公开(公告)号：US06835772B2

公开(公告)日：2004-12-28

申请号：US10055372

申请日：2002-01-25

申请人： Takashi Kita ,  Hiroyuki Arimoto ,  Osamu Shoji ,  Takayuki Kishimoto ,  Kenji Kawazu ,  Mika Kai

发明人： Takashi Kita ,  Hiroyuki Arimoto ,  Osamu Shoji ,  Takayuki Kishimoto ,  Kenji Kawazu ,  Mika Kai

IPC分类号： C08J300

CPC分类号： C08J3/12 ,  C08J2375/04 ,  C08K5/10 ,  C09D175/04 ,  Y10T428/31551 ,  C08L75/04

摘要： This invention aims to provide a favorable feel coating film having gently soft feel (comfortable feel), a coating composition for forming the coating film, and fine particles of a polymer for incorporation in the coating composition, and concerns with fine particles of lanolin-deposited polyurethane resin obtainable by reacting at least one of polyesters and polyethers with polyisocyanate having at least two isocyanate groups in a poor solvent in the presence of a lanolin derivative; a coating composition comprising (i) at least one binder resin selected from the group consisting of polyester resins and polyether resins, the binder resin having a specific glass transition temperature, a specific number average molecular weight and a specific hydroxyl value, (ii) polyisocyanate having at least two isocyanate groups, (iii) the fine particles of polyurethane resin as described above, and (iv) an organic solvent; and an article coated with the coating composition.

摘要翻译： 本发明的目的在于提供一种柔软的手感（舒适的手感），用于形成涂膜的涂料组合物和用于掺入涂料组合物中的聚合物的微粒，以及关于羊毛脂沉积的细颗粒的感觉涂层 在羊毛脂衍生物的存在下，通过在不良溶剂中使至少一种聚酯和聚醚与具有至少两个异氰酸酯基团的多异氰酸酯反应得到的聚氨酯树脂; 涂料组合物，其包含（i）至少一种选自聚酯树脂和聚醚树脂的粘合剂树脂，具有特定玻璃化转变温度，特定数均分子量和特定羟值的粘合剂树脂，（ii）多异氰酸酯 具有至少两个异氰酸酯基团，（iii）如上所述的聚氨酯树脂的细颗粒，和（iv）有机溶剂; 和涂覆有涂料组合物的制品。

公开(公告)号：US20090048378A1

公开(公告)日：2009-02-19

申请号：US12158199

申请日：2006-12-19

申请人： Kenji Kawazu ,  Kentaro Komabayashi ,  Naoya Yabuuchi ,  Shinnosuke Kawano ,  Hirofumi Yamashita

发明人： Kenji Kawazu ,  Kentaro Komabayashi ,  Naoya Yabuuchi ,  Shinnosuke Kawano ,  Hirofumi Yamashita

IPC分类号： C09D5/02

CPC分类号： C09D5/02 ,  C08L33/08 ,  C08L51/06 ,  C08L75/04 ,  C09D133/02 ,  C09D175/04 ,  C08L2666/02

摘要： It is an object of the present invention to provide a water-based one-pack-type coating composition which can form a coating film having a satisfactory feel of achieving a soft feel and coating film performance simultaneously and further maintains common performance of paint such as excellent design (a matt appearance, etc.), an adhesion property, coating film strength, abrasion resistance, water resistance, oil and grease-contamination resistance. A water-based one-pack-type coating composition of the present invention comprises: an ionomer resin emulsion (A), a polyolefin resin emulsion (B), resin particles (C), and a urethane dispersion (D), wherein a solid content mass ratio (mass ratio as converted into a solid content) of (C)/{(A)+(B)+(D)} is 40/100 to 100/100, a solid content mass ratio of (A)/(B) is 1/3 to 3/1, and a solid content mass ratio of {(A)+(B)}/(D) is 40/60 to 70/30.

摘要翻译： 本发明的目的是提供一种水性单组分型涂料组合物，其可以形成具有令人满意的达到柔软手感和涂膜性能的手感的涂膜，并进一步保持涂料的共同性能，例如 优异的设计（无光泽外观等），粘合性，涂膜强度，耐磨性，耐水性，油和油脂污染性。 本发明的水性单组分涂料组合物包括：离聚物树脂乳液（A），聚烯烃树脂乳液（B），树脂颗粒（C）和氨基甲酸酯分散体（D），其中固体 （C）/ {（A）+（B）+（D）}的含量质量比（转化为固体成分的质量比）为40/100〜100/100，固体成分质量比（A）/ （B）为1/3〜3/1，{（A）+（B）} /（D）的固体成分质量比为40/60〜70/30。

公开(公告)号：US06908951B2

公开(公告)日：2005-06-21

申请号：US10395946

申请日：2003-03-24

申请人： Hiroya Dejima ,  Hiroyuki Kai ,  Kenji Kawazu

发明人： Hiroya Dejima ,  Hiroyuki Kai ,  Kenji Kawazu

IPC分类号： B05D7/24 ,  C08G18/40 ,  C09D175/04 ,  C08L75/04

CPC分类号： C08G18/40 ,  C08G2101/0083 ,  C08G2150/60

摘要： An expandable coating composition, yields a coating film having elasticity, a soft feeling, and strength which are sufficient for an instrument panel of an automobile by simple processes. An expandable coating composition yields an expanded coating film and contains (a) a polyol compound, (b) an isocyanate compound, and (c) water; the (a) polyol compound reacts with a part of the (b) isocyanate compound, thereby yielding polyurethane resin; the remaining (b) isocyanate compound reacts with the (c) water, thereby yielding carbon dioxide; the polyurethane resin has a breaking strength of 5 N/cm2 or greater and less than 200 N/cm2 in a case in which an elongation percentage thereof is 100% or less; and the polyurethane resin has a breaking strength of 5 N/cm2 to 1,500 N/cm2 in a case in which an elongation percentage thereof is more than 100%.

摘要翻译： 可膨胀涂料组合物通过简单的方法产生具有弹性，柔软感和强度的涂膜，其对于汽车的仪表板是足够的。 可膨胀涂料组合物产生膨胀涂膜，并含有（a）多元醇化合物，（b）异氰酸酯化合物和（c）水; （a）多元醇化合物与（b）异氰酸酯化合物的一部分反应，得到聚氨酯树脂; 剩余的（b）异氰酸酯化合物与（c）水反应，从而产生二氧化碳; 在伸长率为100％的情况下，聚氨酯树脂的断裂强度为5N / cm 2以上且小于200N / cm 2以下，或 减; 在其伸长率大于100％的情况下，聚氨酯树脂的断裂强度为5N / cm 2〜1500N / cm 2以下。

公开(公告)号：US5438091A

公开(公告)日：1995-08-01

申请号：US329136

申请日：1994-10-25

申请人： Yoshiharu Saito ,  Masao Sakaizawa ,  Kunio Iwanami ,  Kitsusho Kitano ,  Michihisa Tasaka ,  Kenji Kawazu ,  Shizuo Miyazaki ,  Takao Nomura ,  Takeyoshi Nishio ,  Hisayuki Iwai

发明人： Yoshiharu Saito ,  Masao Sakaizawa ,  Kunio Iwanami ,  Kitsusho Kitano ,  Michihisa Tasaka ,  Kenji Kawazu ,  Shizuo Miyazaki ,  Takao Nomura ,  Takeyoshi Nishio ,  Hisayuki Iwai

IPC分类号： C08K3/00 ,  C08L23/16 ,  C08L53/00

CPC分类号： C08L53/00 ,  C08K3/0033 ,  C08L23/16

摘要： A resin composition having excellent paint coatability containing (a) 50-80 weight % of a multi-stage polymerized propylene-ethylene block copolymer consisting essentially of (i) a propylene homopolymer portion, (ii) a propylene-ethylene random copolymer portion, and (iii) an ethylene homopolymer portion, (b) 20-40 weight % of an ethylene-.alpha.-olefin copolymer elastomer, and (c) 20 weight % or less of an inorganic filler, components in the components (a) and (b), which are soluble in p-xylene at a room temperature, having a number-average molecular weight of 4.times.10.sup.4 or more and a weight-average molecular weight of 20.times.10.sup.4 or more.

摘要翻译： 一种树脂组合物，其具有优异的涂布性，其包含（a）50-80重量％的多阶段聚合丙烯 - 乙烯嵌段共聚物，其基本上由（i）丙烯均聚物部分，（ii）丙烯 - 乙烯无规共聚物部分和 （iii）乙烯均聚物部分，（b）20-40重量％的乙烯-α-烯烃共聚物弹性体，和（c）20重量％或更少的无机填料，组分（a）和（b）中的组分 ），其在室温下可溶于对二甲苯，其数均分子量为4×10 4以上，重均分子量为20×10 4以上。

公开(公告)号：US07351476B2

公开(公告)日：2008-04-01

申请号：US10980185

申请日：2004-11-04

申请人： Kenji Kawazu ,  Mika Kai ,  Hirokazu Yoshida ,  Yasuhiro Nakano

发明人： Kenji Kawazu ,  Mika Kai ,  Hirokazu Yoshida ,  Yasuhiro Nakano

IPC分类号： B32B27/40 ,  C08J3/00 ,  C08K3/20 ,  C08L75/00

CPC分类号： C08G18/62 ,  C09D175/04 ,  Y10T428/31551 ,  C08L2666/20 ,  C08L2666/28

摘要： The present invention aims to give a two package curing type polyurethane coating composition which can form a film having soft, wet and dry feelings simultaneously and which maintains general properties such as designing property, film strength, pot life, resistance to scratching and discoloration, resistance to stains with fats and oils and the like, and to provide a coated article with the coating composition. The two package curing type polyurethane coating composition comprises a resin solution containing an acrylic polyol and a curing agent solution containing a polyisocyanate. The resin solution contains urethane resin beads (A) in the amount of 25 to 50 parts by weight and an organic matting agent (B) in the amount of 3 to 10 parts by weight, and the total of (A) and (B) is at least 30 parts by weight in 100 parts by weight of solid contents of the resin solution. And the equivalent ratio of OH groups/NCO groups of the acrylic polyol and the polyisocyanate is in the range of 4.5:1 to 1.5:1.

摘要翻译： 本发明的目的在于提供一种可以同时形成具有柔软，湿润和干燥感觉的膜的两包装固化型聚氨酯涂料组合物，其保持一般性能，例如设计性能，膜强度，适用期，抗划痕和变色性，耐电阻性 用油脂等进行染色，并提供涂布制品与涂料组合物。 两种包装固化型聚氨酯涂料组合物包含含有丙烯酸多元醇的树脂溶液和含有多异氰酸酯的固化剂溶液。 树脂溶液含有25〜50重量份的聚氨酯树脂珠（A）和3〜10重量份的有机消光剂（B），（A）和（B）的总和 在100重量份的树脂溶液的固体成分中为至少30重量份。 丙烯酸多元醇和多异氰酸酯的OH基/ NCO基团的当量比在4.5:1至1.5:1的范围内。

公开(公告)号：US06410131B1

公开(公告)日：2002-06-25

申请号：US09080291

申请日：1998-05-18

申请人： Kenji Kawazu ,  Sonoko Nishimoto ,  Yukitaka Hasegawa ,  Yasuhiko Ogisu

发明人： Kenji Kawazu ,  Sonoko Nishimoto ,  Yukitaka Hasegawa ,  Yasuhiko Ogisu

IPC分类号： B32B1508

CPC分类号： C08J7/045 ,  B05D5/068 ,  B60R2019/525 ,  C08G18/6216 ,  C09D175/06 ,  C09D175/16 ,  C23C14/205 ,  Y10T428/265 ,  Y10T428/31573 ,  Y10T428/31576 ,  Y10T428/31587 ,  Y10T428/31605 ,  Y10T428/31609

摘要： A flexible lustered product used in automobiles. The flexible lustered product includes a base material made of resin. A base coat layer is formed on at least a portion of a surface of the base material by applying a coating. The base coat layer has a glass transition point that is at least −30° C. and at most 0° C. The base coat layer includes a silane coupling agent having a mercapto group. A metal film layer is applied to at least a portion of a surface of the base coat layer. The metal film layer is anticorrosive and has a thickness that is at least 150 Å and at most 800 Å. The metal film layer is formed by a plurality of metal particles disposed in contact with one another so as to define a grain boundary between adjacent metal particles. A top coat layer is formed on at least a portion of a surface of the metal film layer by applying a coating.

摘要翻译： 用于汽车的灵活光泽产品。 柔性光泽产品包括由树脂制成的基材。 通过施加涂层，在基材的表面的至少一部分上形成底涂层。 底涂层的玻璃化转变点至少为-30℃，最多为0℃。底涂层包括具有巯基的硅烷偶联剂。 金属膜层施加到基底涂层的表面的至少一部分上。 金属薄膜层是防腐蚀的，其厚度至少为150埃至多800埃。 金属膜层由彼此接触设置的多个金属颗粒形成，以便在相邻的金属颗粒之间限定晶界。 通过施加涂层在金属膜层的至少一部分表面上形成面漆层。

公开(公告)号：US5461105A

公开(公告)日：1995-10-24

申请号：US415566

申请日：1995-04-03

申请人： Yoshiharu Saito ,  Masao Sakaizawa ,  Kunio Iwanami ,  Kitsusho Kitano ,  Michihisa Tasaka ,  Kenji Kawazu ,  Shizuo Miyazaki ,  Takao Nomura ,  Takeyoshi Nishio ,  Hisayuki Iwai

发明人： Yoshiharu Saito ,  Masao Sakaizawa ,  Kunio Iwanami ,  Kitsusho Kitano ,  Michihisa Tasaka ,  Kenji Kawazu ,  Shizuo Miyazaki ,  Takao Nomura ,  Takeyoshi Nishio ,  Hisayuki Iwai

IPC分类号： C08K3/00 ,  C08L23/16 ,  C08L53/00

CPC分类号： C08K3/0033 ,  C08L23/16 ,  C08L53/00

摘要： A resin composition having excellent paint coatability containing (a) 50-80 weight % of a multi-stage polymerized propylene-ethylene block copolymer consisting essentially of (i) a propylene homopolymer portion, (ii) a propylene-ethylene random copolymer portion, and (iii) an ethylene homopolymer portion, (b) 20-40 weight % of an ethylene-.alpha.-olefin copolymer elastomer, and (c) 20 weight % or less of an inorganic filler, components in the components (a) and (b), which are soluble in p-xylene at a room temperature, having a number-average molecular weight of 4.times.10.sup.4 or more and a weight-average molecular weight of 20.times.10.sup.4 or more.

公开(公告)号：US07846249B2

公开(公告)日：2010-12-07

申请号：US11886297

申请日：2006-03-14

申请人： Kenji Kawazu ,  Susumu Umemura ,  Hiroyoshi Mori ,  Daisuke Suzuki ,  Minoru Yamamoto

发明人： Kenji Kawazu ,  Susumu Umemura ,  Hiroyoshi Mori ,  Daisuke Suzuki ,  Minoru Yamamoto

IPC分类号： C09D7/12 ,  C09D201/00

CPC分类号： C09D17/001 ,  C01G23/005 ,  C01P2004/20 ,  C01P2004/84 ,  C09C1/36 ,  C09C1/3653 ,  C09C1/3669 ,  C09D5/22 ,  C09D17/007 ,  C09K11/671

摘要： A pigment aqueous-medium dispersion and coating material which have no particle feeling and exhibit a highly excellent silky feeling, the pigment aqueous-medium dispersion is a dispersion of a photoluminescent pigment in an aqueous medium, characterized in that the photoluminescent pigment is flaky titanic acid obtained by treating layered titanate with acid and then reacting an organic basic compound with the treated layered titanate to delaminate, and the flaky titanic acid has an average longer diameter of 5 to 30 μm and an average thickness of 0.5 to 300 nm.

摘要翻译： 颜料含水介质分散体和涂料，其没有颗粒感和表现出极好的丝滑感，颜料水介质分散体是光致发光颜料在水性介质中的分散体，其特征在于，所述光致发光颜料是片状钛酸 通过用酸处理层状钛酸盐，然后使有机碱性化合物与经处理的层状钛酸盐反应而分层，并且片状钛酸的平均长度直径为5〜30μm，平均厚度为0.5〜300nm。

公开(公告)号：US07700676B2

公开(公告)日：2010-04-20

申请号：US12158199

申请日：2006-12-19

申请人： Kenji Kawazu ,  Kentaro Komabayashi ,  Naoya Yabuuchi ,  Shinnosuke Kawano ,  Hirofumi Yamashita

发明人： Kenji Kawazu ,  Kentaro Komabayashi ,  Naoya Yabuuchi ,  Shinnosuke Kawano ,  Hirofumi Yamashita

IPC分类号： C08G18/28 ,  C08K5/06

CPC分类号： C09D5/02 ,  C08L33/08 ,  C08L51/06 ,  C08L75/04 ,  C09D133/02 ,  C09D175/04 ,  C08L2666/02

摘要： It is an object of the present invention to provide a water-based one-pack-type coating composition which can form a coating film having a satisfactory feel of achieving a soft feel and coating film performance simultaneously and further maintains common performance of paint such as excellent design (a matt appearance, etc.), an adhesion property, coating film strength, abrasion resistance, water resistance, oil and grease-contamination resistance. A water-based one-pack-type coating composition of the present invention comprises: an ionomer resin emulsion (A), a polyolefin resin emulsion (B), resin particles (C), and a urethane dispersion (D), wherein a solid content mass ratio (mass ratio as converted into a solid content) of (C)/{(A)+(B)+(D)} is 40/100 to 100/100, a solid content mass ratio of (A)/(B) is 1/3 to 3/1, and a solid content mass ratio of {(A)+(B)}/(D) is 40/60 to 70/30.

摘要翻译： 本发明的目的是提供一种水性单组分型涂料组合物，其可以形成具有令人满意的达到柔软手感和涂膜性能的手感的涂膜，并进一步保持涂料的共同性能，例如 优异的设计（无光泽外观等），粘合性，涂膜强度，耐磨性，耐水性，油和油脂污染性。 本发明的水性单组分涂料组合物包括：离聚物树脂乳液（A），聚烯烃树脂乳液（B），树脂颗粒（C）和氨基甲酸酯分散体（D），其中固体 （C）/ {（A）+（B）+（D）}的含量质量比（转化为固体成分的质量比）为40/100〜100/100，固体成分质量比（A）/ （B）为1/3〜3/1，{（A）+（B）} /（D）的固体成分质量比为40/60〜70/30。

公开(公告)号：US5981652A

公开(公告)日：1999-11-09

申请号：US935206

申请日：1997-09-22

申请人： Kenji Kawazu ,  Hiroshi Iida ,  Ryuichi Asamen

发明人： Kenji Kawazu ,  Hiroshi Iida ,  Ryuichi Asamen

IPC分类号： C08G18/40 ,  C09D175/04 ,  C08K3/10 ,  C08K5/07

CPC分类号： C08G18/4063 ,  C09D175/04

摘要： The present invention provides a one-liquid low temperature hardenable type colored enamel paint and a one-liquid low temperature hardenable type clear paint, which are used for coating of plastic materials and sufficiently harden even by baking at a low temperature and can form a hardened coating film that is excellent in contaminationproofing and acidproofing without damaging flexibility. The colored enamel paint comprises: resin components, which include a polyesterpolyol and an acrylic polyol; a crosslinking agent, which includes a blocked isocyanate as the essential component and may further include a melamine resin; a blocked isocyanate dissociation catalyst, which at least includes a dibutyltin dicarboxylate; and a pigment. The clear paint comprises: a resin component, which includes an acrylic polyol; the crosslinking agent; and the blocked isocyanate dissociation catalyst.

摘要翻译： 本发明提供一种单液低温可硬化型着色搪瓷漆和一液低温可硬化型透明漆，其用于塑料材料的涂覆并且即使通过在低温下烘烤而充分硬化，并且可以形成硬化 涂膜具有优异的防污和防酸性，不会损害柔韧性。 着色搪瓷涂料包括：树脂组分，其包括聚酯多元醇和丙烯酸多元醇; 交联剂，其包含封端异氰酸酯作为必需组分，并且还可以包含三聚氰胺树脂; 封端的异氰酸酯解离催化剂，其至少包括二羧酸二丁基锡; 和颜料。 透明涂料包括：包含丙烯酸多元醇的树脂组分; 交联剂; 和封端的异氰酸酯解离催化剂。