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公开(公告)号:US20070134558A1
公开(公告)日:2007-06-14
申请号:US11637695
申请日:2006-12-13
申请人: Hiroshi Fukunaga , Youshin Yagi , Shuichi Wada , Konji Hara , Kazushige Kohno , Hiroshi Haruna
发明人: Hiroshi Fukunaga , Youshin Yagi , Shuichi Wada , Konji Hara , Kazushige Kohno , Hiroshi Haruna
CPC分类号: H01M4/505 , H01M4/364 , H01M4/366 , H01M10/0525 , H01M10/0567 , H01M10/0569 , H01M10/0585 , Y02T10/7011
摘要: Using a positive electrode active material including spinel type manganese oxide as the main constituent, a novel low cost and high output power flat type nonaqueous secondary cell for HEVs that has increased safety at overcharge, and superior storage properties and cycle life is provided. A flat type nonaqueous secondary cell that has increased safety and is superior in storage and cycle properties even though the cell is a laminate type cell which does not have a blocking mechanism can be obtained by blending the spinel type lithium manganese oxide of the positive electrode and 5 wt % to 40 wt % of layered type lithium manganese oxide, to suppress storage deterioration at a high temperature and to simultaneously achieve safety when overcharged, and further, by adding a Li compound having a structure as shown in Formula (1) structure, to suppress deterioration of a mixed positive electrode active material during a high temperature cycle.
摘要翻译: 使用包括尖晶石型氧化锰作为主要成分的正极活性物质,提供了一种用于HEV的新型低成本和高输出功率平面型非水电解槽,其在过充电时具有增加的安全性,并且具有优异的储存性能和循环寿命。 即使电池是不具有阻挡机构的层压型电池,也可以通过将正极的尖晶石型锂锰氧化物和 5重量%〜40重量%的层状锂锰氧化物,以抑制高温下的储存劣化,同时在过充电时同时达到安全性,进一步通过加入具有式(1)所示结构的Li化合物, 以抑制高温循环中的混合正极活性物质的劣化。