekazu Satake ,  Futoshi Kitatani ,  Tsuyoshi Tomosada ,  Takeshi Furuta ,  Takayuki Tsuji

发明人： Tetsuji Kawamoto ,  Tomio Kawazoe ,  Kiyoshi Ikeda ,  Munekazu Satake ,  Futoshi Kitatani ,  Tsuyoshi Tomosada ,  Takeshi Furuta ,  Takayuki Tsuji

IPC分类号： C08G1810

CPC分类号： C08G18/632 ,  C08F2/06 ,  C08F283/006 ,  C08F283/06 ,  C08G2101/00 ,  C08G2101/005 ,  C08G2101/0083

摘要： This invention provides a polymer polyol composition (I) comprising a polyol (A) and polymer particles (B) dispersed in (A), the polymer particles (B) being formed by polymerizing an ethylenically unsaturated compound (b) in a polyol, wherein the content of (B) in (I) is from 35 to 75 mass %, based on the mass of (I), and the amount of soluble polymers (P) dissolved in (A) is not more than 5 mass %, based on the mass of (A), and provides methods for producing the polymer polyol composition (I). Further, this invention provides a method for producing a foamed or non-foamed polyurethane resin, which method comprises reacting a polyol component with a polyisocyanate component in the presence or absence of a blowing agent, wherein the above polymer polyol composition is used at least as a portion of the polyol component. A polymer polyol having a low viscosity and excellent dispersion stability is provided even when having a high concentration of polymer particles, and is used advantageously to produce polyurethane resins having excellent 25% ILD (hardness) and compression set, or foams thereof, with good operation efficiency.

摘要翻译： 本发明提供一种包含分散在（A）中的多元醇（A）和聚合物颗粒（B））的聚合物多元醇组合物（I），聚合物颗粒（B）通过在多元醇中聚合烯属不饱和化合物（b）而形成，其中 基于（I）的质量，（I）中的（B）的含量为35〜75质量％，溶解在（A）中的可溶性聚合物（P）的量为5质量％以下 （A）的质量，并且提供了制备聚合物多元醇组合物（I）的方法。 此外，本发明提供一种发泡或非发泡聚氨酯树脂的制造方法，其特征在于，在发泡剂的存在或不存在下，使多元醇成分与多异氰酸酯成分反应，其中上述聚合物多元醇组合物至少使用 一部分多元醇组分。 即使具有高浓度的聚合物颗粒，也提供了具有低粘度和优异的分散稳定性的聚合物多元醇，并且有利地生产具有优异的25％ILD（硬度）和压缩永久变形或其泡沫的优异的操作的聚氨酯树脂 效率。

公开(公告)号：US06624209B2

公开(公告)日：2003-09-23

申请号：US10068182

申请日：2002-02-06

申请人： Tetsuji Kawamoto ,  Tomio Kawazoe ,  Kiyoshi Ikeda ,  Munekazu Satake ,  Futoshi Kitatani ,  Tsuyoshi Tomosada ,  Takeshi Furuta ,  Takayuki Tsuji

发明人： Tetsuji Kawamoto ,  Tomio Kawazoe ,  Kiyoshi Ikeda ,  Munekazu Satake ,  Futoshi Kitatani ,  Tsuyoshi Tomosada ,  Takeshi Furuta ,  Takayuki Tsuji

IPC分类号： C08G1863

CPC分类号： C08F283/006 ,  C08F283/06 ,  C08G18/632 ,  C08G2101/00 ,  C08G2101/005 ,  C08G2101/0083

摘要： This invention provides a polymer polyol composition (I) comprising a polyol (A) and polymer particles (B) dispersed in (A), the polymer particles (B) being formed by polymerizing an ethylenically unsaturated compound (b) in a polyol, wherein the content of (B) in (I) is from 35 to 75 mass %, based on the mass of (I), and the amount of soluble polymers (P) dissolved in (A) is not more than 5 mass %, based on the mass of (A), and provides methods for producing the polymer polyol composition (I). Further, this invention provides a method for producing a foamed or non-foamed polyurethane resin, which method comprises reacting a polyol component with a polyisocyanate component in the presence or absence of a blowing agent, wherein the above polymer polyol composition is used at least as a portion of the polyol component. A polymer polyol having a low viscosity and excellent dispersion is stability is provided even when having a high concentration of polymer particles, and is used advantageously to produce polyurethane resins having excellent 25% ILD (hardness) and compression set, or foams thereof, with good operation efficiency.

摘要翻译： 本发明提供一种包含分散在（A）中的多元醇（A）和聚合物颗粒（B））的聚合物多元醇组合物（I），聚合物颗粒（B）通过在多元醇中聚合烯属不饱和化合物（b）而形成，其中 基于（I）的质量，（I）中的（B）的含量为35〜75质量％，溶解在（A）中的可溶性聚合物（P）的量为5质量％以下 （A）的质量，并且提供了制备聚合物多元醇组合物（I）的方法。 此外，本发明提供一种发泡或非发泡聚氨酯树脂的制造方法，其特征在于，在发泡剂的存在或不存在下，使多元醇成分与多异氰酸酯成分反应，其中上述聚合物多元醇组合物至少使用 一部分多元醇组分。 具有低粘度和优异分散性的聚合物多元醇即使当具有高浓度聚合物颗粒时也是稳定的，并且有利地用于制备具有优异的25％ILD（硬度）和压缩永久变形或其泡沫的优异的聚氨酯树脂，具有良好的 运行效率。

公开(公告)号：US06555591B1

公开(公告)日：2003-04-29

申请号：US09367500

申请日：1999-10-15

申请人： Tsuyoshi Tomosada ,  Kimihiko Noda ,  Satoshi Sasaki ,  Hideo Nishiguchi ,  Hideyuki Nishida

发明人： Tsuyoshi Tomosada ,  Kimihiko Noda ,  Satoshi Sasaki ,  Hideo Nishiguchi ,  Hideyuki Nishida

IPC分类号： C08J900

CPC分类号： C08G59/30 ,  C08G18/50 ,  C08G2101/00 ,  C08J9/0066 ,  Y10S521/906 ,  Y10S521/907

摘要： The present invention has its object to provide a foam outstanding in electrification and heat insulating and sound insulating properties and has high compressive strength even when it has low density. The present invention relates to a foam comprising an organic polymer expanded matrix (I) and at least one kind of inorganic substance (II) selected from the group consisting of metals, metal compounds and non-metal inorganic fillers, wherein said expanded matrix (I) contains metal salt-crosslinks and the relation between the weight percentage (M) of the metal forming said metal salt-crosslinks in the expanded matrix (I) based on the total weight of the expanded matrix (I) and the inorganic substance (II) and the weight percentage (S) of the inorganic substance (II) based on the total weight of the expanded matrix (I) and the inorganic substance (II) satisfies the following expression. M≧10−S/4  (1) wherein M≦50 and S≧5.

摘要翻译： 本发明的目的是提供一种在起电隔热和隔音性能优异的泡沫中，即使密度低，也具有高抗压强度。 本发明涉及包含有机聚合物发泡基质（I）和至少一种选自金属，金属化合物和非金属无机填料的无机物质（II）的泡沫，其中所述膨胀基质（I ）含有金属盐交联，并且基于膨胀基质（I）和无机物质（II）的总重量，在膨胀基质（I）中形成所述金属盐交联的金属的重量百分比（M）之间的关系 ）和基于膨胀基质（I）和无机物质（II）的总重量的无机物质（II）的重量百分比（S）满足下式：其中M≤50且S> = 5。

公开(公告)号：US4931483A

公开(公告)日：1990-06-05

申请号：US279508

申请日：1988-12-05

申请人： Masahiro Matsuoka ,  Keiichi Akimoto ,  Takeshi Sumita ,  Tsuyoshi Tomosada ,  Isao Ishikawa

发明人： Masahiro Matsuoka ,  Keiichi Akimoto ,  Takeshi Sumita ,  Tsuyoshi Tomosada ,  Isao Ishikawa

IPC分类号： C08F283/06 ,  C08G18/63

CPC分类号： C08F283/06 ,  C08G18/638

摘要： Polymer/polyol compositions, obtained by polymerizing, in situ in a polyol, one or more ethylenically unsaturated monomers comprising an alpha-olefin containing at least 5 carbon atoms and/or an acrylate or methacrylate ester of an alcohol containing at least 9 carbon atoms, which are of relatively low viscosity and which afford polyurethanes having improved properties.

摘要翻译： 聚合物/多元醇组合物，其通过在多元醇中原位聚合一种或多种包含至少5个碳原子的α-烯烃和/或含有至少9个碳原子的醇的丙烯酸酯或甲基丙烯酸酯的烯属不饱和单体， 其具有相对低的粘度，并且其提供具有改进性能的聚氨酯。