公开(公告)号：US4623632A

公开(公告)日：1986-11-18

申请号：US668102

申请日：1984-11-05

申请人： Susan L. Lambert ,  Russell W. Johnson ,  Randy J. Lawson ,  Tery L. Barr

发明人： Susan L. Lambert ,  Russell W. Johnson ,  Randy J. Lawson ,  Tery L. Barr

IPC分类号： B01J29/10 ,  B01J29/064 ,  B01J29/52 ,  B01J29/61 ,  B01J29/62 ,  B01J29/72 ,  C07B61/00 ,  C07C1/00 ,  C07C5/41 ,  C07C15/00 ,  C07C15/46 ,  C07C67/00 ,  C10G11/02 ,  C10G11/05 ,  C10G35/095 ,  B01J29/04

CPC分类号： C10G35/095 ,  B01J29/62 ,  C07C5/417 ,  B01J2229/26 ,  B01J2229/42 ,  Y02P20/588

摘要： A novel catalytic composite, method of preparation, and process for the conversion of hydrocarbons is disclosed. The novel catalyst comprises a nonacidic zeolite having deposited thereon catalytically effective amounts of a Group VIII metal component and sufficient surface-deposited alkali metal to provide a surface-deposited alkali metal index of at least 10.

公开(公告)号：US5367101A

公开(公告)日：1994-11-22

申请号：US995455

申请日：1992-12-22

申请人： Randy J. Lawson ,  Dorothy M. Richmond ,  Gregory J. Gajda ,  Paul T. Barger

发明人： Randy J. Lawson ,  Dorothy M. Richmond ,  Gregory J. Gajda ,  Paul T. Barger

IPC分类号： C07C5/22 ,  C07C5/25 ,  C07C5/27 ,  C07C5/23

CPC分类号： C07C5/2206 ,  C07C5/2518 ,  C07C5/2775

摘要： An improved process is disclosed for the isomerization of pentenes in the absence of hydrogen using a catalyst comprising a non-zeolitic molecular sieve. It is of particular interest to increase the proportion of olefins containing tertiary carbons in the product with low formation of undesirable by-products. Product olefins may be further processed to obtain methyl t-amyl ether, which enjoy high current interest as components for reformulated gasoline. Pentenes in raffinate from etherification may be returned to the isomerization process.

摘要翻译： 公开了使用包含非沸石分子筛的催化剂在不存在氢的情况下使戊烯异构化的改进方法。 特别值得注意的是，产品中含有叔碳的烯烃的比例增加，形成不希望的副产物。 可以进一步处理产物烯烃以获得作为重整汽油的组分享有高电流兴趣的甲基叔戊基醚。 来自醚化的残液中的Pentenes可以返回到异构化过程。

公开(公告)号：US5321184A

公开(公告)日：1994-06-14

申请号：US997831

申请日：1992-12-29

申请人： Chi-Chu D. Low ,  Randy J. Lawson ,  Paul J. Kuchar ,  Gail L. Gray

发明人： Chi-Chu D. Low ,  Randy J. Lawson ,  Paul J. Kuchar ,  Gail L. Gray

IPC分类号： C07C5/27 ,  C07C5/22

CPC分类号： C07C5/2702 ,  C07C5/2724

摘要： A pretreatment method for a C.sub.8 aromatic isomerization process wherein the isomerization catalyst is initially contacted with a C.sub.8 aromatic feedstock under high severity isomerization conditions for a period of time sufficient to deposit a substantial amount to carbonaceous material on the catalyst. After pretreatment, the carbon-laden catalyst continues to be contacted by the C.sub.8 aromatic feedstock under less severe conditions than that of the pretreatment mode of operation.

摘要翻译： 用于C8芳族异构化方法的预处理方法，其中异构化催化剂最初在高严重度异构化条件下与C8芳族原料接触一段足以在催化剂上沉积大量碳质材料的时间。 在预处理之后，碳载体催化剂在比预处理操作模式更恶劣的条件下继续与C8芳族原料接触。

公开(公告)号：US5242576A

公开(公告)日：1993-09-07

申请号：US795573

申请日：1991-11-21

申请人： Robert J. Schmidt ,  Michael B. Russ ,  Paula L. Bogdan ,  Randy J. Lawson

发明人： Robert J. Schmidt ,  Michael B. Russ ,  Paula L. Bogdan ,  Randy J. Lawson

IPC分类号： C10G59/06

CPC分类号： C10G59/06

摘要： A process combination is disclosed to selectively upgrade naphtha to obtain gasoline which is in accordance with current standards for reformulated fuels. A naphtha feedstock is fractionated to selectively direct light naphtha to isomerization or blending, a heart-cut fraction to reforming, and a heavy portion to selective isoparaffin synthesis to yield light and heavy synthesis naphtha and isobutane. The heavy portion of the synthesis naphtha is processed by reforming. Light naphtha may be isomerized, with or without recycle of low-octane components of the product. A gasoline component is blended from light, synthesis, and reformate products from the process combination.

摘要翻译： 公开了一种方法组合以选择性地升级石脑油以获得符合目前重新配制的燃料标准的汽油。 分馏石脑油原料以选择性地将轻质石脑油引导至异构化或共混，心切成分转化为重馏分，并将重质部分引导至选择性异链烷烃合成以产生轻质和重质合成石脑油和异丁烷。 合成石脑油的重质部分通过重整进行处理。 轻石脑油可以异构化，有或没有产物的低辛烷值组分的再循环。 来自工艺组合的轻质，合成和重整产物的汽油组分混合。

公开(公告)号：US4957891A

公开(公告)日：1990-09-18

申请号：US448445

申请日：1989-12-11

申请人： Johann W. A. Sachtler ,  Randy J. Lawson ,  Susan L. Lambert

发明人： Johann W. A. Sachtler ,  Randy J. Lawson ,  Susan L. Lambert

IPC分类号： C07C5/27

CPC分类号： C07C5/2724

摘要： This invention presents a novel catalyst formulation for the isomerization of alkylaromatic hydrocarbons. The catalyst comprises at least one Group VIII metal, a pentasil zeolite wherein a portion of the aluminum atom has been replaced with gallium atoms and a matrix material of zirconia-alumina. When utilized in a process for isomerizing a non-equilibrium mixture of xylenes containing ethylbenzene, a greater yield of para-xylene is obtained compared to prior art processes.

摘要翻译： 本发明提出了用于烷基芳族烃异构化的新型催化剂配方。 该催化剂包含至少一种Ⅷ族金属，其中一部分铝原子被镓原子取代的五硅烷沸石和氧化锆 - 氧化铝的基质材料。 当用于异构化含有乙苯的二甲苯的非平衡混合物的方法中时，与现有技术方法相比，获得了更高的对二甲苯的产率。

公开(公告)号：US4619906A

公开(公告)日：1986-10-28

申请号：US734308

申请日：1985-05-15

申请人： Susan L. Lambert ,  Randy J. Lawson ,  Russell W. Johnson ,  Tery L. Barr

发明人： Susan L. Lambert ,  Randy J. Lawson ,  Russell W. Johnson ,  Tery L. Barr

IPC分类号： B01J29/10 ,  B01J29/064 ,  B01J29/52 ,  B01J29/61 ,  B01J29/62 ,  B01J29/72 ,  C07B61/00 ,  C07C1/00 ,  C07C5/41 ,  C07C15/00 ,  C07C15/46 ,  C07C67/00 ,  C10G11/02 ,  C10G11/05 ,  C10G35/095

CPC分类号： C10G35/095 ,  B01J29/62 ,  C07C5/417 ,  B01J2229/26 ,  B01J2229/42 ,  Y02P20/588

摘要： A novel catalytic composite, a method of making the composite, and use of the composite is disclosed. The novel catalyst comprises a nonacidic zeolite bound within a support matrix. Additionally, the catalyst comprises catalytically effective amounts of a Group VIII metal component. There is also present within the catalyst sufficient surface-deposited alkali metal to provide a surface-deposited alkali metal index of at least 10. The catalytic composite has utility for the conversion of hydrocarbons and, in particular, has specific utility as a dehydrocyclization catalyst.

摘要翻译： 公开了一种新型催化复合材料，制备该复合材料的方法和该复合材料的用途。 新型催化剂包含结合在载体基质内的非酸性沸石。 另外，催化剂包含催化有效量的VIII族金属组分。 在催化剂中还存在足够的表面沉积的碱金属以提供至少10的表面沉积的碱金属指数。催化复合材料具有用于转化烃的用途，特别是作为脱氢环化催化剂具有特定用途。

公开(公告)号：US4464480A

公开(公告)日：1984-08-07

申请号：US498625

申请日：1983-05-27

申请人： Hassan Windawi ,  Randy J. Lawson

发明人： Hassan Windawi ,  Randy J. Lawson

IPC分类号： B01J23/78 ,  B01J37/02 ,  B01J21/02 ,  B01J31/02

CPC分类号： B01J37/0203 ,  B01J23/78

摘要： Improved catalyst systems which may be used for a wide variety of chemical reactions such as gas conversion reactions may be prepared by impregnating a transition metal compound which may contain a structural promoter with a nonaqueous solution of an alkali metal superhydride in order to provide a more uniform distribution of the chemical promoter on the active surface of the catalyst. As an example, iron oxide which has been structurally promoted with aluminum may be impregnated with a nonaqueous solution of potassium triethyl-borohydride to prepare an active gas conversion catalyst.

摘要翻译： 可用于各种化学反应如气体转化反应的改进的催化剂体系可以通过用含有碱金属超级氢氧化物的非水溶液浸渍可含有结构促进剂的过渡金属化合物来制备，以提供更均匀的 化学助催化剂在催化剂活性表面上的分布。 例如，用铝结构促进的氧化铁可以用三乙基硼氢化钾的非水溶液浸渍以制备活性气体转化催化剂。

公开(公告)号：US4962259A

公开(公告)日：1990-10-09

申请号：US447274

申请日：1989-12-07

申请人： Johann W. A. Sachtler ,  Randy J. Lawson ,  Susan L. Lambert

发明人： Johann W. A. Sachtler ,  Randy J. Lawson ,  Susan L. Lambert

IPC分类号： C07C5/27

CPC分类号： C07C5/2724

摘要： This invention presents a novel catalyst formulation for the isomerization of alkylaromatic hydrocarbons. The catalyst is comprised of at least one Group VIII metal, and a pentasil zeolite having an x-ray diffraction characteristic of ZSM-12 wherein a portion of the aluminum atoms have been replaced with gallium atoms. When utilized in a process for isomerizing a non-equilibrium mixture of xylenes containing ethylbenzene, a greater yield of paraxylene is obtained compared to prior-art processes.

摘要翻译： 本发明提出了用于烷基芳族烃异构化的新型催化剂配方。 催化剂由至少一种VIII族金属和具有ZSM-12的X射线衍射特性的pentasil沸石组成，其中一部分铝原子被镓原子代替。 当用于异构化含有乙苯的二甲苯的非平衡混合物的方法中时，与现有技术方法相比，获得更高的对二甲苯收率。

公开(公告)号：US4677094A

公开(公告)日：1987-06-30

申请号：US910099

申请日：1986-09-22

申请人： Mark D. Moser ,  Randy J. Lawson

发明人： Mark D. Moser ,  Randy J. Lawson

IPC分类号： B01J27/135 ,  B01J23/62 ,  B01J23/89 ,  B01J35/00 ,  B01J37/18 ,  C10G11/02 ,  C10G35/085 ,  C10G35/09 ,  C10G35/095 ,  C10G45/46 ,  C10G49/06 ,  C10G49/08

CPC分类号： B01J35/008 ,  B01J23/624 ,  B01J23/626 ,  B01J23/628 ,  B01J23/8933 ,  B01J23/8966 ,  B01J35/0006 ,  B01J35/0073 ,  B01J35/0093 ,  B01J37/18 ,  C10G35/09

摘要： A novel trimetallic catalytic composite, a method of manufacture and process use thereof is disclosed. The composite comprises a refractory support having a nominal diameter of at least 650 microns and having deposited thereon a uniformly dispersed platinum component, a uniformly dispersed tin component and a surface-impregnated metal component selected from the group consisting of rhodium, ruthenium, cobalt, nickel, iridium and mixtures thereof. When this catalytic composite is used in the reforming of hydrocarbons at low pressures significant improvements in activity stability is observed compared to catalysts of the prior art.

摘要翻译： 公开了一种新型的三金属催化复合材料，其制造方法和工艺用途。 复合材料包括具有至少650微米的标称直径的耐火支撑体，并且在其上沉积有均匀分散的铂组分，均匀分散的锡组分和选自铑，钌，钴，镍的表面浸渍金属组分 ，铱及其混合物。 当这种催化复合材料用于低压烃转化时，与现有技术的催化剂相比，观察到活性稳定性显着改善。

公开(公告)号：US4422959A

公开(公告)日：1983-12-27

申请号：US376080

申请日：1982-05-07

申请人： Randy J. Lawson ,  Russell W. Johnson ,  Lee Hilfman

发明人： Randy J. Lawson ,  Russell W. Johnson ,  Lee Hilfman

IPC分类号： B01J23/847 ,  C10G47/12 ,  C10G13/02 ,  B01J21/12 ,  B01J37/02

CPC分类号： B01J23/8472 ,  C10G47/12

摘要： A catalytic composite is disclosed which catalyst comprises a silica-alumina carrier material, a nickel component and a vanadium component, and which catalyst is useful for the conversion of hydrocarbons. A preferred method of preparation comprises the incorporation of the vanadium component from an alcoholic solution of a vanadium compound.

摘要翻译： 公开了催化剂复合材料，该催化剂包括二氧化硅 - 氧化铝载体材料，镍组分和钒组分，并且该催化剂可用于烃的转化。 优选的施用方法包括从钒化合物的醇溶液中加入钒组分。