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公开(公告)号：US4282241A
公开(公告)日：1981-08-04
申请号：US115720
申请日：1980-01-28
IPC分类号： A01N37/32 , A01N41/06 , A01N41/08 , A01N43/40 , B27K3/34 , C07D209/48 , C07D213/76
CPC分类号： C07D209/48 , A01N37/32 , A01N41/06 , A01N41/08 , A01N43/40 , B27K3/343 , C07D213/76
摘要： The invention provides novel fluoro-imides/amides of the formula: ##STR1## in which at least two of X.sub.1, X.sub.2, X.sub.3 and X.sub.4 are fluorine and any of X.sub.1, X.sub.2, X.sub.3 and X.sub.4 which is not fluorine, is chlorine, and A is selected from:(a) ##STR2## in which R.sub.1 is hydrogen or a halogen atom, preferably chlorine,Z is CH or a nitrogen atom,n is 0 or 1, andR is an alkyl group having 1-6 carbon atoms, preferably methyl, or a halogen atom, preferably chlorine;(b) ##STR3## in which Z, n and R have the above-stated meanings: (c) ##STR4## and (d) ##STR5## and a process for preparing said compounds. Said compounds have valuable fungicidal and miticidal activity.
摘要翻译： 本发明提供新颖的下式的氟 - 酰亚胺/酰胺：其中X 1，X 2，X 3和X 4中的至少两个是氟，并且不是氟的X1，X2，X3和X4中的任何一个是氯， A选自：（a）其中R 1是氢或卤素原子，优选氯，Z是CH或氮原子，n是0或1，R是具有1-6个碳原子的烷基的
，优选甲基或卤素原子，优选氯; （b）其中Z，n和R具有上述含义的 ：（c） 和（d） 及其制备方法。 所述化合物具有有价值的杀真菌和杀螨活性。 -
公开(公告)号：US4219558A
公开(公告)日：1980-08-26
申请号：US967508
申请日：1978-12-07
IPC分类号： B27K3/34 , C07D209/48 , C07D213/76 , C07D213/75 , A01N9/12
CPC分类号： C07D209/48 , C07D213/76 , B27K3/343
摘要： The invention provides novel fluoro-imides/amides of the formula: ##STR1## in which at least two of X.sub.1, X.sub.2, X.sub.3 and X.sub.4 are fluorine and any of X.sub.1, X.sub.2, X.sub.3 and X.sub.4 which is not fluorine, is chlorine, and A is selected from: ##STR2## in which R.sub.1 is hydrogen or a halogen atom, preferably chlorine,Z is CH or a nitrogen atom,n is 0 or 1, andR is an alkyl group having 1-6 carbon atoms, preferably methyl, or a halogen atom, preferably chlorine; ##STR3## in which Z, n and R have the above-stated meanings: ##STR4## and a process for preparing said compounds. Said compounds have valuable fungicidal and miticidal activity.
摘要翻译： 本发明提供新颖的下式的氟 - 酰亚胺/酰胺：其中X 1，X 2，X 3和X 4中的至少两个是氟，并且不是氟的X1，X2，X3和X4中的任何一个是氯， A选自：其中R 1是氢或卤素原子，优选氯，Z是CH或氮原子，n是0或1，R是具有1-6个碳原子的烷基的（a） ，优选甲基或卤素原子，优选氯; （b）其中Z，n和R具有上述含义：图像（c）和图像（d）及其制备方法。 所述化合物具有有价值的杀真菌和杀螨活性。
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公开(公告)号：US4138584A
公开(公告)日：1979-02-06
申请号：US799587
申请日：1977-05-23
IPC分类号： C07C69/65 , B01J27/00 , B01J27/08 , C07B61/00 , C07C20060101 , C07C67/00 , C07C67/30 , C07C69/74 , C07C69/743 , C07C69/747 , C07C69/753 , C07D307/28 , C07D307/33
CPC分类号： C07C2101/02
摘要： A three-step process for the production of chrysanthemic acid esters and their homologues of the formula: ##STR1## in which R.sub.1 and R.sub.2 are hydrogen or C.sub.1 -C.sub.6 alkyl,R.sub.3 and R.sub.4 are C.sub.1 -C.sub.6 alkyl or halogen or, together with the C atom to which they are attached, form a cycloalkyl group, andR.sub.5 is C.sub.1 -C.sub.6 alkyl,Which comprises:(1) decarboxylating a lactone of the formula: ##STR2## (2) treating the resulting decarboxylated lactone to effect ring cleavage, halogenation and esterification to form an ester of the formula: ##STR3## in which X is Cl, Br or I, and (3) TREATING THE ESTER X with a base to effect internal condensation whereby the desired product of formula I is obtained.The esters I are valuable intermediates for the preparation of synthetic pyrethroids having insecticidal activity.
摘要翻译： 用于生产菊酸酯及其同系物的三步法，其具有下式：其中R 1和R 2是氢或C 1 -C 6烷基，R 3和R 4是C 1 -C 6烷基或卤素，或者与 它们所连接的C原子形成环烷基，R 5是C 1 -C 6烷基，其包括：
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公开(公告)号：US4148901A
公开(公告)日：1979-04-10
申请号：US742592
申请日：1976-11-17
IPC分类号： A01N43/40 , A01N37/32 , A01N41/06 , A01N43/54 , A01P3/00 , B27K3/38 , C07C67/00 , C07C313/00 , C07C313/36 , C07D209/48 , C07D213/76 , A01N9/16 , A01N9/22 , C07C143/74 , C07D213/02
CPC分类号： C07D209/48 , C07D213/76 , B27K3/343
摘要： The invention provides novel fluoro-imides/amides of the formula: ##STR1## IN WHICH AT LEAST TWO OF X.sub.1, X.sub.2, X.sub.3 and X.sub.4 are fluorine and any of X.sub.1, X.sub.2, X.sub.3 and X.sub.4 which is not fluorine, is chlorine, and A is selected from:(a) ##STR2## IN WHICH R.sub.1 is hydrogen or a halogen atom, preferably chlorine, Z is CH or a nitrogen atom,N is 0 or 1, andR is an alkyl group having 1-6 carbon atoms, preferably methyl, or a halogen atom, preferably chlorine;(b) ##STR3## IN WHICH Z, n and R have the above-stated meanings: (C) ##STR4## (d) ##STR5## and a process for preparing said compounds. Said compounds have valuable fungicidal and miticidal activity.
摘要翻译： 本发明提供新型的下式的氟 - 酰亚胺/酰胺：其中X1，X2，X3和X4的至少两个是氟，并且不是氟的X1，X2，X3和X4中的任何一个是氯， A选自：
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公开(公告)号：US4229353A
公开(公告)日：1980-10-21
申请号：US26746
申请日：1979-04-03
IPC分类号： A01N43/08 , C07C17/00 , C07C69/743 , C07C69/747 , C07D303/08 , C07D307/30 , C07D307/32 , C07D307/33
CPC分类号： C07D307/33 , C07C17/358 , C07C17/363 , C07D303/08
摘要： (2,2-Disubstituted vinyl)-.gamma.-butyrolactones of the formula: ##STR1## in which R.sub.1 and R.sub.2 are hydrogen or C.sub.1 -C.sub.6 alkyl, preferably methyl,R.sub.3 and R.sub.4 are hydrogen, C.sub.1 -C.sub.6 alkyl, preferably methyl, or halogen, or, together with the carbon atom to which they are attached, form a cycloalkyl group, andR.sub.5 is C.sub.1 -C.sub.6 alkyl,are prepared by condensing an epoxide of the formula: ##STR2## with a malonic acid ester of the formula: ##STR3## in a basic medium. The butyrolactones of formula I are valuable intermediates for the synthesis of synthetic pyrethroids having insecticidal activity.
摘要翻译： 其中R 1和R 2是氢或C 1 -C 6烷基，优选甲基，R 3和R 4是氢，C 1 -C 6烷基，优选甲基的式（II 2 - 二取代的乙烯基）-γ-丁内酯， 或卤素，或者与它们连接的碳原子一起形成环烷基，并且R 5是C 1 -C 6烷基，是通过将下式的环氧化物与下式的丙二酸酯缩合制备的： 公式：
在基本介质中。 式I的丁内酯是合成具有杀虫活性的合成拟除虫菊酯的有价值的中间体。
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