公开(公告)号：US20030045425A1

公开(公告)日：2003-03-06

申请号：US10136691

申请日：2002-04-30

申请人： OMG AG & Co. KG

发明人： Karsten Ruth ,  Peter Biberbach ,  Karl Anton Starz

IPC分类号： B01J023/38

CPC分类号： B82Y30/00 ,  B01J21/18 ,  B01J23/38 ,  B01J23/54 ,  B01J23/6522 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/0033 ,  B01J35/0053 ,  B01J35/006 ,  B01J37/08 ,  H01M4/90 ,  H01M4/9075 ,  H01M4/9083 ,  H01M4/92 ,  H01M4/921 ,  H01M4/925 ,  H01M4/926

摘要： The invention provides a noble metal-containing supported catalyst which contains one of the noble metals from the group Au, Ag, Pt, Pd, Rh, Ru, Ir, Os or alloys of one or more of these noble metals in the form of noble metal particles on a powdered support material. The particles deposited on the support material have a degree of crystallinity, determined by X-ray diffraction, of more than 2 and an average particle size between 2 and 10 nm. The high crystallinity and the small particle size of the noble metal particles lead to high catalytic activity for the catalyst. It is particularly suitable for use in fuel cells and for the treatment of exhaust gases from internal combustion engines.

摘要翻译： 本发明提供一种贵金属负载催化剂，其含有Au，Ag，Pt，Pd，Rh，Ru，Ir，Os族中的一种贵金属或贵金属中的一种或多种的贵金属的贵金属 粉末状载体材料上的金属颗粒。 沉积在载体材料上的颗粒具有通过X射线衍射确定的大于2的结晶度，平均粒度在2和10nm之间。 贵金属颗粒的高结晶度和小颗粒尺寸导致催化剂的高催化活性。 它特别适用于燃料电池和用于处理来自内燃机的废气。

公开(公告)号：US20020150799A1

公开(公告)日：2002-10-17

申请号：US10109152

申请日：2002-03-27

申请人： OMG AG & Co., KG

发明人： Frank Baumann ,  Stefan Wieland ,  Peter Britz ,  Klaus Heikrodt

IPC分类号： H01M008/06

CPC分类号： H01M8/0612 ,  H01M8/0662 ,  Y02P70/56

摘要： The invention provides a combined heat and power plant with an integrated gas production system. The combined heat and power plant contains a steam reformer heated with a gas burner which converts a mixture of hydrocarbons and water vapour into a reformate gas stream containing hydrogen and carbon monoxide. The plant further contains a reactor system with several stages for removing carbon monoxide from the reformate gas stream. The plant also contains a heat exchanger for removing heat energy from the reformate gas stream and a fuel cell unit for producing electrical energy by catalytic reaction of the hydrogen contained in the reformate gas with oxygen in the fuel cell, wherein the reformate gas stream is supplied to the anode in the fuel cell unit and the anode waste gas is taken to the gas burner of the steam reformer as fuel, via a gas pipe. The reactor system for removing carbon monoxide from the reformate gas stream contains, according to one embodiment of the invention, a low temperature shift reactor and a downstream methanisation reactor and the heat exchanger for cooling the reformate gas stream leaving the steam reformer to the inlet temperature of the low temperature shift reactor is located in the reformate gas stream between the steam reformer and the low temperature shift reactor. This combined heat and power plant is operated according to the invention in such a way that the reformate gas contains 5 to 10 vol. % of unreformed hydrocarbon which enables the flame in the gas burner to be monitored using an ionisation detector when burning the anode waste gas in the gas burner of the steam reformer.

摘要翻译： 本发明提供了一种具有集成气体生产系统的组合式热电厂。 组合的热电厂包含用气体燃烧器加热的蒸汽重整器，其将烃和水蒸汽的混合物转化为含有氢和一氧化碳的重整产品气流。 该设备还包含一个反应器系统，其具有几个阶段用于从重整产品气流中除去一氧化碳。 该设备还包含用于从重整产品气流中除去热能的热交换器和用于通过燃料电池中重整气体中所含的氢气与氧气的催化反应来产生电能的燃料电池单元，其中重整气流被供应 到燃料电池单元中的阳极，并且通过气体管将阳极废气作为燃料被带到蒸汽重整器的气体燃烧器。 根据本发明的一个实施方案，用于从重整产品气流中除去一氧化碳的反应器系统包含低温变换反应器和下游甲烷化反应器，以及用于将离开蒸汽重整器的重整产品气流冷却至入口温度的热交换器 的低温变换反应器位于蒸汽重整器和低温变换反应器之间的重整产品气流中。 根据本发明，这种组合的热电厂是以重整气体含有5〜10vol。 ％的未重整烃，当燃烧蒸汽重整器的气体燃烧器中的阳极废气时，能够使用电离检测器监测气体燃烧器中的火焰。

公开(公告)号：US20020121083A1

公开(公告)日：2002-09-05

申请号：US10056814

申请日：2002-01-24

申请人： OMG AG & Co. KG

发明人： Dieter Lindner ,  Jorg-Michael Richter ,  Egbert Lox ,  Thomas Kreuzer ,  Martin Votsmeier ,  Lothar Mussmann

IPC分类号： F01N003/00 ,  F01N007/00 ,  G01M019/00

CPC分类号： F02D41/2458 ,  F02D41/0295 ,  F02D41/1408 ,  F02D41/1456 ,  F02D2041/1437 ,  F02D2200/0814 ,  Y02T10/22

摘要： A process is provided for operating a three-way catalyst that contains an oxygen storage component, that has a minimum and a maximum filling degree for oxygen and that is located in the exhaust gas line of an internal combustion engine. The air/fuel mixture supplied to the engine is varied in such a way that the filling degree of the oxygen storage component in the catalyst is held within a set-point interval between the minimum and maximum filling degree. According to this process, in order to regulate the air/fuel mixture, migration of the filling degree out of the set-point interval is checked in a test phase in such a way that the filling degree is increased or lowered relative to the instantaneous value (initial value) by short-term enrichment or reduction in richness of the air/fuel mixture supplied to the engine by a certain amount and immediately returned to the initial value by a short-term opposing change in the air/fuel mixture (lean/rich pulse sequence or rich/lean pulse sequence). In the case of a breakthrough of lean or rich exhaust gas through the catalyst during the test phase, the air/fuel mixture is enriched or reduced in richness in order to correct the filling degree, wherein the amount by which the filling degree during the test phase is increased or decreased is such that no breakthrough of lean or rich exhaust gas takes place through the catalyst when the filling degree of the oxygen storage component is within the set-point interval.

摘要翻译： 提供了一种用于操作含有储氧部件的三元催化剂的方法，其具有氧气的最小和最大填充度，并且位于内燃机的废气管线中。 提供给发动机的空气/燃料混合物以使得催化剂中的储氧组分的填充度保持在最小和最大填充度之间的设定点间隔内的方式变化。 根据该过程，为了调节空气/燃料混合物，在测试阶段中检查填充度在设定点间隔之外的迁移，使得填充度相对于瞬时值增加或降低 （初始值），通过短时间浓缩或将提供给发动机的空气/燃料混合物的浓度降低一定量，并立即通过空气/燃料混合物的短期相反变化（稀/ 富脉冲序列或富/脉冲序列）。 在试验阶段通过催化剂的贫或富排气的突破的情况下，空气/燃料混合物的浓度丰富或减少，以便校正填充度，其中在试验期间填充度的量 相位增加或减少使得当储氧部件的填充度在设定点间隔内时，没有通过催化剂发生贫或富排气的突破。

公开(公告)号：US20020116952A1

公开(公告)日：2002-08-29

申请号：US10079031

申请日：2002-02-19

申请人： OMG AG & Co. KG

发明人： Rudolf Singer

IPC分类号： C03B007/098

CPC分类号： C03B7/098 ,  C03B5/26 ,  C03B7/088 ,  Y10S65/04

摘要： The present invention provides devices for glass melt devlivery and methods for using these devices. In these devices, a delivery nozzle comprising at least one platinum group metal material is directly heated by electricty. To facilitate heating, a cylindrical heating ring is mounted in ceramic base. The device's construction ensures a regulatable heating of the nozzle and the melted glass flux.

摘要翻译： 本发明提供了用于玻璃熔体成型的装置和使用这些装置的方法。 在这些装置中，包含至少一种铂族金属材料的输送喷嘴被电力直接加热。 为了方便加热，圆筒形加热环安装在陶瓷基体中。 该设备的结构确保了喷嘴和熔化的玻璃熔剂的可调节加热。

公开(公告)号：US20020116920A1

公开(公告)日：2002-08-29

申请号：US10058685

申请日：2002-01-28

申请人： OMG AG & Co. KG

发明人： Marcus Pfeifer ,  Barry Van Setten ,  Jurgen Gieshoff ,  Paul Spurk ,  Egbert Lox ,  Thomas Kreuzer

IPC分类号： F01N003/00 ,  F01N003/10

CPC分类号： F01N3/0842 ,  B01D53/9418 ,  B01D53/944 ,  B01D53/945 ,  B01D53/9477 ,  B01D2255/1021 ,  B01D2255/911 ,  F01N3/0814 ,  F01N3/20 ,  F01N13/009 ,  F01N13/0097 ,  Y02T10/22 ,  Y02T10/24

摘要： The present invention provides an exhaust gas treatment unit for an internal combustion engine. A first catalyst unit produces ammonia from corresponding constituents in a rich exhaust gas composition. A second catalyst unit that is located downstream of the first catalyst unit temporarily stores the ammonia produced by the first catalyst unit in the presence of a rich exhaust gas composition. In the presence of a lean exhaust gas composition, the nitrogen oxides present in the exhaust gas are subjected to a reduction reaction using the temporarily stored ammonia as reducing agent. The exhaust gas treatment unit also contains a third catalyst unit that is located between the other two catalyst units, and oxidizes the nitrogen oxides present in the exhaust gas at lean exhaust gas conditions to a such an extent that 25 to 75 vol. % of the nitrogen oxides entering the second catalyst unit consist of nitrogen dioxide.

摘要翻译： 本发明提供一种用于内燃机的废气处理单元。 第一催化剂单元从富排气组合物中的相应组分产生氨。 位于第一催化剂单元下游的第二催化剂单元在富排气组合物的存在下临时存储由第一催化剂单元产生的氨。 在贫废气组合物的存在下，使用临时储存的氨作为还原剂对废气中存在的氮氧化物进行还原反应。 排气处理单元还含有位于其他两个催化剂单元之间的第三催化剂单元，并且将贫排气条件下的排气中存在的氮氧化物氧化至25〜75体积％ 进入第二催化剂单元的氮氧化物的％由二氧化氮组成。

公开(公告)号：US20030116472A1

公开(公告)日：2003-06-26

申请号：US10300173

申请日：2002-11-20

申请人： OMG AG & Co. KG

发明人： Stefan Wieland ,  Frank Baumann

IPC分类号： C10G035/06

CPC分类号： C01B3/323 ,  C01B2203/0244 ,  C01B2203/0844 ,  C01B2203/1023 ,  C01B2203/1029 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1217 ,  C01B2203/1247 ,  C01B2203/82 ,  Y02P20/52

摘要： The invention relates to a process for catalytic autothermal steam reforming of alcohols having two or more carbon atoms by directing a preheated educt or reactant mixture of the alcohols, oxygen and water or steam over a catalyst. The process is conducted in an adiabatic manner wherein the catalyst comprises at least one platinum group metal on an oxidic support selected from the group consisting of aluminum oxide, silicon dioxide, titanium dioxide or mixed oxides thereof and zeolites, and that the educt or reactant mixture contains additional hydrocarbons, which are reformed at the same time as the alcohols.

摘要翻译： 本发明涉及通过将催化剂上的醇，氧和水或蒸汽的预热的脱水或反应物混合物引入催化剂，从而对具有两个或多个碳原子的醇进行催化自热蒸汽重整的方法。 该方法以绝热方式进行，其中催化剂包含选自氧化铝，二氧化硅，二氧化钛或其混合氧化物的氧化物载体上的至少一种铂族金属和沸石，并且所述离子或反应物混合物 含有另外的烃，它们与醇同时重整。

公开(公告)号：US20030059658A1

公开(公告)日：2003-03-27

申请号：US10147102

申请日：2002-05-15

申请人： OMG AG & Co. KG

发明人： Joachim Kohler ,  Anita Kramer ,  Karl-Anton Starz ,  Knut Fehl ,  Armin Bayer

IPC分类号： H01M004/96 ,  H01M008/10 ,  H01M004/86 ,  B29C071/00

CPC分类号： H01M4/926 ,  C25B9/10 ,  H01M4/8605 ,  H01M4/8807 ,  H01M4/8828 ,  H01M4/8882 ,  H01M4/8896 ,  H01M8/1004 ,  Y02P70/56

摘要： The invention comprises a process for making a membrane electrode assembly comprising a polymer electrolyte membrane having two opposite faces, on each face of which is applied a catalyst layer and a gas distribution layer. The two gas distribution layers in the membrane electrode assembly are formed by hydrophobized carbon substrates which, using appropriate inks containing at least one catalyst, dissolved ionomer and solvent, are each coated with a catalyst layer and are then laid on opposite faces of the polymer electrolyte membrane with the catalyst layers still in the moist state. Afterwards, a firm bond between electrolyte membrane, catalyst layers and carbon substrates is produced by treating the membrane electrode assembly at elevated temperature under pressure.

摘要翻译： 本发明包括一种制造膜电极组件的方法，该膜电极组件包括具有两个相对面的聚合物电解质膜，每个表面上涂覆有催化剂层和气体分布层。 膜电极组件中的两个气体分配层由疏水化的碳基底形成，其中使用含有至少一种催化剂，溶解的离子交联聚合物和溶剂的合适的油墨各自涂覆有催化剂层，然后铺设在聚合物电解质的相对表面上 膜与催化剂层仍处于潮湿状态。 之后，通过在压力升高的温度下处理膜电极组件来产生电解质膜，催化剂层和碳基底之间的牢固结合。

公开(公告)号：US20020127932A1

公开(公告)日：2002-09-12

申请号：US10068547

申请日：2002-02-05

申请人： OMG AG & Co. KG

发明人： Jurgen Neumann ,  Dietmar Konigs ,  Thomas Stoll ,  Hubertus Golitzer

IPC分类号： B01J023/42

CPC分类号： D04B21/12 ,  B01J23/40 ,  B01J23/464 ,  B01J35/06 ,  C01B21/265 ,  C01C3/0216 ,  D04B1/14 ,  D04B21/04 ,  Y10T442/109 ,  Y10T442/322 ,  Y10T442/40

摘要： The present invention relates to three-dimensional catalyst gauzes for gas reactions knitted in two or more layers from noble metal wires in which the meshes of the individual layers are joined to one another by pile threads. In these catalyst gauzes weft threads are inserted between the mesh layers. These catalyst gauzes have an increased catalytic activity and efficiency in gas reaction. These improvements enable operation with a lower total amount of noble metal employed, for example by reducing the number of gauzes and/or the length of the wire processed in the catalyst gauze and/or the wire thickness, without thereby having to accept disadvantages with respect to the yield and selectivity of the gas reaction, mechanical strength and service life of the gauzes or unavoidable loss of noble metal.

摘要翻译： 本发明涉及用贵金属丝编织的两层或多层气体反应的三维催化剂纱布，其中各层的网格通过绒头线彼此接合。 在这些催化剂纱布中，纬纱线插入网格层之间。 这些催化剂纱布具有增加的催化活性和气体反应的效率。 这些改进使得能够以较低的所用贵金属总量进行操作，例如通过减少纱布的数量和/或在催化剂纱布中加工的丝的长度和/或丝线厚度，而不必因此而受到不利影响 对于气体反应的产率和选择性，纱布的机械强度和使用寿命或贵金属的不可避免的损失。

公开(公告)号：US20040186016A1

公开(公告)日：2004-09-23

申请号：US10389834

申请日：2003-03-17

申请人： OMG AG & Co. KG

发明人： Tassilo Bog ,  Lothar Mussmann ,  Dieter Lindner ,  Martin Votsmeier ,  Matthias Feger ,  Egbert Lox ,  Thomas Kreuzer ,  Mamoun Muhammed ,  Othon Adamopoulos

IPC分类号： B01J023/10

CPC分类号： B01J37/0242 ,  B01D53/945 ,  B01J23/002 ,  B01J23/10 ,  B01J23/63 ,  B01J35/04 ,  B01J2523/00 ,  C01F17/0012 ,  C01P2002/50 ,  C01P2002/60 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2006/90 ,  Y02T10/22 ,  B01J2523/23 ,  B01J2523/31 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/3706

摘要： An oxygen storage material comprising cerium oxide and at least one second oxide of a metal M1 is disclosed as well as a process for manufacturing the material and the use of this material in an exhaust gas cleaning catalyst. In a preferred embodiment the oxygen storage material comprises particles from a Ce/M1 mixed oxide solid solution coated with an oxide of another metal M2. Metal M1 e.g. can be calcium or zirconium while metal M2 most preferably is aluminum.

摘要翻译： 公开了一种包含氧化铈和金属M 1的至少一种第二氧化物的储氧材料，以及用于制造材料的方法以及在废气清洁催化剂中使用该材料。 在优选的实施方案中，储氧材料包含涂覆有另一种金属M 2的氧化物的Ce / M 1混合氧化物固溶体的颗粒。 金属M 1，例如 可以是钙或锆，而金属M 2最优选是铝。

公开(公告)号：US20030118890A1

公开(公告)日：2003-06-26

申请号：US10308491

申请日：2002-12-03

申请人： OMG AG & Co. KG

发明人： Sandra Wittpahl ,  Markus Robert Vogt ,  Karl-Anton Starz ,  Joachim Kohler

IPC分类号： H01M004/88 ,  H01M004/86 ,  B05D005/12 ,  H01M008/10

CPC分类号： H01M8/1004 ,  H01M2300/0082 ,  Y02P70/56

摘要： The present invention relates to a method for the production of a membrane electrode assembly comprising a polymer electrolyte membrane with two opposing membrane surfaces and a cathode and an anode electrode each comprising a catalyst layer and a gas distribution layer. Each catalyst layer is interposed between a membrane surface and the corresponding gas distribution layer. The catalyst layer of the cathode and/or the catalyst layer of the anode comprise at least two sub-layers. According to the present invention at least one of the sub-layers of the cathode electrode and/or the anode electrode is applied directly to the surface of the membrane while the remaining sub-layers are applied to the corresponding gas distribution layers. Finally the assembly of the coated membrane and the coated gas distribution layers is produced.

摘要翻译： 本发明涉及一种制造膜电极组件的方法，该膜电极组件包括具有两个相对的膜表面的聚合物电解质膜和各自包含催化剂层和气体分布层的阴极和阳极电极。 每个催化剂层介于膜表面和相应的气体分配层之间。 阳极的催化剂层和/或阳极的催化剂层包括至少两个子层。 根据本发明，将阴极电极和/或阳极电极的子层中的至少一个直接施加到膜的表面，而将其余子层施加到相应的气体分布层。 最后，制造了涂覆的膜和涂覆的气体分布层的组装。