公开(公告)号：US4255148A

公开(公告)日：1981-03-10

申请号：US872561

申请日：1978-01-26

申请人： Elmar Reinwald ,  Milan J. Schwuger ,  Heinz Smolka ,  Peter Krings

发明人： Elmar Reinwald ,  Milan J. Schwuger ,  Heinz Smolka ,  Peter Krings

IPC分类号： B01D15/04 ,  C01B39/00 ,  C01B39/02 ,  C11D3/12 ,  C11D11/00 ,  D06F39/10 ,  B08B3/00

CPC分类号： C11D11/0017 ,  C11D3/128 ,  D06F39/10

摘要： The machine washing of solid textiles or dishes is improved when the wash water is passed through a cation exchange agent of the formula:(M.sub.2/n O).sub.x.Me.sub.2 O.sub.3.(SiO.sub.2).sub.y,wherein M is a cation of valence n interchangeable with calcium, Me is a member selected from aluminum and boron, x is a number from 0.7 to 1.5 and y is a number from 0.8 to 6, said agent having a calcium binding power of at least 50 mg. of CaO per gram, said agent being maintained during said washing out of contact with the objects being washed within a filter apparatus. Apparatus for carrying out the process includes means for circulating the wash water through a vessel containing the cation exchange agent in porous solid or in fluidized bed form within a filter means.

摘要翻译： 当洗涤水通过下式的阳离子交换剂（M2 / nO）x.Me2O3。（SiO2）y时，固体纺织品或盘子的洗涤机会得到改善，其中M是与钙可互换的价态的阳离子 Me是选自铝和硼的成员，x是0.7至1.5的数，y是0.8至6的数，所述试剂的钙结合力至少为50mg。 的CaO /克，所述试剂在所述洗涤期间保持与在过滤装置内被清洗的物体接触。 用于进行该方法的装置包括用于使清洗水循环通过多孔固体中的阳离子交换剂的容器或在过滤装置内以流化床形式循环的装置。

公开(公告)号：US4215007A

公开(公告)日：1980-07-29

申请号：US948219

申请日：1978-10-03

申请人： Peter Krings ,  Josef Huppertz ,  Herbert Latka ,  Gerhard Sperling ,  Milan J. Schwuger ,  Heinz Smolka

发明人： Peter Krings ,  Josef Huppertz ,  Herbert Latka ,  Gerhard Sperling ,  Milan J. Schwuger ,  Heinz Smolka

IPC分类号： C11D3/00 ,  C11D3/12 ,  C11D11/00 ,  C11D11/02 ,  C02B1/44

CPC分类号： C11D11/02 ,  C11D3/128 ,  Y10S159/14

摘要： A process for the manufacture of low-phosphorus or phorphorus-free spray dried detergents containing at least one water-soluble inorganic or organic compound exerting a washing or cleansing effect and at least one compound inhibiting alkaline earth metal ion precipitation comprising a finely-dispersed, water-insoluble, bound water-containing silicate compound having a calcium-binding power of at least 50 mg CaO/gm of anhydrous active substance and having the formula, combined water not shown,(M.sub.2 /.sub.n O).sub.x . Me.sub.2 O.sub.3 . (SiO.sub.2).sub.ywhere M is a cation of the valence n, exchangeable with calcium, x is a number of from 0.7 to 1.5, Me is a member selected from aluminum and boron and y is a number of from 0.8 to 6, comprising spraying an aqueous slurry containing at least 50% by weight of the total solids of the final spray dried detergent into a conventional spray drier and simultaneously injecting at the area of the spray cone at least 25% of the total amount of said bound water-containing silicate compound, as a powder.

摘要翻译： 一种制备含有至少一种施用洗涤或清洁效果的水溶性无机或有机化合物的低磷或无磷无喷雾干燥洗涤剂的方法，以及至少一种抑制碱土金属离子沉淀的化合物，其包含微细分散的， 具有钙结合力至少为50mg CaO / gm的无水活性物质且具有下式的组合水（M2 / nO）x的水不溶性结合含水硅酸盐化合物。 Me2O3。 （SiO 2）y，其中M是价数为n的阳离子，可与钙交换，x为0.7至1.5的数，Me为选自铝和硼的成员，y为0.8至6的数量，包括喷涂 含有至少50重量％的最终喷雾干燥洗涤剂的总固体量的常规喷雾干燥器，同时在喷雾锥体区域注入所述结合含水硅酸盐的总量的至少25％ 化合物，作为粉末。

公开(公告)号：US4164430A

公开(公告)日：1979-08-14

申请号：US852029

申请日：1977-11-16

申请人： Elmar Reinwald ,  Heinz Smolka ,  Milan J. Schwuger

发明人： Elmar Reinwald ,  Heinz Smolka ,  Milan J. Schwuger

IPC分类号： B08B3/08 ,  C11D3/00 ,  C11D3/37 ,  C11D11/00 ,  D06F39/10 ,  B08B7/04

CPC分类号： D06F39/10 ,  C11D11/0011 ,  C11D3/3788

摘要： Solid soiled materials are machine washed by withdrawing and recycling the wash liquor in contact with said solid soiled materials through a water-insoluble cation exchange polymer in particulate state having a calcium binding power of at least 2 mVal per gram, said polymer in particulate state being maintained out of contact with said solid soiled materials, for such time that the recycling wash liquor has passed through said polymer at least twice, in the presence of other soluble washing and cleaning compounds, while reversing the direction of flow of said wash liquor through said polymer repeatedly.

摘要翻译： 机械洗涤固体污染的材料，通过将具有至少2mVal /克的钙结合力的颗粒状态的水不溶性阳离子交换聚合物取出并再循环与所述固体污染物接触的洗涤液体，所述颗粒状态的聚合物为 保持与所述固体污染的材料不接触，使得在其它可溶性洗涤和清洁化合物的存在下，再循环洗涤液已经通过所述聚合物至少两次，同时使所述洗涤液的流动方向反转通过所述 聚合物反复。

公开(公告)号：US4755319A

公开(公告)日：1988-07-05

申请号：US437518

申请日：1982-10-29

申请人： Heinz Smolka ,  Milan J. Schwuger

发明人： Heinz Smolka ,  Milan J. Schwuger

IPC分类号： C01B39/00 ,  C01B39/02 ,  C01B39/06 ,  C11D3/00 ,  C11D3/12 ,  C01B33/28 ,  C02F1/42 ,  C11D11/00

CPC分类号： C11D3/128

摘要： A process for the production of solid, pourable, washing or cleaning agents containing surface-active compounds, builders, and calcium binding compounds, said calcium binding compounds consisting of at least one finely-dispersed water-insoluble silicate compound containing at least some combined water and having a calcium binding power of at least 50 mg CaO/gm of anhydrous active substance and the formula on the anhydrous basis:(M.sub.2/n O).sub.x .multidot.Me.sub.2 O.sub.3 .multidot.(SiO.sub.2).sub.ywhere M is a cation of the valence n, exchangeable with calcium, x is a member of from 0.7 to 1.5, Me is a member selected from the group consisting of aluminum and boron, and y is a number form 0.8 to 6, comprising the steps of mixing said silicate compound, while still moist from its production, with at least part of the remaining components of the washing and cleaning agent and converting the entire mixture of components into a pourable product.

摘要翻译： 一种用于生产含有表面活性化合物，助洗剂和钙结合化合物的固体，可倾倒，洗涤或清洁剂的方法，所述钙结合化合物由至少一种细分散的水不溶性硅酸盐化合物组成，所述硅酸盐化合物含有至少一些组合的水 并且具有至少50mg CaO / gm的无水活性物质的钙结合能力和以无水为基准的式：（M2 / nO）xxMe2O3x（SiO2）y其中M是价数为n的阳离子，可与钙交换， x为0.7〜1.5的成员，Me为选自铝和硼的成员，y为数字形式，为0.8〜6，包括以下步骤：将硅酸酯化合物从其生产中仍然湿润， 与洗涤和清洁剂的剩余组分的至少一部分并将整个组分混合物转化成可倾倒的产品。

公开(公告)号：US4330423A

公开(公告)日：1982-05-18

申请号：US813436

申请日：1977-07-07

申请人： Heinz Smolka ,  Milan J. Schwuger

发明人： Heinz Smolka ,  Milan J. Schwuger

IPC分类号： C01B39/00 ,  C01B39/02 ,  C01B39/06 ,  C11D3/00 ,  C11D3/12 ,  C01B33/28 ,  C02F1/42 ,  C11D11/00

CPC分类号： C11D3/128

摘要： A process for the production of solid, pourable, washing or cleaning agents containing surface-active compounds, builders, and calcium binding compounds, said calcium binding compounds consisting of at least one finely-dispersed water-insoluble silicate compound containing at least some combined water and having a calcium binding power of at least 50 mg CaO/gm of anhydrous active substance and the formula on the anhydrous basis(M.sub.2 /n.sup.O)x.Me.sub.2 O.sub.3.(SiO.sub.2).sub.ywhere M is a cation of the valence n, exchangeable with calcium, x is a member of from 0.7 to 1.5, Me is a member selected from the group consisting of aluminum and boron, and y is a number from 0.8 to 6, comprising the steps of mixing said silicate compound, while still moist from its production, with at least part of the remaining components of the washing and cleaning agent and converting the entire mixture of components into a pourable product.

摘要翻译： 一种用于生产含有表面活性化合物，助洗剂和钙结合化合物的固体，可倾倒，洗涤或清洁剂的方法，所述钙结合化合物由至少一种细分散的水不溶性硅酸盐化合物组成，所述硅酸盐化合物含有至少一些组合的水 并且具有至少50mg CaO / gm无水活性物质的钙结合力和无水基础上的式（M2 / nO）x.Me 2 O 3（SiO 2）y，其中M是价数n的阳离子，可与 钙，x为0.7〜1.5的成员，Me为选自铝和硼的成员，y为0.8至6的数，包括以下步骤：将所述硅酸盐化合物从其中 生产，至少部分洗涤和清洁剂的剩余组分，并将整个组分混合物转化成可倾倒的产品。

公开(公告)号：US4179268A

公开(公告)日：1979-12-18

申请号：US852028

申请日：1977-11-16

申请人： Elmar Reinwald ,  Heinz Smolka ,  Milan J. Schwuger ,  Edgar Koppelmann

发明人： Elmar Reinwald ,  Heinz Smolka ,  Milan J. Schwuger ,  Edgar Koppelmann

IPC分类号： B08B3/08 ,  B01D15/04 ,  C11D3/12 ,  C11D11/00 ,  D06F39/10 ,  D06L1/12 ,  B08B3/00 ,  C02B1/00

CPC分类号： C11D3/128 ,  C11D11/0005 ,  D06F39/10 ,  D06L1/12

摘要： An improvement in the machine washing of solid soiled materials comprising withdrawing and recycling the wash liquor in contact with said solid soiled materials through a silicate cation exchange compound having some combined water and a particle size of at least 10.mu. of the formula:(M.sub.2/n O).sub.x.Me.sub.2 O.sub.3.(SiO.sub.2).sub.ywherein M is a cation of valence n exchangeable with calcium, Me is a member selected from aluminum and boron, x is a number from 0.7 to 1.5 and y is a number from 0.8 to 6, said silicate compound having a calcium binding power of at least 50 mg of CaO per gram, said silicate compound being maintained out of contact with said solid soiled materials, for such time that the recycling wash liquor has passed through said silicate compound at least twice, in the presence of other soluble washing and cleaning compounds, while reversing the direction of flow of said wash liquor through said silicate compound repeatedly.

摘要翻译： 固体污染物质的洗涤方法的改进包括通过具有一定组合的水和至少10微米的粒径的硅酸盐阳离子交换化合物来取出和再循环与所述固体污染物接触的洗涤液：（M2 / nO）x.Me 2 O 3（SiO 2）y其中M是可与钙交换的价数n的阳离子，Me是选自铝和硼的成员，x是0.7至1.5的数，y是0.8至6的数， 所述硅酸盐化合物具有每克至少50mg CaO的钙结合力，所述硅酸盐化合物与所述固体污染的材料保持脱离接触，使得再循环洗涤液已经通过所述硅酸盐化合物至少两次， 在其它可溶性洗涤和清洁化合物的存在下，同时反复地将所述洗涤液体的流动方向反转通过所述硅酸盐化合物。

公开(公告)号：US4148603A

公开(公告)日：1979-04-10

申请号：US873381

申请日：1978-01-30

申请人： Milan J. Schwuger ,  Heinz Smolka ,  Manfred Rostek

发明人： Milan J. Schwuger ,  Heinz Smolka ,  Manfred Rostek

IPC分类号： C11D3/00 ,  C11D3/12 ,  B08B3/00

CPC分类号： C11D3/128 ,  C11D3/364

摘要： A method of treating soiled textiles, wherein the soiled textiles are immersed in an aqueous liquor which contains at least two compounds inhibiting alkaline earth metal ion precipitation on said soiled textiles comprising using (1) from 0.2 to 10 gm of anhydrous active substance per liter of at least one finely-dispersed, water-insoluble silicate compound having a calcium-binding power of at least 50 mg CaO/gm of anhydrous active substance and having the formula, combined water not shown(M.sub.2/n O).sub.x . Me.sub.2 O.sub.3 . (SiO.sub.2).sub.ywhere M is a cation of the valence n, exchangeable with calcium, x is a number of from 0.7 to 1.5, Me is aluminum or boron, and y is a number from 0.8 to 6, and (2) from 0.05 to 2gm/l of at least one of certain polyphosphonates; as well as washing compositions containing said at least two compounds.

摘要翻译： 一种处理污染纺织品的方法，其中将污染的纺织品浸入含有至少两种抑制所述污染纺织品上的碱土金属离子沉淀的化合物的水性液体中，其中包括使用（1）0.2至10克无水活性物质/ 至少一种细分散的水不溶性硅酸盐化合物，其钙结合力为至少50mg CaO / gm的无水活性物质，并具有下式，组合水未示出（M2 / nO）x。 Me2O3。 （SiO 2）y其中M是价数为n的阳离子，可与钙交换，x为0.7至1.5的数，Me为铝或硼，y为0.8至6的数，（2）为0.05 至2gm / l的某些多聚膦酸酯中的至少一种; 以及含有所述至少两种化合物的洗涤组合物。

公开(公告)号：US4126574A

公开(公告)日：1978-11-21

申请号：US811964

申请日：1977-06-30

申请人： Elmar Reinwald ,  Milan J. Schwuger ,  Heinz Smolka

发明人： Elmar Reinwald ,  Milan J. Schwuger ,  Heinz Smolka

IPC分类号： B01J39/08 ,  C11D3/12 ,  C01B33/28 ,  C02B1/44 ,  C11D1/38

CPC分类号： B01J39/085 ,  C01B33/28 ,  C11D3/128 ,  C11D3/1286 ,  Y10S516/07

摘要： This invention relates to cation-exchanging, water-insoluble aluminosilicates containing bound water and an ionic surface-active compound resistant to water hardness formers and having, for every mol of Al.sub.2 O.sub.3, from 0.7 to 1.5 mols Cat.sub.2/n O, where Cat is a cation having the valence n, and from 0.8 to 6 mols SiO.sub.2, and being produced by the precipitation of said aluminosilicate in an aqueous solution, wherein said reaction is conducted in the presence of an aqueous solution of said ionic surface-active compound, and optional subsequent crystallization; as well as a process for its preparation and a process for the sequestration of water hardness cations employing said aluminosilicates.

摘要翻译： 本发明涉及含有结合水的阳离子交换的水不溶性硅铝酸盐和对水硬化剂具有抗性的离子表面活性化合物，并且对于每摩尔Al 2 O 3，具有0.7至1.5摩尔的Cat2 / nO，其中Cat是阳离子 具有n价和0.8至6摩尔SiO 2，并且通过在水溶液中沉淀所述铝硅酸盐而制备，其中所述反应在所述离子表面活性化合物的水溶液存在下进行，并且任选地随后 结晶; 以及其制备方法和使用所述铝硅酸盐螯合水硬度阳离子的方法。

公开(公告)号：US4272242A

公开(公告)日：1981-06-09

申请号：US923576

申请日：1978-07-11

申请人： Juergen Plapper ,  Klaus Schumann ,  Milan J. Schwuger ,  Heinz G. Smolka ,  Emanuel Arndt ,  Emil Ruscheinsky ,  Herman Jansen

发明人： Juergen Plapper ,  Klaus Schumann ,  Milan J. Schwuger ,  Heinz G. Smolka ,  Emanuel Arndt ,  Emil Ruscheinsky ,  Herman Jansen

IPC分类号： C14C1/08 ,  C14C3/02 ,  C14C5/00 ,  C14C3/04 ,  C14C3/06

CPC分类号： C14C3/02 ,  C14C1/08 ,  C14C5/00

摘要： In the process of tanning for the production of leather comprising subjecting pickled uncured hides to the action of an aqueous liquor containing(1) chemical tanning or pretanning agents, and(2) auxiliary chemicals to tanning and recovering leather, the improvement consisting essentially of employing a water-insoluble aluminosilicate, containing bound water, of theformula(Cat.sub.2/n O).sub.x.Al.sub.2 O.sub.3.(SiO.sub.2).sub.ywherein Cat represents a cation selected from the group consisting of alkali metals, bivalent metal ions, trivalent metal ions and mixtures thereof, n represents an integer from 1 to 3 of the valence of the cation, x is an integer from 0.5 to 1.8 and y is an integer from 0.8 to 50, said aluminosilicates having an average particle size in the range of 0.1.mu. to 5 mm and a calcium binding power of from 0 to 200 mg CaO/gm of anhydrous active substance measured at 22.degree. C. according to the Calcium Binding Power Test Method set out in the specification, as partial replacement of said chemical tanning or pretanning agents and said auxiliary chemicals to tanning.

摘要翻译： 在制造皮革的鞣制过程中，包括将腌制的未固化的皮革用于含有（1）化学鞣制或预鞣剂的含水液体的作用，和（2）辅助化学品来鞣制和回收皮革，其改进主要包括采用 含有结合水的式（Cat2 / nO）x.Al2O3。（SiO2）y的水不溶性硅铝酸盐，其中Cat代表选自碱金属，二价金属离子，三价金属离子及其混合物的阳离子 ，n表示阳离子价数的1〜3的整数，x表示0.5〜1.8的整数，y表示0.8〜50的整数，所述铝硅酸盐的平均粒径为0.1〜5mm 根据本说明书中列出的钙结合力测试方法，在22℃下测定的0〜200mg CaO / gm无水活性物质的钙结合力作为所述化学品t的部分置换 安宁或预制剂和所述辅助化学品进行鞣制。

公开(公告)号：US4184975A

公开(公告)日：1980-01-22

申请号：US860611

申请日：1977-12-14

申请人： Peter Krings ,  Josef Huppertz ,  Herbert Reuter ,  Dieter Kuhling ,  Milan J. Schwuger ,  Heinz Smolka

发明人： Peter Krings ,  Josef Huppertz ,  Herbert Reuter ,  Dieter Kuhling ,  Milan J. Schwuger ,  Heinz Smolka

IPC分类号： C11D3/12 ,  C01B33/28 ,  C11D3/06 ,  C11D11/00

CPC分类号： C11D3/128

摘要： A pourable agglomerated aluminosilicate builder composition comprising(A) from 20% to 70% by weight of at least one finely-divided, synthetically-produced, water-insoluble aluminosilicate compound containing at least some combined water and having a calcium binding power of at least 50 mg CaO/gm of anhydrous active substance and the formula on the anhydrous basis(M.sub.2/n O).sub.x. Me.sub.2 O.sub.3.(SiO.sub.2).sub.ywhere M is a cation of the valence n, exchangeable with calcium, x is a number from 0.7 to 1.5, Me is aluminum or boron, and y is a number from 0.8 to 6, and(B) from 30% to 80% by weight of at least two water-soluble alkali metal salts containing water of crystallization selected from the group consisting of tripolyphosphates, pyrophosphates, orthophosphates, sulfates, carbonates, metasilicates and borates; as well as the process of production of the same.

摘要翻译： 一种可倾倒的附聚硅铝酸盐助洗剂组合物，其包含（A）20重量％至70重量％的至少一种细碎的合成产生的水不溶性硅铝酸盐化合物，其含有至少一些组合水并且具有至少 50mg CaO / gm无水活性物质和无水基础上的配方（M2 / nO）x。 Me 2 O 3（SiO 2）y其中M是价数为n的阳离子，可与钙交换，x为0.7至1.5的数，Me为铝或硼，y为0.8至6的数，（B） 30重量％至80重量％的至少两种含水结晶的水溶性碱金属盐，其选自三聚磷酸盐，焦磷酸盐，正磷酸盐，硫酸盐，碳酸盐，偏硅酸盐和硼酸盐; 以及生产的过程。