公开(公告)号：US5238782A

公开(公告)日：1993-08-24

申请号：US484277

申请日：1990-02-26

申请人： Koichi Kawamura ,  Mitsuru Koike

发明人： Koichi Kawamura ,  Mitsuru Koike

IPC分类号： G03F7/031

CPC分类号： G03F7/031 ,  Y10S430/114 ,  Y10S430/121 ,  Y10S430/123

摘要： A photopolymerizable composition comprises at least one addition polymerizable compound having at least one ethylenically unsaturated bond and at least one photopolymerization initiator represented by the following general formula (I): ##STR1## wherein R.sub.1 to R.sub.4 independently represent hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, hydroxyl group, a substituted or unsubstituted alkoxy group, or a substituted or unsubstituted amino group with the proviso that R.sub.1 to R.sub.4 may form a non-metallic ring together with the carbon atoms bonded thereto; R.sub.5 and R.sub.6 each represents hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a heteroaromatic group, an acyl group, cyano group, an alkoxycarbonyl group, carboxyl group or a substituted alkenyl group with the proviso that R.sub.5 and R.sub.6 may form a non-metallic ring together with the carbon atoms bonded thereto; X represents O, S, NH or a nitrogen atom having a substituent; and G.sub.1 and G.sub.2 each represents hydrogen atom, cyano group, a substituted or unsubstituted alkoxycarbonyl group, a substituted or unsubstituted aryloxycarbonyl group, a substituted or unsubstituted acyl group, a substituted or unsubstituted arylcarbonyl group, an alkylthio group, an arylthio group, an alkylsulfonyl group, an arylsulfonyl group or a fluorosulfonyl group with the proviso that G.sub.1 and G.sub.2 cannot simultaneously represent hydrogen atom and that G.sub.1 and G.sub.2 may form a non-metallic ring together with the carbon atoms bonded thereto. This composition provides light-sensitive layer of highly sensitive to light from a variety of light sources.

摘要翻译： 光聚合性组合物包含至少一种具有至少一个烯键式不饱和键的加成聚合化合物和至少一种由以下通式（I）表示的光聚合引发剂：其中R 1至R 4独立地表示氢原子，卤素 原子，取代或未取代的烷基，取代或未取代的芳基，羟基，取代或未取代的烷氧基或取代或未取代的氨基，条件是R 1至R 4可与 与其键合的碳原子; R5和R6各自表示氢原子，取代或未取代的烷基，取代或未取代的芳基，杂芳基，酰基，氰基，烷氧基羰基，羧基或取代的烯基，条件是R5和 R6可以与其键合的碳原子一起形成非金属环; X表示O，S，NH或具有取代基的氮原子; G1，G2各自表示氢原子，氰基，取代或未取代的烷氧基羰基，取代或未取代的芳氧基羰基，取代或未取代的酰基，取代或未取代的芳基羰基，烷硫基，芳硫基，烷基磺酰基 基团，芳基磺酰基或氟磺酰基，条件是G1和G2不能同时表示氢原子，并且G1和G2可以与其键合的碳原子一起形成非金属环。 该组合物提供对来自各种光源的光敏感的光敏层。

公开(公告)号：US4511645A

公开(公告)日：1985-04-16

申请号：US530821

申请日：1983-09-09

申请人： Mitsuru Koike ,  Kesanao Kobayashi ,  Tadao Toyama ,  Hiroshi Misu ,  Koji Tamoto ,  Masayuki Iwasaki

发明人： Mitsuru Koike ,  Kesanao Kobayashi ,  Tadao Toyama ,  Hiroshi Misu ,  Koji Tamoto ,  Masayuki Iwasaki

IPC分类号： G03F7/004 ,  C08F265/04 ,  G03F7/00 ,  G03F7/029 ,  G03F7/032 ,  G03F7/033 ,  G03F7/038 ,  G03C1/94 ,  G03C1/68

CPC分类号： C08F265/04 ,  G03F7/032 ,  G03F7/0295 ,  Y10S430/111 ,  Y10S430/128

摘要： A presensitized printing plate which has a photopolymerizing composition layer provided on at least one side of a support, with the photopolymerizing composition being constituted with (A) a polymer containing in its side chains groups represented by the following general formula (I) and carboxylic groups: ##STR1## (wherein R.sub.1 to R.sub.5 each represents a hydrogen atom, a halogeno group, a carboxyl group, a sulfo group, a nitro group, a cyano group, and amido group, an amino group, or an unsubstituted or a substituted alkyl, aryl, alkoxy, aryloxy, alkylamino, arylamino, alkylsulfonyl or arylsulfonyl group; and Z represents an oxygen atom, a sulfur atom, --NH-- or --NR-- (R=alkyl)), (B) a monomer or an olygomer having at least two polymerizable ethylenically unsaturated double bonds, and (C) a photopolymerization initiator.

摘要翻译： 一种具有光聚合组合物层的预敏印刷版，其中所述光聚合组合物层设置在载体的至少一侧上，所述光聚合组合物由（A）含有由下列通式（I）表示的侧链基团的聚合物和羧基组成 ：其中，R 1〜R 5各自表示氢原子，卤代基，羧基，磺基，硝基，氰基，酰胺基，氨基或未取代的或未取代的 取代的烷基，芳基，烷氧基，芳氧基，烷基氨基，芳基氨基，烷基磺酰基或芳基磺酰基; Z表示氧原子，硫原子，-NH-或-NR-（R =烷基）），（B）单体或 具有至少两个可聚合的烯键式不饱和双键的共聚物，和（C）光聚合引发剂。

公开(公告)号：US5274673A

公开(公告)日：1993-12-28

申请号：US973713

申请日：1992-11-09

申请人： Takeo Kaharu ,  Masato Shimamura ,  Yuzo Kohsaka ,  Shuichi Aihara ,  Kousuke Maezawa ,  Mitsuru Koike

发明人： Takeo Kaharu ,  Masato Shimamura ,  Yuzo Kohsaka ,  Shuichi Aihara ,  Kousuke Maezawa ,  Mitsuru Koike

IPC分类号： H04L25/49 ,  H04L27/10

CPC分类号： H04L25/4904

摘要： In each terminal connected to an optical bus a narrow pulse synchronized with the rise of a pre-synchronizing pulse appended to the head of the one digital signal TXN of Manchester-biphase signals, a narrow pulse synchronized with the rise of each pulse of the other Manchester-biphase digital signal TXO and a narrow pulse occurring every fixed period of time during the duration of each pulse are produced, and these narrow pulses are converted into optical signals, which are provided as an optical pulse train to the optical bus. In each terminal optical pulses received from the optical bus are converted into an electric signal, which is separated into its leading pulse and the subsequent pulses, a synchronizing pulse is produced in synchronization with the leading pulse, the subsequent pulses are each converted into a pulse of a fixed width to regenerate the signal TXO, and the regenerated signal TXO is polarity inverted and then combined with the pre-synchronizing pulse to regenerate the signal TXN.

摘要翻译： 在连接到光总线的每个终端中，与曼彻斯特双相信号的一个数字信号TXN的头部附加的预同步脉冲的上升同步的窄脉冲，与另一个的每个脉冲的上升同步的窄脉冲 产生曼彻斯特双相数字信号TXO和在每个脉冲期间每固定时间段发生的窄脉冲，并且将这些窄脉冲转换成光信号，其作为光脉冲串提供给光总线。 在每个端子中，从光总线接收的光脉冲被转换成电信号，其被分离为其前导脉冲和随后的脉冲，与前导脉冲同步地产生同步脉冲，随后的脉冲被转换为脉冲 固定宽度以再生信号TXO，并且再生信号TXO被极性反转，然后与预同步脉冲组合以再生信号TXN。

公开(公告)号：US5220582A

公开(公告)日：1993-06-15

申请号：US717675

申请日：1991-06-19

申请人： Takeo Kaharu ,  Masato Shimamura ,  Yuzo Kohsaka ,  Shuichi Aihara ,  Kousuke Maezawa ,  Mitsuru Koike

发明人： Takeo Kaharu ,  Masato Shimamura ,  Yuzo Kohsaka ,  Shuichi Aihara ,  Kousuke Maezawa ,  Mitsuru Koike

IPC分类号： H04B10/556 ,  H04B10/07 ,  H04B10/2507 ,  H04B10/29 ,  H04L12/40 ,  H04L25/02 ,  H04L25/49

CPC分类号： H04L25/4904

摘要： In each terminal connected to an optical bus a narrow pulse synchronized with the rise of a pre-synchronizing pulse appended to the head of the one digital signal TXN of Manchester-biphase signals, a narrow pulse synchronized with the rise of each pulse of the other Manchester-biphase digital signal TXO and a narrow pulse occurring every fixed period of time during the duration of each pulse are produced, and these narrow pulses are converted into optical signals, which are provided as an optical pulse train to the optical bus. In each terminal optical pulses received from the optical bus are converted into an electric signal, which is separated into its leading pulse and the subsequent pulses, and the synchronizing pulse is produced in synchronization with the leading pulse and the subsequent pulses are each converted into a pulse of a fixed width to regenerate the signal TXO, and the regenerated signal TXO is polarity inverted and is then combined with the pre-synchronizing pulse to regenerate the signal TXN.

公开(公告)号：US5080999A

公开(公告)日：1992-01-14

申请号：US707190

申请日：1991-05-28

申请人： Masanori Imai ,  Mitsuru Koike ,  Noriaki Watanabe ,  Nobuyuki Kita ,  Tatsuji Higashi

发明人： Masanori Imai ,  Mitsuru Koike ,  Noriaki Watanabe ,  Nobuyuki Kita ,  Tatsuji Higashi

IPC分类号： G03F7/016 ,  G03F7/027 ,  G03F7/033 ,  G03F7/095

CPC分类号： G03F7/0166 ,  G03F7/027 ,  G03F7/033 ,  G03F7/0955

摘要： A light-sensitive composition which comprises, (a) an ethylenically unsaturated addition polymerizable compound, (b) an alkaline water-soluble or swellable, and film-forming polymer, (c) a photopolymerization initiator, (d) a negative working diazo resin, and (e) at least one compound selected from the group consisting of a higher fatty acid and a higher fatty acid amide which are solid at ordinary temperatures.The light-sensitive composition is hardly influenced by oxygen and is suitable for a presensitized plate from which a printing plate is to be prepared.

摘要翻译： 一种感光性组合物，其包含（a）烯属不饱和加成聚合性化合物，（b）碱性水溶性或可溶胀性和成膜性聚合物，（c）光聚合引发剂，（d）负性重氮树脂 ，和（e）至少一种选自常温下为固体的高级脂肪酸和高级脂肪酸酰胺的化合物。 感光性组合物几乎不受氧的影响，适用于要制备印版的预感板。

公开(公告)号：US4950581A

公开(公告)日：1990-08-21

申请号：US215353

申请日：1988-07-05

申请人： Mitsuru Koike ,  Nobuyuki Kita

发明人： Mitsuru Koike ,  Nobuyuki Kita

IPC分类号： C08F2/50 ,  G03F7/029

CPC分类号： G03F7/029 ,  Y10S430/114 ,  Y10S430/116 ,  Y10S430/117 ,  Y10S430/12 ,  Y10S430/121 ,  Y10S430/126

摘要： A photopolymerizable composition is provided containing a polymerizable compound having an ethylenically unsaturated bond, a photopolymerization initiator, and if necessary, a linear organic high molecular weight polymer. The photopolymerization initiator comprises a combination of (a) an organic compound represented by formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4, which may be the same or different, each represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkenyl group a substituted or unsubstituted alkynyl group, or a substituted or unsubstituted heterocyclic group, and at least two of said R.sup.1, R.sup.2, R.sup.3, and R.sup.4 may combine to form a cyclic structure, with the proviso that at least one of R.sup.1, R.sup.2, R.sup.3, and R.sup.4 is an alkyl group, and wherein Z.sym. represents an alkali metal cation or a quaternary ammonium cation, and (b) an organic dye having no counter anion.

摘要翻译： 提供含有具有烯键式不饱和键的可聚合化合物，光聚合引发剂和必要时的线性有机高分子量聚合物的光聚合组合物。 光聚合引发剂包括（a）由式（I）表示的有机化合物：其中R 1，R 2，R 3和R 4可以相同或不同，各自表示取代或未取代的 烷基，取代或未取代的芳基，取代或未取代的烯基，取代或未取代的炔基或取代或未取代的杂环基，并且所述R 1，R 2，R 3和R 4中的至少两个可以结合形成 环状结构，条件是R 1，R 2，R 3和R 4中的至少一个为烷基，并且其中Z（+）表示碱金属阳离子或季铵阳离子，和（b）无 抗衡阴离子

公开(公告)号：US4937161A

公开(公告)日：1990-06-26

申请号：US214938

申请日：1988-07-05

申请人： Nobuyuki Kita ,  Mitsuru Koike

发明人： Nobuyuki Kita ,  Mitsuru Koike

IPC分类号： C08F2/50 ,  G03C5/16 ,  G03F7/029

CPC分类号： C08F2/50 ,  G03F7/029 ,  G03F7/0295 ,  Y10S430/115 ,  Y10S430/117 ,  Y10S430/121

摘要： A photopolymerizable composition containing a polymerizable compound having an ethylenically unsaturated bond, a photopolymerization initiator, and if necessary, a linear organic hibh molecular weight polymer. The photopolymerization initiator comprises a combination of (a) at least one organic boron compound anion salt of an organic cationic dye, andd (b) a compound represented by formula (I): ##STR1## wherein x represents a halogen atom; Y represents --CH.sub.3, --NH.sub.2, --NHR', --N(R').sub.2, or --OR' wherein R' represents an alkyl group, a substituted alkyl group, an aryl group, or a substituted aryl group; and wherein R represents --CX.sub.3, an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group, or a substituted alkenyl group.

摘要翻译： 含有具有烯键式不饱和键的聚合性化合物，光聚合引发剂和必要时的线性有机高分子量聚合物的光聚合性组合物。 光聚合引发剂包括（a）有机阳离子染料的至少一种有机硼化合物阴离子盐和d（b）由式（I）表示的化合物的组合：其中x表示卤素原子; Y表示-CH 3，-NH 2，-NHR'，-N（R'）2或-OR'，其中R'表示烷基，取代的烷基，芳基或取代的芳基; 并且其中R表示-CX3，烷基，取代的烷基，芳基，取代的芳基或取代的烯基。

公开(公告)号：US4833884A

公开(公告)日：1989-05-30

申请号：US113407

申请日：1987-10-26

申请人： Kiyoshi Seko ,  Kazuhiko Soe ,  Mitsuru Koike ,  Yoshitaka Iida

发明人： Kiyoshi Seko ,  Kazuhiko Soe ,  Mitsuru Koike ,  Yoshitaka Iida

IPC分类号： B65B51/10 ,  F15B11/20

CPC分类号： F15B11/20 ,  Y10T83/8864

摘要： A fluid actuator including at least two cylinders connected to a common pressurized-fluid supply mechanism. Actuation units are connected to piston rods of the cylinders, respectively. The piston of one of the cylinders is operated by pressurized fluid, and when the piston is moved back, the pressure in the cylinder is increased to operate the piston of the other cylinder. The actuation units are thus operated with a certain amount of interval of time or in a synchronous mode.

摘要翻译： 流体致动器包括连接到公共加压流体供应机构的至少两个气缸。 驱动单元分别连接到气缸的活塞杆。 其中一个气缸的活塞由加压流体操作，并且当活塞向后移动时，气缸中的压力增加以操作另一气缸的活塞。 致动单元因此以一定的时间间隔或同步模式操作。

公开(公告)号：US4810618A

公开(公告)日：1989-03-07

申请号：US142185

申请日：1988-01-11

申请人： Mitsuru Koike ,  Koichi Kawamura

发明人： Mitsuru Koike ,  Koichi Kawamura

IPC分类号： C08F2/50 ,  G03F7/028 ,  G03F7/029 ,  G03C1/68

CPC分类号： G03F7/0295 ,  C08F2/50 ,  Y10S430/116 ,  Y10S430/12 ,  Y10S430/121 ,  Y10S430/123 ,  Y10S430/127

摘要： A photopolymerizable composition comprises at least one polymerizable compound having at least one ethylenically unsaturated bond therein and at least one photopolymerization initiator and optionally at least one linear organic high molecular weight polymer and characterized in that the photopolymerization initiator comprises a specific combination of two kinds of compounds, for instance, 2,4,6-tris(trichloromethyl)-s-triazine and compound (12) represented by the following formula: ##STR1## The photopolymerizable composition exhibits a high sensitivity to extremely wide range of actinic rays extending from ultraviolet light to visible light and is useful for manufacturing PS plates and photoresist layer for use in making print circuit-boards or the like.

摘要翻译： 可光聚合组合物包含至少一种其中具有至少一个烯属不饱和键的可聚合化合物和至少一种光聚合引发剂和任选的至少一种线性有机高分子量聚合物，其特征在于光聚合引发剂包括两种化合物的特定组合 例如，2,4,6-三（三氯甲基）-s-三嗪和由下式表示的化合物（12）：（12）可光聚合组合物显示出对极宽范围的光化射线延伸的高灵敏度 从紫外光到可见光，并且可用于制造用于制造印刷电路板等的PS板和光致抗蚀剂层。

公开(公告)号：US4687727A

公开(公告)日：1987-08-18

申请号：US774165

申请日：1985-09-09

申请人： Tadao Toyama ,  Kesanao Kobayashi ,  Mitsuru Koike ,  Koji Tamoto

发明人： Tadao Toyama ,  Kesanao Kobayashi ,  Mitsuru Koike ,  Koji Tamoto

IPC分类号： G03F7/004 ,  G03F7/021 ,  G03F7/027 ,  G03F7/033 ,  G03F7/038 ,  G03F7/095 ,  G03C1/60 ,  G03C1/68

CPC分类号： G03F7/033 ,  G03F7/0955

摘要： A light-sensitive planographic printing plate comprising a layer of a photo-polymerizable composition provided on at least one side of a base, wherein said photo-polymerizable composition comprises:(A) a polymer having at least one group represented by the general formula (I) ##STR1## wherein R.sub.1 to R.sub.5 each represent a member selected from the group consisting of a hydrogen atom, a halgen atom, a carboxyl group, a sulfo group, a nitro group, a cyano group, an amido group, an amino group and a substituted or unsubstituted alkyl group, aryl group, alkoxy gruop, aryloxy group, alkylamino group, arylamino group, alkylsulfonyl group and arylsulfonyl group and Z represents an oxygen atom, a sulfur atom, NH or NR, wherein R represents an alkyl group; and a carboxyl group on the side chain;(B) a monomer or oligomer having at least two polymerizable ethylenically unsaturated double bonds;(C) a photo-polymerization initiator, and(D) a diazo resin.

摘要翻译： 一种感光平版印刷版，其包含设置在基材的至少一侧上的可光聚合组合物层，其中所述光聚合性组合物包含：（A）具有至少一个由通式（ I）其中R 1〜R 5各自表示选自氢原子，卤原子，羧基，磺基，硝基，氰基，酰氨基， 氨基和取代或未取代的烷基，芳基，烷氧基，芳氧基，烷基氨基，芳基氨基，烷基磺酰基和芳基磺酰基，Z表示氧原子，硫原子，NH或NR，其中R表示 烷基; 和侧链上的羧基; （B）具有至少两个可聚合的烯属不饱和双键的单体或低聚物; （C）光聚合引发剂，（D）重氮树脂。