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公开(公告)号:US06235963B1
公开(公告)日:2001-05-22
申请号:US09060281
申请日:1998-04-14
申请人: Yasuhiro Yamauchi , Kan Ogata , Naoki Shindo , Nobuhiro Hokao , Yoshihiko Tsuchiyama , Masakazu Tateishi , Tadatsugu Fukuzumi
发明人: Yasuhiro Yamauchi , Kan Ogata , Naoki Shindo , Nobuhiro Hokao , Yoshihiko Tsuchiyama , Masakazu Tateishi , Tadatsugu Fukuzumi
IPC分类号: A62D300
CPC分类号: A62D3/38 , A62D3/35 , A62D2101/22 , A62D2203/10 , B01D3/14 , B01D3/4211
摘要: The present invention provides a PCB decomposing apparatus capable of decomposing PCB efficiently. The PCB decomposing apparatus comprises a PCB extracting container for extracting PCB from a PCB-containing material with an organic solvent. A distilling tower provided on the downstream side of the PCB extracting container distills the organic solvent to separate the PCB. A primary reactor provided on the downstream side of the distilling tower includes a nozzle for supplying aqueous Na2CO3 solution and a nozzle for supplying an oxidizing agent into the container. A liquid cyclone provided on the downstream side of the primary reactor can remove Na2CO3 having a large particle size. A secondary reactor formed by a long pipe is connected to the liquid cyclone. A gas-liquid separator provided on the further downstream side of the secondary reactor can separate a gas from a solution. A film separator separates treated water into purified water and a concentrated solution, and the purified water is supplied as circulating water to the upstream side of a pressure pump.
摘要翻译: 本发明提供能够有效地分解PCB的PCB分解装置。 PCB分解装置包括用于从含有PCB的材料用有机溶剂提取PCB的PCB提取容器。 设置在PCB提取容器下游侧的蒸馏塔蒸馏有机溶剂以分离PCB。 设置在蒸馏塔的下游侧的主反应器包括用于供给Na 2 CO 3水溶液的喷嘴和用于将氧化剂供应到容器中的喷嘴。 设置在初级反应器的下游侧的液体旋风分离器可以除去大粒径的Na 2 CO 3。 由长管形成的二次反应器连接到液体旋风分离器。 设置在次级反应器的更下游侧的气液分离器可以将气体与溶液分离。 膜分离器将经处理的水分离成纯水和浓缩溶液,将纯化水作为循环水供给到压力泵的上游侧。
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公开(公告)号:US06599485B1
公开(公告)日:2003-07-29
申请号:US09329591
申请日:1999-06-10
申请人: Yasuhiro Yamauchi , Kan Ogata , Naoki Shindo , Nobuhiro Hokao , Yoshihiko Tsuchiyama , Masakazu Tateishi , Tadatsugu Fukuzumi
发明人: Yasuhiro Yamauchi , Kan Ogata , Naoki Shindo , Nobuhiro Hokao , Yoshihiko Tsuchiyama , Masakazu Tateishi , Tadatsugu Fukuzumi
IPC分类号: B09B300
CPC分类号: A62D3/38 , A62D3/35 , A62D2101/22 , A62D2203/10 , B01D3/14 , B01D3/4211
摘要: The present invention provides a PCB decomposing apparatus capable of decomposing PCB efficiently. The PCB decomposing apparatus comprises a PCB extracting container for extracting PCB from a PCB-containing material with an organic solvent. A distilling tower provided on the downstream side of the PCB extracting container distills the organic solvent to separate the PCB. A primary reactor provided on the downstream side of the distilling tower includes a nozzle for supplying aqueous Na2CO3 solution and a nozzle for supplying an oxidizing agent into the container. A liquid cyclone provided on the downstream side of the primary reactor can remove Na2CO3 having a large particle size. A secondary reactor formed by a long pipe is connected to the liquid cyclone. A gas-liquid separator provided on the further downstream side of the secondary reactor can separate a gas from a solution. A film separator separates treated water into purified water and a concentrated solution, and the purified water is supplied as circulating water to the upstream side of a pressure pump.
摘要翻译: 本发明提供能够有效地分解PCB的PCB分解装置。 PCB分解装置包括用于从含有PCB的材料用有机溶剂提取PCB的PCB提取容器。 设置在PCB提取容器下游侧的蒸馏塔蒸馏有机溶剂以分离PCB。 设置在蒸馏塔的下游侧的主反应器包括用于供给Na 2 CO 3水溶液的喷嘴和用于将氧化剂供应到容器中的喷嘴。 设置在初级反应器的下游侧的液体旋风分离器可以除去大粒径的Na 2 CO 3。 由长管形成的二次反应器与液体旋风分离器连接。 设置在次级反应器的更下游侧的气液分离器可以将气体与溶液分离。 膜分离器将经处理的水分离成纯水和浓缩溶液,将纯化水作为循环水供给到压力泵的上游侧。
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公开(公告)号:US6162958A
公开(公告)日:2000-12-19
申请号:US266664
申请日:1999-03-11
申请人: Masakazu Tateishi , Yoshihiko Tsuchiyama , Yasuhiro Yamauchi , Tadatsugu Fukuzumi , Toshiyuki Hatano
发明人: Masakazu Tateishi , Yoshihiko Tsuchiyama , Yasuhiro Yamauchi , Tadatsugu Fukuzumi , Toshiyuki Hatano
CPC分类号: A62D3/38 , A62D2101/22
摘要: This invention relates to a PCB decomposition process which comprises the steps of reacting an organic material with sodium hydroxide to form sodium carbonate, and decomposing PCB with the aid of the sodium carbonate so formed.
摘要翻译: 本发明涉及PCB分解方法,其包括以下步骤:使有机物与氢氧化钠反应形成碳酸钠,并借助于如此形成的碳酸钠分解PCB。
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公开(公告)号:US06949231B2
公开(公告)日:2005-09-27
申请号:US09975614
申请日:2001-10-10
申请人: Yasuhiro Yamauchi , Kan Ogata , Takashi Moribe , Masakazu Tateishi , Tadatsugu Fukuzumi , Mitsuji Iwao , Nobuyuki Ikeda , Naoki Shindo , Nobuhiro Hokao
发明人: Yasuhiro Yamauchi , Kan Ogata , Takashi Moribe , Masakazu Tateishi , Tadatsugu Fukuzumi , Mitsuji Iwao , Nobuyuki Ikeda , Naoki Shindo , Nobuhiro Hokao
IPC分类号: A62D3/00 , A62D3/20 , A62D3/36 , A62D3/38 , A62D101/22 , B01J8/00 , B01J8/18 , B01J8/22 , B01J10/00 , B01J19/00 , B01J19/26 , B09B3/00 , C01B32/50
CPC分类号: A62D3/36 , A62D2101/22 , A62D2203/10 , B01J8/0055 , B01J8/1818 , B01J8/228 , B01J10/002 , B01J19/26 , B01J2219/00164
摘要: A PCB decomposition reactor includes: an injector for injecting a mixture of water and sodium hydroxide connected to the lower part of the reaction vessel; an outlet pipe for withdrawing treated fluid connected to the sidewall of the reaction vessel and a cyclone for separating sodium carbonate from the treated fluid; a discharge pipe connected to the top of the cyclone to discharge treated fluid from which precipitated sodium carbonate has been removed; a downcomer for the separated fluid connected to the bottom of the cyclone so that precipitated sodium carbonate and fluid containing it are discharged therethrough and to an injector which is connected to a feed pipe for feeding a mixture of PCB and mineral oil; and a gas supply nozzle for injecting a gas into the reaction vessel installed at the bottom of the reaction vessel.
摘要翻译: PCB分解反应器包括:用于注入连接到反应容器下部的水和氢氧化钠的混合物的注射器; 用于抽出连接到反应容器侧壁的处理流体的出口管和用于从处理过的流体中分离出碳酸钠的旋风分离器; 连接到旋风分离器顶部的排放管,以排出已经从其中除去沉淀的碳酸钠的处理过的流体; 用于连接到旋风分离器底部的分离的流体的降液管,使得沉淀的碳酸钠和含有它的流体通过其排放到与进料管连接以供给PCB和矿物油的混合物的喷射器; 以及用于将气体注入安装在反应容器底部的反应容器中的气体供给喷嘴。
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公开(公告)号:US06322761B1
公开(公告)日:2001-11-27
申请号:US09266388
申请日:1999-03-11
申请人: Yasuhiro Yamauchi , Kan Ogata , Takashi Moribe , Masakazu Tateishi , Tadatsugu Fukuzumi , Mitsuji Iwao , Nobuyuki Ikeda , Naoki Shindo , Nobuhiro Hokao
发明人: Yasuhiro Yamauchi , Kan Ogata , Takashi Moribe , Masakazu Tateishi , Tadatsugu Fukuzumi , Mitsuji Iwao , Nobuyuki Ikeda , Naoki Shindo , Nobuhiro Hokao
IPC分类号: B01J800
CPC分类号: A62D3/36 , A62D2101/22 , A62D2203/10 , B01J8/0055 , B01J8/1818 , B01J8/228 , B01J10/002 , B01J19/26 , B01J2219/00164
摘要: This invention provides a PCB decomposition reactor which can decompose PCB efficiently. In this PCB decomposition reactor, an injector for injecting a mixture of water and sodium hydroxide into a reaction vessel is connected to the lower part of the reaction vessel. An outlet pipe for withdrawing the fluid treated within the reaction vessel is connected to the sidewall of the reaction vessel. The other end of the outlet pipe is connected to a cyclone for separating sodium carbonate from the treated fluid. A discharge pipe is connected to the top of the cyclone, so that the treated fluid from which the precipitated sodium carbonate has been removed is discharged therethrough. A downcomer for the separated fluid is connected to the bottom of the cyclone, so that the precipitated sodium carbonate and some fluid containing it are discharged therethrough. The lower end of the downcomer is connected to an injector, which has connected thereto a feed pipe for feeding a mixture of PCB and mineral oil. A gas supply nozzle for injecting a gas into the reaction vessel is installed at the bottom of the reaction vessel.
摘要翻译: 本发明提供一种能够有效分解PCB的PCB分解反应器。 在该PCB分解反应器中,将反应容器内的水和氢氧化钠的混合物注入喷射器连接到反应容器的下部。 用于取出在反应容器内处理的流体的出口管连接到反应容器的侧壁。 出口管的另一端连接到用于从处理过的流体分离碳酸钠的旋风分离器。 排出管连接到旋风分离器的顶部,从而将已经除去了沉淀的碳酸钠的处理流体排出。 分离流体的降液管连接到旋风分离器的底部,使得沉淀的碳酸钠和含有它的一些流体通过其排出。 降液管的下端连接到喷射器,喷射器连接有用于供给PCB和矿物油混合物的进料管。 用于将气体注入反应容器的气体供给喷嘴安装在反应容器的底部。
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