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1.发明授权
公开(公告)号：US4915899A
公开(公告)日：1990-04-10
申请号：US299335
申请日：1989-01-23
CPC分类号： C04B41/009 , C04B41/5127 , C04B41/88 , H01L21/4867 , C04B2111/00844 , H05K1/0306 , H05K1/092 , H05K3/4629 , Y10T428/12056
摘要： The invention comprises a process for co-sintering of conductors of copper or copper-based alloy and a ceramic substrate, the substrate being produced from a ceramic powder of cordierite type, having a sintering temperature of lower than 950.degree. C.The process comprises the following steps:(a) shaping of the ceramic substrate from a powder of cordierite type,(b) deposit of copper on the ceramic substrate, and(c) co-sintering heat treatment, during which the organic compounds are removed, the copper is regenerated in a reducing atmosphere, and co-sintering of the conductors and the substrate is carried out in a flow of moist inert gas with a plateau at a temperature of between 1065.degree. and 1080.degree. C.The process according to the invention makes it possible to produce substrates of cordierite with internal and external conductors.
摘要翻译： 本发明包括一种用于共烧烧铜或铜基合金和陶瓷基体的导体的方法，该基底由堇青石型陶瓷粉末制成，烧结温度低于950℃。该方法包括 以下步骤：（a）从堇青石型粉末中形成陶瓷衬底，（b）在陶瓷衬底上沉积铜，和（c）共烧结热处理，其中除去有机化合物，铜是 在还原气氛中再生，并且导体和衬底的共烧结在具有1065和1080℃之间的平台的湿惰性气体流中进行。根据本发明的方法使得可能 以生产具有内部和外部导体的堇青石衬底。
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2.发明授权Process for the isomerisation of straight hydrocarbons containing at least 7 carbon atoms using catalysts with a base of molybdenum oxycarbide 失效使用具有碳氧化钼基的催化剂异构化含有至少7个碳原子的直链烃的方法
公开(公告)号：US5576466A
公开(公告)日：1996-11-19
申请号：US337368
申请日：1994-11-08
申请人： Marc J. Ledoux , Jean-Louis Guille , Cuong P. Huu , Edd Blekkan , Eric Peschiera
发明人： Marc J. Ledoux , Jean-Louis Guille , Cuong P. Huu , Edd Blekkan , Eric Peschiera
CPC分类号： C07C5/2206 , B01J27/22 , C07C5/277 , C07C2523/28 , C07C2527/20
摘要： A process for isomerizing straight chain hydrocarbons having at least seven carbon atoms by forming a reaction mixture including at least one of the straight chain hydrocarbons and hydrogen and passing the reaction mixture over a catalyst including a molybdenum compound, at least the surface of which is formed of molybdenum carbide partially oxidized in the form of at least one oxycarbide.
摘要翻译： 通过形成包括直链烃和氢中的至少一种的反应混合物并使反应混合物通过包含至少其表面形成的钼化合物的催化剂，使具有至少7个碳原子的直链烃异构化的方法 的碳化钼以至少一种碳氧化物的形式部分氧化。
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公开(公告)号：US5391524A
公开(公告)日：1995-02-21
申请号：US32858
申请日：1993-01-07
CPC分类号： B01D53/945 , B01J27/22 , C01B31/30 , C01B31/301 , C01B31/303 , C01B31/34 , C01P2004/50 , C01P2006/12 , C01P2006/80 , Y02T10/22
摘要： A method of producing heavy metal carbides of high specific surface area characterised in that a compound in the gazeous state of said heavy metal is caused to react with reactive carbon having a specific surface area at least equal to 200 m.sup.2.g.sup.-1 at a temperature comprised between 900.degree. and 1400.degree. C., and thus obtained carbides.
摘要翻译： 一种制造高比表面积的重金属碳化物的方法，其特征在于使所述重金属的眩晕状态的化合物与比表面积至少等于200m 2·g -1的反应性碳在温度 在900〜1400℃之间，由此得到碳化物。
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4.发明授权
公开(公告)号：US4914070A
公开(公告)日：1990-04-03
申请号：US254149
申请日：1988-10-06
IPC分类号： B01D53/86 , B01D53/94 , B01J27/224 , C01B31/36 , C10G49/02
CPC分类号： B01D53/945 , B01J27/224 , C01B31/36 , C10G49/02 , C01P2002/54 , C01P2006/12 , C01P2006/60 , Y02C20/20 , Y02T10/22
摘要： The invention is directed to a process for the production of fine grains of silicon carbide which are formed by an agglomerate of submicronic grains having a specific surface area that is at least 100 m.sup.2 .multidot.g.sup.-1, which are intended in particular to serve as a carrier for catalysts for petrochemistry, and for catalytic reactions at elevated temperature which can attain 1000.degree. C., the process comprising reacting vapors of silicon monoxide SiO on carbon, being characterized by: generating vapors of SiO in a first reaction zone by heating a mixture SiO.sub.2 +Si at a temperature of between 1100.degree. and 1400.degree. C., under a pressure of between 0.1 and 1.5 hPa; and, in a second reaction zone, contacting the SiO vapors with reactive carbon in the divided state with a specific surface area that is at least equal to 200 m.sup.2 .multidot.g.sup.-1 at a temperature of between 1100.degree. and 1400.degree. C. Preferably, the reactive carbon is doped by an addition of from 1 to 10% by weight of a metallic element selected from uranium, cerium, titanium, zirconium, hafnium and lanthanides.
摘要翻译： 本发明涉及一种用于生产碳化硅微细颗粒的方法，该方法由具有至少100m 2×g -1的比表面积的亚微米颗粒的聚集体形成，特别是用作载体 用于石油化学的催化剂，以及在可以达到1000℃的升高的温度下进行催化反应，该方法包括使一氧化碳SiO的蒸汽反应在碳上，其特征在于：通过加热混合物SiO 2 +产生第一反应区中的SiO的蒸汽， Si在1100至1400℃的温度下，在0.1至1.5hPa的压力下; 并且在第二反应区中，使分解状态的SiO蒸气与至少等于200m 2×g-1的比表面积在1100〜1400℃的温度下接触。优选地，反应性 通过加入1至10重量％的选自铀，铈，钛，锆，铪和镧系元素的金属元素来掺杂碳。
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5.发明授权Preparation of a catalyst from metal oxides by reduction and partial carburization by reaction gases 失效通过反应气体还原和部分渗碳从金属氧化物制备催化剂
公开(公告)号：US5468370A
公开(公告)日：1995-11-21
申请号：US162293
申请日：1993-12-07
CPC分类号： B01J37/024 , B01J23/28 , B01J27/22 , B01J37/18 , C10G35/06
摘要： A catalyst for chemical and petrochemical reactions and a process for its production. The catalyst comprises an oxide of one of the transition metals, rare earth elements, or actinide elements, e.g., molybdenum, having on its surface carbides and oxycarbides, the core being the metal or the metal oxide. In the process for catalyst production, the reaction gas mixture containing carbon products is passed onto the oxide, leading to a progressive carburization of the surface of the oxide and to a progressive increase in the efficiency of the catalyst.
摘要翻译： 化学和石油化学反应的催化剂及其生产工艺。 催化剂包括过渡金属，稀土元素或锕系元素之一的氧化物，例如钼，其表面上具有碳化物和碳氧化物，核是金属或金属氧化物。 在催化剂生产过程中，含有碳产物的反应气体混合物通过氧化物，导致氧化物表面逐渐渗碳，催化剂效率逐渐增加。
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公开(公告)号：US5308597A
公开(公告)日：1994-05-03
申请号：US613627
申请日：1990-11-27
IPC分类号： B01D53/86 , B01D53/94 , B01J27/22 , C01B31/00 , C01B31/30 , C01B31/34 , C07B61/00 , C07C5/27 , C07C5/31 , C07C5/367 , C07C5/387 , C07C9/14 , C07C9/16 , C07C15/04 , C10G11/02 , C10G35/06
CPC分类号： B01D53/945 , B01J27/22 , C01B31/30 , C01B31/301 , C01B31/303 , C01B31/34 , C01P2004/50 , C01P2004/80 , C01P2006/12 , C01P2006/80 , Y02T10/22
摘要： A method of producing heavy metal carbides of high specific surface area characterized in that a compound in the gazeous state of said heavy metal is caused to react with reactive carbon having a specific surface area at least equal to 200 m.sup.2. g.sup.-1 at a temperature comprised between 900.degree. and 1400.degree. C., and thus obtained carbides.
摘要翻译： PCT No.PCT / FR90 / 00204 Sec。 371日期1990年11月27日第 102（e）日期1990年11月27日PCT 1990年3月26日PCT公布。 WO90 / 11251 PCT出版物 日本1990年10月4日。一种制造高比表面积的重金属碳化物的方法，其特征在于使所述重金属的眩晕状态的化合物与比表面积至少等于200m 2的反应性碳反应 。 g-1，在900〜1400℃的温度下，由此得到碳化物。
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7.发明授权
公开(公告)号：US5139987A
公开(公告)日：1992-08-18
申请号：US754927
申请日：1991-09-04
摘要： Process for activating carbides of heavy metals with a large specific surface with a view to their use as a catalyst for chemical or petrochemical reactions consisting of treating the said carbides by managed oxidation under an oxidizing gas stream at a temperature between 250.degree. and 450.degree. C., maintaining the temperature for at least 3 hours and then cooling to ambient temperature, still under said oxidizing stream.
摘要翻译： 为了激活具有大比表面积的重金属碳化物的方法，考虑到它们用作化学或石油化学反应的催化剂的用途，其包括在氧化气流下在250-450℃的温度下通过管理氧化处理所述碳化物 ，保持温度至少3小时，然后冷却至环境温度，仍然在所述氧化流下。
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