公开(公告)号：US20060014635A1

公开(公告)日：2006-01-19

申请号：US11200038

申请日：2005-08-10

Applicant: Alain Forestiere ,  P. Hubert Mutin ,  Andre Vioux ,  Gilles Guerrero

Inventor： Alain Forestiere ,  P. Hubert Mutin ,  Andre Vioux ,  Gilles Guerrero

IPC: C07F15/00

CPC classification number: B01J31/0217 ,  B01J20/3204 ,  B01J20/321 ,  B01J20/3251 ,  B01J20/3257 ,  B01J20/3259 ,  B01J31/0211 ,  B01J31/0212 ,  B01J31/0225 ,  B01J31/0259 ,  B01J31/10 ,  B01J37/033 ,  C07F9/095 ,  C07F9/3294 ,  C07F9/409

Abstract: The invention describes materials comprising organic groups containing sulphur and phosphorous bonded together by a hydrocarbon chain and bonded via phosphorous and oxygen atoms to a mineral oxide of an element M, said materials being characterized in that they comprise M-O-M′ bonds, M′representing an element of a mineral oxide identical to or different from M, in that the ratio of the element M to the phosphorous is about 0.5: 1 to about 500:1 and in that each phosphorous atom of the phosphorous-containing groups forms at least one P—O-M bond and/or P—O-M′ bond. The invention also describes a process for preparing such materials.

Abstract translation: 本发明描述了包含含硫和磷的有机基团的材料，其通过烃链键合在一起并通过磷和氧原子键合到元素M的矿物氧化物，所述材料的特征在于它们包含MOM'键，M'表示元素 的与M相同或不同的矿物氧化物，其中元素M与磷的比例为约0.5:1至约500:1，并且所述含磷基团的每个磷原子形成至少一个POM键 和/或POM'债券。 本发明还描述了制备这种材料的方法。

公开(公告)号：US07160836B2

公开(公告)日：2007-01-09

申请号：US11200038

申请日：2005-08-10

Applicant: Alain Forestiere ,  P. Hubert Mutin ,  Andre Vioux ,  Gilles Guerrero

Inventor： Alain Forestiere ,  P. Hubert Mutin ,  Andre Vioux ,  Gilles Guerrero

IPC: B01J31/00

CPC classification number: B01J31/0217 ,  B01J20/3204 ,  B01J20/321 ,  B01J20/3251 ,  B01J20/3257 ,  B01J20/3259 ,  B01J31/0211 ,  B01J31/0212 ,  B01J31/0225 ,  B01J31/0259 ,  B01J31/10 ,  B01J37/033 ,  C07F9/095 ,  C07F9/3294 ,  C07F9/409

Abstract: The invention describes materials comprising organic groups containing sulphur and phosphorous bonded together by a hydrocarbon chain and bonded via phosphorous and oxygen atoms to a mineral oxide of an element M, said materials being characterized in that they comprise M-O-M′ bonds, M′representing an element of a mineral oxide identical to or different from M, in that the ratio of the element M to the phosphorous is about 0.5: 1 to about 500:1 and in that each phosphorous atom of the phosphorous-containing groups forms at least one P—O-M bond and/or P—O-M′ bond. The invention also describes a process for preparing such materials.

Abstract translation: 本发明描述了包含含硫和磷的有机基团的材料，其通过烃链键合在一起并通过磷和氧原子键合到元素M的矿物氧化物，所述材料的特征在于它们包含MOM'键，M'表示元素 的与M相同或不同的矿物氧化物，其中元素M与磷的比例为约0.5:1至约500:1，并且所述含磷基团的每个磷原子形成至少一个POM键 和/或POM'债券。 本发明还描述了制备这种材料的方法。

公开(公告)号：US06958307B2

公开(公告)日：2005-10-25

申请号：US09930153

申请日：2001-08-16

Applicant: Alain Forestiere ,  P-Hubert Mutin ,  André Vioux ,  Gilles Guerrero

Inventor： Alain Forestiere ,  P-Hubert Mutin ,  André Vioux ,  Gilles Guerrero

IPC: B01J20/281 ,  B01J20/32 ,  B01J21/04 ,  B01J21/06 ,  B01J31/02 ,  C01B13/14 ,  C01F7/02 ,  C01G1/02 ,  C01G23/04 ,  C07F5/06 ,  C07F7/28 ,  C07F9/38 ,  C07F9/40 ,  G01N30/88 ,  B01J31/00 ,  B01J20/22 ,  B01J27/14

CPC classification number: B01J31/0225 ,  B01J20/3204 ,  B01J20/3219 ,  B01J20/3248 ,  B01J20/3251 ,  B01J20/3257 ,  B01J20/3259 ,  B01J20/3265 ,  B01J21/04 ,  B01J21/063 ,  B01J21/066 ,  B01J31/0269 ,  B82Y30/00 ,  B82Y40/00

Abstract: The present invention relates to a composition including an organic phosphorous-containing group bonded via an oxygen atom to a metal oxide of at least one element M. Generally, the composition is essentially amorphous, and includes an essentially monomolecular layer of an organic group directly bonded to the phosphorous atom. In addition, the composition is generally essentially free of any phosphate, phosphonate or phosphinate phase of the element M. Moreover, the composition has a ratio of the element M to phosphorous of about 15:1-200:1.

Abstract translation: 本发明涉及包含通过氧原子与至少一个元素M的金属氧化物键合的含有机磷基团的组合物。通常，该组合物基本上是无定形的，并且包括直接键合的有机基团的基本单分子层 到磷原子。 此外，组合物通常基本上不含元素M的任何磷酸盐，膦酸盐或次膦酸盐相。此外，组合物的元素M与磷的比例为约15：1-200:1。