公开(公告)号：US07250468B2

公开(公告)日：2007-07-31

申请号：US10819444

申请日：2004-04-07

申请人： Reinhard Harzschel ,  Thomas Bastelberger ,  Ulf Dietrich ,  Armin Hoffmann

发明人： Reinhard Harzschel ,  Thomas Bastelberger ,  Ulf Dietrich ,  Armin Hoffmann

IPC分类号： C08L29/04

CPC分类号： C08J3/122 ,  C04B24/163 ,  C04B24/2623 ,  C04B24/2641 ,  C04B24/2676 ,  C04B24/2688 ,  C04B2103/0057 ,  C04B2103/30 ,  C04B2111/62 ,  C04B2111/70 ,  C08L29/04

摘要： Polyvinyl-alcohol-stabilized redispersible powders which have plasticizing properties are obtained by drying polyvinyl-alcohol-stabilized aqueous dispersions of polymers of one or more monomers from the group of vinyl esters of optionally branched C1-18 alkylcarboxylic acids, (meth)acrylic esters of optionally branched C1-15 alcohols, dienes, olefins, vinylaromatics and vinylhalides, in the presence of a copolymer formed from a) one or more monomers from the group of ethylenically unsaturated monocarboxylic acids, ethylenically unsaturated dicarboxylic acids and their anhydrides, each having 4 to 8 carbon atoms, and salts thereof, b) one or more ethylenically unsaturated compounds containing sulfonic, sulfuric, and/or phosphonic acid groups, and salts thereof, and c) one or more monomers from the group consisting of vinyl esters of optionally branched C1-18 alkylcarboxylic acids and (meth)acrylic esters of optionally branched C1-15 alcohols.

摘要翻译： 具有增塑性能的聚乙烯醇稳定的可再分散粉末通过干燥聚乙烯醇稳定的一种或多种单体的聚合物的水分散体获得，该水分散体由任选支链C 1-18烷基羧酸的乙烯基酯组 酸，（甲基）丙烯酸酯，任选支链C 1-15醇，二烯，烯烃，乙烯基芳烃和卤代乙烯，在由以下组成的共聚物存在下形成：a）一种或多种烯属的单体 不饱和一元羧酸，烯键式不饱和二羧酸及其酸酐，各自具有4至8个碳原子，及其盐，b）一种或多种含有磺酸，硫酸和/或膦酸基团的烯属不饱和化合物及其盐，以及c ）一种或多种由任选支链C 1-18烷基羧酸的乙烯基酯和任选支链C 1-15醇的（甲基）丙烯酸酯组成的组中的单体。

公开(公告)号：US20060254468A1

公开(公告)日：2006-11-16

申请号：US10557658

申请日：2004-05-13

申请人： Thomas Bastelberger ,  Reinhard Harzschel ,  Franz Jodlbauer

发明人： Thomas Bastelberger ,  Reinhard Harzschel ,  Franz Jodlbauer

IPC分类号： C04B24/00

CPC分类号： C04B40/0042 ,  C04B24/085 ,  C04B2103/0057 ,  C04B2103/65 ,  C04B14/26 ,  C04B24/2623 ,  C04B24/42

摘要： Hydrophobicizing agents which are easily admixed with construction chemical products are prepared by providing a solution of a protective colloid and adding thereto a fatty acid compound sensitive to high pH environments, optionally, a hydrophobicizing organosilicon compound, and drying the resulting aqueous mixture.

摘要翻译： 通过提供保护胶体的溶液并向其中加入对高pH环境敏感的脂肪酸化合物，任选的疏水化有机硅化合物，并干燥所得的含水混合物，制备容易与构建化学产品混合的疏水剂。

公开(公告)号：US06656983B1

公开(公告)日：2003-12-02

申请号：US09856538

申请日：2001-08-01

申请人： Theo Mayer ,  Thomas Kohler ,  Reinhard Harzschel ,  Hans-Peter Weitzel ,  Bernd Schilling

发明人： Theo Mayer ,  Thomas Kohler ,  Reinhard Harzschel ,  Hans-Peter Weitzel ,  Bernd Schilling

IPC分类号： C08L100

CPC分类号： C09J125/10 ,  C08F236/10 ,  C08L2666/02 ,  C09J109/06

摘要： The invention provides mixed aromatic vinyl-1,3-diene polymers stabilized by a protective colloid and present in the form of aqueous polymer dispersions or polymer powders redispersible in water as adhesives for porous substrates. The polymer dispersions and the polymer powders are obtained by emulsion polymerization of a mixture containing: a) 20 to 80 percent by weight of one or more vinylaromatics; b) 19.9 to 79.9 percent by weight of one or more 1,3-dienes; c) 0.1 to 15 percent by weight of one or more comonomers from the group consisting of N-methylolacrylamide, N-methylolmethacrylamide and the N-(alkoxymethyl)-acrylamides and N-(alkoxymethyl)-methacrylamides with a C1 to C6-alkyl radical. The sum of the above percentages adds up to 100% by weight. Emulsion polymerization is carried out in the presence of one or more protective colloids and without emulsifiers, optionally followed by drying of the resulting aqueous polymer dispersion.

摘要翻译： 本发明提供了由保护胶体稳定并以聚合物水分散体形式存在的混合芳族乙烯基-1,3-二烯聚合物或可再分散在水中的聚合物粉末作为多孔基材的粘合剂。 聚合物分散体和聚合物粉末通过混合物的乳液聚合获得，所述混合物包含：a）20至80重量％的一种或多种乙烯基芳烃; b）19.9至79.9重量％的一种或多种1,3-二烯; c）0.1至15重量％的来自由N-羟甲基丙烯酰胺，N-羟甲基甲基丙烯酰胺和N-（烷氧基甲基） - 丙烯酰胺和具有C 1至C 6 - 烷基的N-（烷氧基甲基） - 甲基丙烯酰胺组成的组中的一种或多种共聚单体 。 上述百分比的总和高达100重量％。 乳液聚合在一种或多种保护胶体和不含乳化剂的存在下进行，任选然后干燥所得的聚合物水分散体。