公开(公告)号：US4256782A

公开(公告)日：1981-03-17

申请号：US947024

申请日：1978-09-29

Applicant: Shigeo Tazuke ,  Hitoshi Kimura ,  Hiroyuki Nakayama

Inventor： Shigeo Tazuke ,  Hitoshi Kimura ,  Hiroyuki Nakayama

IPC: C08J7/12 ,  C08J7/18 ,  B05D3/06

CPC classification number: C08J7/18

Abstract: A treating method for imparting hydrophilic property to the surface of a hydrophobic polymer substrate comprising the step of: contacting the surface of the polymer substrate having carbon atoms bonded with a single hydrogen atom in the molecule with a radically polymerizable compound and then irradiating actinic rays to the polymer substrate coated with the polymerizable compound. The homopolymer of the above polymerizable compound is soluble and/or swellable in water or in electrolytic solutions. If desired, the polymerizable compound may be mixed with a triplet state sensitizer having triplet state energy of 50 Kcal/mol or more or photosensitizer which produces free radicals by irradiation.

Abstract translation: 一种赋予疏水性聚合物基材表面亲水性的处理方法，包括以下步骤：将具有与分子中单个氢原子键合的碳原子的聚合物基材的表面与可自由基聚合的化合物接触，然后将光化射线 涂覆有可聚合化合物的聚合物基材。 上述可聚合化合物的均聚物在水或电解溶液中是可溶的和/或溶胀的。 如果需要，可以将聚合性化合物与三重状态能量为50Kcal / mol以上的三线态增感剂或通过照射产生自由基的光敏剂混合。

公开(公告)号：US4226967A

公开(公告)日：1980-10-07

申请号：US34700

申请日：1979-04-30

Applicant: Shigeo Tazuke ,  Hajime Nagahara

Inventor： Shigeo Tazuke ,  Hajime Nagahara

IPC: C08G18/00 ,  C08F226/12 ,  C08G18/32 ,  C08G18/38 ,  C08G63/685 ,  C08G63/688 ,  G03G5/07 ,  H01L51/30 ,  C08G18/62

CPC classification number: H01L51/004 ,  C08G18/384 ,  C08G63/685 ,  C08G63/688 ,  G03G5/075 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/42 ,  Y10S430/10

Abstract: An electron acceptor polycondensation polymer of the formula (I) ##STR1## wherein R.sub.1 is a hydrogen atom or an alkyl group, an aryl group or an aralkyl group having not more than 15 carbon atoms; C.sub.m is a divalent connecting group; FLac is an electron acceptor group having a fluorene nucleus as its basic structure; X and Y are a carbonyl group or an acid amide group forming a urethane linkage with the oxygen atom of the diol; R.sub.2 is a bifunctional organic residue having not more than 20 carbon atoms, n is a number greater than 10 which represents the degree of polycondensation of the resultant polycondensation polymer.

Abstract translation: 式（I）的电子受体缩聚聚合物（I）其中R1是氢原子或烷基，芳基或碳原子数不超过15个的芳烷基; Cm是二价连接基团; FLac是具有芴核作为其基本结构的电子受体基团; X和Y是与二醇的氧原子形成氨基甲酸酯键的羰基或酰胺基; R2是具有不超过20个碳原子的双官能有机残基，n是大于10的数，表示所得缩聚聚合物的缩聚度。

公开(公告)号：US4355053A

公开(公告)日：1982-10-19

申请号：US240365

申请日：1981-03-04

Applicant: Tuguo Nezu ,  Masuo Tsuchiya ,  Masahiro Sakamoto ,  Hiroyuki Nakayama ,  Shigeo Tazuke

Inventor： Tuguo Nezu ,  Masuo Tsuchiya ,  Masahiro Sakamoto ,  Hiroyuki Nakayama ,  Shigeo Tazuke

IPC: C08J7/00 ,  B05D7/02 ,  C08F2/48 ,  C08J7/04 ,  C08J7/18 ,  C09D4/06 ,  B05D3/06

CPC classification number: C08J7/18 ,  C08F2/48 ,  C09D4/06

Abstract: A method for improving the adhesiveness of the surface of a synthetic polymeric substrate to coatings, which comprises coating the surface of the synthetic polymeric substrate with a photopolymerizable composition comprising (A) a hydrophilic resin obtained by the polymerization of a polymerizable unsaturated monomer composition containing at least 10% by weight of a hydrophilic unsaturated monomer, (B) a radical-polymerizable mono-unsaturated monomer and (C) a triplet state sensitizer having a triplet state energy of at least 50 Kcal/mole, and then irradiating actinic rays to the coated surface of the polymeric substrate.

Abstract translation: 一种用于改善合成聚合物基材表面与涂层的粘合性的方法，其包括用可光聚合组合物涂覆合成聚合物基材的表面，该组合物包含（A）通过聚合可聚合不饱和单体组合物而获得的亲水性树脂， 至少10重量％的亲水性不饱和单体，（B）可自由基聚合的单不饱和单体和（C）具有至少50千卡/摩尔的三线态能量的三线态增感剂，然后将光化学射线照射到 聚合物基材的涂覆表面。