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    METHOD OF PREPARING RESIN COMPOSITION FOR HARD COAT AND RESIN COMPOSITION FOR HARD COAT
    1.
    发明申请
    METHOD OF PREPARING RESIN COMPOSITION FOR HARD COAT AND RESIN COMPOSITION FOR HARD COAT 有权
    硬质涂层硬质合成树脂组合物的制备方法

    公开(公告)号：US20130041063A1

    公开(公告)日：2013-02-14

    申请号：US13208998

    申请日：2011-08-12

    申请人： Asaki NAKANE ,  Shigehiro KOIDE ,  Yasuharu YAMADA

    发明人： Asaki NAKANE ,  Shigehiro KOIDE ,  Yasuharu YAMADA

    IPC分类号： C09D4/02 ,  C09D7/12

    CPC分类号： C09D7/40 ,  C08G83/001 ,  C08K9/08 ,  C09D4/00 ,  C09D7/62

    摘要： A method of preparing a resin composition for hard coat, comprises: a first step of obtaining a polyfunctional (meth)acrylate monomer modifying agent by addition reaction between a modifying agent having a thiol group and a three- or more functional (meth)acrylate monomer to form a covalent bond between the thiol group and acryloyl group and/or methacryloyl group, and a second step of modifying metal oxide microparticles with the polyfunctional (meth)acrylate monomer modifying agent that is obtained from the first step.

    摘要翻译： 一种制备硬涂层树脂组合物的方法，包括：通过具有硫醇基的改性剂和三官能以上的（甲基）丙烯酸酯单体之间的加成反应获得多官能（甲基）丙烯酸酯单体改性剂的第一步骤 在硫醇基和丙烯酰基和/或甲基丙烯酰基之间形成共价键，以及用第一步获得的多官能（甲基）丙烯酸酯单体改性剂改性金属氧化物微粒的第二步骤。

    Method of preparing resin composition for hard coat and resin composition for hard coat
    2.
    发明授权
    Method of preparing resin composition for hard coat and resin composition for hard coat 有权
    硬涂层用树脂组合物及硬质涂层用树脂组合物的制备方法

    公开(公告)号：US09062214B2

    公开(公告)日：2015-06-23

    申请号：US13208998

    申请日：2011-08-12

    申请人： Asaki Nakane ,  Shigehiro Koide ,  Yasuharu Yamada

    发明人： Asaki Nakane ,  Shigehiro Koide ,  Yasuharu Yamada

    IPC分类号： C08F290/06 ,  C09D7/12 ,  C09D4/00 ,  C08G83/00 ,  C08K9/08

    CPC分类号： C09D7/40 ,  C08G83/001 ,  C08K9/08 ,  C09D4/00 ,  C09D7/62

    摘要： A method of preparing a resin composition for hard coat, comprises: a first step of obtaining a polyfunctional (meth)acrylate monomer modifying agent by addition reaction between a modifying agent having a thiol group and a three- or more functional (meth)acrylate monomer to form a covalent bond between the thiol group and acryloyl group and/or methacryloyl group, and a second step of modifying metal oxide microparticles with the polyfunctional (meth)acrylate monomer modifying agent that is obtained from the first step.

    摘要翻译： 一种制备硬涂层树脂组合物的方法，包括：通过具有硫醇基的改性剂和三官能以上的（甲基）丙烯酸酯单体之间的加成反应获得多官能（甲基）丙烯酸酯单体改性剂的第一步骤 在硫醇基和丙烯酰基和/或甲基丙烯酰基之间形成共价键，以及用第一步获得的多官能（甲基）丙烯酸酯单体改性剂改性金属氧化物微粒的第二步骤。

    Thermally color-developing reversibly thermochromic pigment
    3.
    发明授权
    Thermally color-developing reversibly thermochromic pigment 有权
    热变色可逆热变色颜料

    公开(公告)号：US07332109B2

    公开(公告)日：2008-02-19

    申请号：US10323844

    申请日：2002-12-20

    申请人： Kuniyuki Senga ,  Katsuyuki Fujita ,  Shigehiro Koide

    发明人： Kuniyuki Senga ,  Katsuyuki Fujita ,  Shigehiro Koide

    IPC分类号： G02B5/22 ,  G02B5/20 ,  G02F1/01

    CPC分类号： B41M5/3375 ,  B41M5/28 ,  B41M5/305

    摘要： A thermally color-developing reversibly thermochromic pigment which shows a uniform color density in the coloring temperature range and also shows an optimal ΔH value within a range of from 3 to 40° C. Thermally color-developing reversibly thermochromic pigments of a three component system having a ΔH value within a range of from 7 to 40° C. in which at least essential three components including (a) an electron-donating chromic organic compound, (b) a specified compound selected from the gallic acid esters and (c) a reaction medium selected from alcohols, esters, ketones and hydrocarbons; which reversibly generates color reactions of both of the compounds within a specified temperature range and has a melting point of less than 50° C., are microencapsulated, and of a four component system having a ΔH value within a range of from 3 to 25° C. in which a compound (d) selected from monomer compounds having a melting point of 50° C. or more or polymer compounds having a softening point of 70° C. or more is added to the three component system.

    摘要翻译： 一种热显色可逆热变色颜料，其在着色温度范围内显示均匀的色密度，并且还显示出在3至40℃范围内的最佳ΔH值。具有三组分体系的热显色可逆热变色颜料 至少必要的三种组分，包括（a）给电子的铬有机化合物，（b）选自没食子酸酯的特定化合物和（c）a 选自醇，酯，酮和烃的反应介质; 其可以在特定温度范围内可逆地产生两种化合物的显色反应，并且具有低于50℃的熔点，微胶囊化，以及ΔH值在3至25°范围内的四组分体系 其中将选自熔点为50℃以上的单体化合物的化合物（d）或软化点为70℃以上的高分子化合物加入到三组分体系中。

    Reversible thermochromic display article
    5.
    发明授权
    Reversible thermochromic display article 有权
    可逆热变色显示制品

    公开(公告)号：US07335624B2

    公开(公告)日：2008-02-26

    申请号：US11043195

    申请日：2005-01-27

    申请人： Kuniyuki Senga ,  Katsuyuki Fujita ,  Shigehiro Koide

    发明人： Kuniyuki Senga ,  Katsuyuki Fujita ,  Shigehiro Koide

    IPC分类号： B41M5/30

    CPC分类号： B41M5/284

    摘要： A reversible thermochromic display article which comprises a substrate and, formed thereon, a heat coloration image containing a heat coloration type reversible thermochromic composition which is colored by heating and is decolored by cooling and a heat decoloration image containing a heat decoloration type reversible thermochromic composition which is decolored by heating and is colored by cooling, or having a multilayer structure comprising a heat coloration layer containing the heat coloration type reversible thermochromic composition and a heat decoloration layer containing the heat decoloration type reversible thermochromic composition, wherein the heat coloration type reversible thermochromic composition is a microcapsule composition which contains, enclosed therein, (a) an electron-donating chromatic organic compound, (b)′ an electron-accepting compound selected from gallic acid esters, and (c) a reaction medium having a melting point lower than 50° C. which is selected from alcohols, esters, ketones, and hydrocarbons and which causes color reactions between the two components to occur reversibly at specific temperatures.

    摘要翻译： 一种可逆热致变色显示制品，其包括基材，并且在其上形成含有通过加热着色并通过冷却而脱色的加热着色型可逆热变色组合物的加热着色图像，以及含有热脱色型可逆热变色组合物的热脱色图像 通过加热进行脱色，并通过冷却着色，或具有包含含有着色型可逆热变色组合物的加色层的多层结构和含有热脱色型可逆热变色组合物的热脱色层，其中，着色型可逆热变色组合物 是包含（a）给电子的有机有机化合物，（b）选自没食子酸酯的电子接受性化合物和（c）熔点低于50℃的反应介质的微胶囊组合物 ℃，选自al 醇，酯，酮和烃，并且导致两种组分之间的颜色反应在特定温度下可逆地发生。

    Reversible thermochromic display article
    6.
    发明申请
    Reversible thermochromic display article 有权
    可逆热变色显示制品

    公开(公告)号：US20060166822A1

    公开(公告)日：2006-07-27

    申请号：US11043195

    申请日：2005-01-27

    申请人： Kuniyuki Senga ,  Katsuyuki Fujita ,  Shigehiro Koide

    发明人： Kuniyuki Senga ,  Katsuyuki Fujita ,  Shigehiro Koide

    IPC分类号： B41M5/20

    CPC分类号： B41M5/284

    摘要： A reversible thermochromic display article which comprises a substrate and, formed thereon, a heat coloration image containing a heat coloration type reversible thermochromic pigment which is colored by heating and is decolored by cooling and a heat decoloration image containing a heat decoloration type reversible thermochromic pigment which is decolored by heating and is colored by cooling, or having a multilayer structure comprising a heat coloration layer containing the heat coloration type reversible thermochromic pigment and a heat decoloration layer containing the heat decoloration type reversible thermochromic pigment, wherein the heat coloration type reversible thermochromic pigment is a microcapsule pigment which contains, enclosed therein, (a) an electron-donating chromatic organic compound, (b)′ an electron-accepting compound selected from gallic acid esters, and (c) a reaction medium having a melting point lower than 50° C. which is selected from alcohols, esters, ketones, and hydrocarbons and which causes color reactions between the two components to occur reversibly at specific temperatures.

    摘要翻译： 一种可逆热致变色显示制品，其包括基底，并在其上形成含有通过加热着色并通过冷却而脱色的加热着色型可逆热变色颜料的加热着色图像和含有热脱色型可逆热变色颜料的热脱色图像 通过加热进行脱色，并通过冷却着色，或具有包含含有着色型可逆热变色颜料的加色层的多层结构和含有热脱色型可逆热变色颜料的热脱色层，其中，着色型可逆热变色颜料 是一种微胶囊颜料，其中包含（a）给电子有机有机化合物，（b）选自没食子酸酯的电子接受性化合物，（c）熔点低于50℃的反应介质 ℃，其选自醇，酯，酮， 并且其导致两种组分之间的颜色反应在特定温度下可逆地发生。