Process and aqueous compositions for treating metal surfaces
    1.
    发明授权
    Process and aqueous compositions for treating metal surfaces 失效
    用于处理金属表面的方法和含水组合物

    公开(公告)号:US4761189A

    公开(公告)日:1988-08-02

    申请号:US53598

    申请日:1987-05-20

    摘要: The invention relates to a process for treating metal surfaces, preferably of aluminum, aluminum alloys and steel, for the subsequent application of organic coating compositions. The metal surfaces are wetted with an aqueous bath solution containing chromium(III)ions, fluoride ions and an organic film former which is soluble or homogeneously dispersible in water, after which the solution applied is dried and converted by heating into a water-insoluble film.The bath solution preferably contains the following constituents and approximate quantities thereof: 0.5 to 10 g/l of chromium(III)ions, 0.55 to 11 g/l of fluoride ions, 0.6 to 12.5 g/l of phosphate ions, and 0.15 to 5.0 g/l of organic film former. The organic film former preferably used is a polymer containing free carboxyl groups, more preferably a homopolymer and/or copolymer of acrylic and/or methacrylic acid.

    摘要翻译: 本发明涉及用于处理金属表面,优选铝,铝合金和钢的方法,用于随后应用有机涂料组合物。 金属表面用含有铬(III)离子,氟离子和可溶于或均匀分散在水中的有机成膜剂的含水浴溶液润湿,之后将所施加的溶液干燥并通过加热转化成水不溶性膜 。 浴溶液优选包含以下成分及其近似量:0.5至10g / l的铬(III)离子,0.55至11g / l的氟离子,0.6至12.5g / l的磷酸根离子和0.15至5.0 g / l有机成膜剂。 优选使用的有机成膜剂是含有游离羧基的聚合物,更优选丙烯酸和/或甲基丙烯酸的均聚物和/或共聚物。

    Process for forming a resinous coating from an autodepositing composition which includes internally stabilized vinylidene chloride copolymer
    2.
    发明授权
    Process for forming a resinous coating from an autodepositing composition which includes internally stabilized vinylidene chloride copolymer 失效
    用于从包含内部稳定的偏二氯乙烯共聚物的自动沉积组合物形成树脂涂层的方法

    公开(公告)号:US06224947B1

    公开(公告)日:2001-05-01

    申请号:US08467622

    申请日:1995-06-06

    IPC分类号: B05D118

    摘要: Improved autodeposited coatings on metallic surfaces are formed by contacting the metallic surfaces with an autodepositing composition comprising an acidic aqueous coating solution containing dispersed solid resin particles or either an internally stabilized or externally stabilized vinylidene chloride polymer, an exemplary internally stabilized polymer being prepared from vinylidene chloride and a monomeric surfactant which includes an inorganic ionizable group, and an exemplary externally stabilized polymer being prepared from vinylidene chloride and a reactive comonomer, the resulting resin particles having surfactant adsorbed thereon, said autodeposited coatings having extremely good corrosion resistant properties without treatment with a reaction rinse such as a chromium rinse.

    摘要翻译: 通过使金属表面与包含分散的固体树脂颗粒或内部稳定或外部稳定的偏二氯乙烯聚合物的酸性水性涂料溶液的自动沉积组合物形成改进的自沉积涂层,由偏二氯乙烯制备的示例性内部稳定的聚合物 和包含无机电离基团的单体表面活性剂和由偏二氯乙烯和反应性共聚单体制备的示例性外部稳定的聚合物,所得树脂颗粒具有吸附在其上的表面活性剂,所述自动沉积涂料具有非常好的耐腐蚀性能,而不用反应处理 冲洗如铬冲洗。

    Chromium free treatment before coating metal surfaces
    3.
    发明授权
    Chromium free treatment before coating metal surfaces 失效
    镀金属表面之前无铬处理

    公开(公告)号:US5026440A

    公开(公告)日:1991-06-25

    申请号:US398108

    申请日:1989-08-24

    摘要: The adhesion of, and corrosion protection provided by, organic surface coatings to underlying metal can be significantly improved if the degreased, etched, and pickled metal surfaces to be coated are first treated with an aqueous solution and/or dispersion of aluminum-zirconium complexes, which are obtainable as the reaction-product of a chelated aluminum component, an organo-functional ligand component, and a zirconium oxyhalide component, with the organo-functional ligand being chemically bonded to the chelated aluminum unit and the zirconium unit in the complex, and are subsequently treated with dilute aqueous solutions, emulsions, and/or dispersions of one or more inorganic and/or organic film-forming materials prior to coating the surfaces with conventional organic surface coatings.

    摘要翻译: 如果要涂覆的脱脂,蚀刻和酸洗的金属表面首先用铝 - 锆络合物的水溶液和/或分散体进行处理,则可以显着改善有机表面涂层对底层金属提供的粘合性和腐蚀保护性, 其可以作为螯合铝组分,有机官能配体组分和卤氧化锆组分的反应产物获得,有机官能配体与络合物中的螯合铝单元和锆单元化学键合,以及 在用常规有机表面涂层涂覆表面之前,用一种或多种无机和/或有机成膜材料的稀水溶液,乳液和/或分散体进行处理。

    Internally stabilized vinylidene chloride resin in autodeposition
    4.
    发明授权
    Internally stabilized vinylidene chloride resin in autodeposition 失效
    内部稳定的偏二氯乙烯树脂自动沉积

    公开(公告)号:US5912297A

    公开(公告)日:1999-06-15

    申请号:US466218

    申请日:1995-06-06

    摘要: Improved autodeposited coatings on metallic surfaces are formed by contacting the metallic surfaces with an autodepositing composition comprising an acidic aqueous coating solution containing dispersed solid resin particles of either an internally stablilized or externally stabilized vinylidene chloride polymer, an exemplary internally stabilized polymer being prepared from vinylidene chloride and a monomeric surfactant which includes an inorganic ionizable group, and an exemplary externally stabilized polymer being prepared from vinylidene chloride and a reactive comonomer, the resulting resin particles having surfactant adsorbed thereon, said autodeposited coatings having extremely good corrosion resistant properties without treatment with a reaction rinse such as a chromium rinse.

    摘要翻译: 通过使金属表面与自动沉积组合物接触而形成改进的自沉积涂层,所述自动沉积组合物包含含有内部稳定或外部稳定的偏二氯乙烯聚合物的分散固体树脂颗粒的酸性水性涂料溶液,由偏二氯乙烯制备的示例性内部稳定的聚合物 和包含无机电离基团的单体表面活性剂和由偏二氯乙烯和反应性共聚单体制备的示例性外部稳定的聚合物,所得树脂颗粒具有吸附在其上的表面活性剂,所述自动沉积涂料具有非常好的耐腐蚀性能,而不用反应处理 冲洗如铬冲洗。

    Phosphating process for zinc-plated metals
    8.
    发明授权
    Phosphating process for zinc-plated metals 失效
    镀锌金属的磷化工艺

    公开(公告)号:US4497668A

    公开(公告)日:1985-02-05

    申请号:US554879

    申请日:1983-11-25

    IPC分类号: C23C22/12 C23C22/13 C23F7/08

    CPC分类号: C23C22/13 C23C22/12

    摘要: A process for phosphating zinc-plated metal articles, particularly electrolytically zinc-plated steel sheets, by treatment thereof for a short period with an acidic phosphating solution which, in addition to zinc and phosphate ions, can contain other metal cations and/or anions of oxygen-containing acids having an accelerating effect, wherein the phosphating solution has a content of Zn.sup.2+ -cations of between about 1 and 2.5 g/l, a free acid content in the range from 0.8 to 3 points, and the acid ratio of total acid to free acid in the range from 5 to 10. The phosphating treatment is carried out for a period of time not in excess of about 5 seconds.

    摘要翻译: 一种通过用酸性磷酸盐溶液处理短时间的镀锌金属制品,特别是电解镀锌钢板的方法,除了锌和磷酸根离子之外,还可以含有其它金属阳离子和/或阴离子 具有促进作用的含氧酸,其中磷酸盐化合物的Zn 2+离子含量在约1至2.5g / l之间,游离酸含量在0.8至3个点之间,而酸的酸的比例 游离酸在5至10的范围内。磷化处理进行不超过约5秒的时间。