公开(公告)号：US3951858A

公开(公告)日：1976-04-20

申请号：US431703

申请日：1974-01-08

申请人： Hannes Schick ,  Peter Hennenberger ,  Gerhard Staiger ,  Heinz Mueller-Tamm

发明人： Hannes Schick ,  Peter Hennenberger ,  Gerhard Staiger ,  Heinz Mueller-Tamm

IPC分类号： C08F4/64 ,  C08F10/00 ,  C08F110/04 ,  C08F110/06 ,  C08F110/08 ,  C08F110/14

CPC分类号： C08F10/00 ,  Y10S526/906

摘要： A process for the manufacture of a modified titanium component for catalysts of the Ziegler/Natta type by milling a mixture of a titanium compound of the formula TiCl.sub.3 .13AlCl.sub.3 and an organic electron donor containing phosphorus and/or nitrogen atoms. The characterizing feature is that the mixture is first milled wet in a liquid inert hydrocarbon medium under specific conditions, then separated from the hydrocarbon medium and finally milled dry under specific conditions. Such modified titanium components give catalysts which provide particularly well reproducible results in the polymerization of .alpha.-olefins.

摘要翻译： 通过研磨式TiCl 3·13AlCl 3的钛化合物和含有磷和/或氮原子的有机电子给体的混合物制备用于齐格勒/纳塔型催化剂的改性钛组分的方法。 其特征是混合物在特定条件下首先在液体惰性烃介质中湿磨，然后与烃介质分离，最后在特定条件下干燥。 这种改性的钛组分产生了在α-烯烃的聚合中提供特别好的可重复结果的催化剂。

公开(公告)号：US3937691A

公开(公告)日：1976-02-10

申请号：US365218

申请日：1973-05-30

申请人： Gerhard Staiger ,  Klaus Bronstert ,  Hannes Schick ,  Peter Hennenberger ,  Heinz Mueller-Tamm

发明人： Gerhard Staiger ,  Klaus Bronstert ,  Hannes Schick ,  Peter Hennenberger ,  Heinz Mueller-Tamm

IPC分类号： C08F4/00 ,  C08F4/60 ,  C08F10/00 ,  C08F4/66 ,  C08F10/06

CPC分类号： C08F10/00 ,  Y10S526/906

摘要： A process for the manufacture of poly(.alpha.-olefins) by polymerization of .alpha.-olefins using a catalyst system comprising (1) a titanium-containing component of (1.1) a substance of the formula TiCl.sub.3 . 1/3 AlCl.sub.3 and (1.2) an organic electron donor containing phosphorus atoms and/or nitrogen atoms, ground together with said substance (1.1), and (2) an aluminum-containing component of a substance of formula Al(C.sub.n H.sub.2 ..sub.n.sub.+1).sub.3 or Al(C.sub.n H.sub.2..sub.n.sub.+1).sub.2 Cl, where n is an integer of from 2 to 6. The characteristic feature is that the catalyst system used is one in which the component (1.1) has been ground with component (1.2) without the use of auxiliaries or additives in a vibratory ball mill using specific steel balls and a specific grinding acceleration over a specific period of time at a temperature which is just below that at which the particles in the ground material begin to agglomerate. The advantage of this process is that the efficiency of the catalyst system is very high and/or poly(.alpha.-olefins) are obtained which have a particularly large fraction which is insoluble in boiling n-heptane.