公开(公告)号：US20070099082A1

公开(公告)日：2007-05-03

申请号：US11546336

申请日：2006-10-12

Applicant: Kojiro Ito ,  Shinichiro Ito ,  Hajime Seri ,  Shinichi Yuasa ,  Munehisa Ikoma

Inventor： Kojiro Ito ,  Shinichiro Ito ,  Hajime Seri ,  Shinichi Yuasa ,  Munehisa Ikoma

IPC: H01M4/58

CPC classification number: C01B3/0078 ,  C01B3/0057 ,  H01M4/383 ,  H01M2004/021 ,  Y02E60/327 ,  Y10S420/90 ,  Y10T29/49108

Abstract: A method of manufacturing a hydrogen-absorption alloy electrode which comprises particles of a hydrogen-absorption alloy that comprises a rare earth element, Ni, Co and Al. The method comprises subjecting the hydrogen-absorption alloy particles to an alkaline treatment in a 10 to 50 weight % NaOH solution at 60 to 140 ° C. for 0.5 to 5 hours such that on the surface of the particles (amount of Al on surface/amount of Al in alloy)

Abstract translation: 一种制造氢吸收合金电极的方法，其包括含有稀土元素Ni，Co和Al的吸氢合金颗粒。 该方法包括使氢吸收合金颗粒在10至50重量％的NaOH溶液中在60至140℃下进行碱处理0.5至5小时，使得在颗粒表面上的Al（表面/ 合金中的Al的量）（表面上的Co的量/合金中的Co的量）。

公开(公告)号：US5753054A

公开(公告)日：1998-05-19

申请号：US634008

申请日：1996-04-17

Applicant: Yoichiro Tsuji ,  Osamu Yamamoto ,  Yasuharu Yamamura ,  Hajime Seri ,  Yoshinori Toyoguchi

Inventor： Yoichiro Tsuji ,  Osamu Yamamoto ,  Yasuharu Yamamura ,  Hajime Seri ,  Yoshinori Toyoguchi

IPC: H01M4/38 ,  C22C30/00

CPC classification number: H01M4/383 ,  Y10S420/90

Abstract: Addition of Mo to a Zr--Mn--V--Cr--Co--Ni, a Zr--Mn--Cr--Co--Ni hydrogen storage alloy, or those including Ti as substitution for Zr improves high-rate discharge characteristics of the hydrogen storage alloy at low temperatures. The hydrogen storage alloy is of the general formula ZrMn.sub.a V.sub.b Mo.sub.c Cr.sub.d Co.sub.e Ni.sub.f, wherein 0.4.ltoreq.a.ltoreq.0.8, 0.ltoreq.b

Abstract translation: 将Mo添加到Zr-Mn-V-Cr-Co-Ni，Zr-Mn-Cr-Co-Ni储氢合金或包含Ti作为取代Zr的那些中，提高了储氢合金的高倍率放电特性 在低温下。 储氢合金是通式为ZrMnaVbMocCrdCoeNif，其中0.4

公开(公告)号：US5541018A

公开(公告)日：1996-07-30

申请号：US384809

申请日：1995-02-06

Applicant: Yasuharu Yamamura ,  Hajime Seri ,  Yoichiro Tsuji ,  Tsutomu Iwaki

Inventor： Yasuharu Yamamura ,  Hajime Seri ,  Yoichiro Tsuji ,  Tsutomu Iwaki

IPC: H01M4/38

CPC classification number: H01M4/383 ,  Y10S420/90

Abstract: The present invention provides a hydrogen storing alloy electrode having a large discharging capacity and a long lifetime at a high temperature. The electrode is also excellent in discharging characteristics in the early charging and discharging cycles. In one aspect of the present invention, the hydrogen storing alloy electrode is made of a hydrogen storing alloy represented by the general formula ZrMn.sub.m V.sub.x X.sub.y Ni.sub.z or a hydride thereof, wherein X is Al, Zn or W; m, x, y, and z are respectively mole ratio of Mn, V, X, and Ni to Zr: 0.4.ltoreq.m.ltoreq.0.8, 0.1.ltoreq.x.ltoreq.0.3, 1.0.ltoreq.z.ltoreq.1.5, and 2.0.ltoreq.m+x+y+z.ltoreq.2.4; when X is Al or Zn, 0

Abstract translation: 本发明提供一种放电容量大，寿命长的储氢合金电极。 该电极在早期充放电循环中的放电特性也优异。 在本发明的一个方面中，储氢合金电极由通式为ZrMnmVxXyNiz或其氢化物表示的储氢合金制成，其中X为Al，Zn或W; m，x，y和z分别是Mn，V，X和Ni与Zr的摩尔比：0.4≤0.08,0.1≤x≤0.3,0.0≤z /=1.5和2.0

公开(公告)号：US5532076A

公开(公告)日：1996-07-02

申请号：US219697

申请日：1994-03-29

Applicant: Yasuharu Yamamura ,  Hajime Seri ,  Yoichiro Tsuji ,  Naoko Owada ,  Tsutomu Iwaki

Inventor： Yasuharu Yamamura ,  Hajime Seri ,  Yoichiro Tsuji ,  Naoko Owada ,  Tsutomu Iwaki

IPC: H01M4/38

CPC classification number: H01M4/383 ,  Y10S420/90

Abstract: A hydrogen storage alloy preferably used for electrodes in alkaline rechargeable battery is of the general formula: Zr.sub.1.2-a Ti.sub.a Mn.sub.v Al.sub.w Ni.sub.x M.sub.y Cr.sub.z wherein M represents at least one element selected from the group consisting of Si, Zn, Sn, Fe, Mo, Cu and Co; and wherein 0.1.ltoreq.a

Abstract translation: 优选用于碱性可再充电电池中的电极的储氢合金具有以下通式：Zr1.2-aTiaMnvAlwNixMyCrz其中M表示选自Si，Zn，Sn，Fe，Mo，Cu和Co中的至少一种元素; 并且其中0.1≤n≤1.2,0.4≤v≤1.2,0≤w≤0.3,0.8≤x≤1.0,0≤y≤0.2,0.0≤x≤0.2,0≤x≤0.6,0.0≤y≤0.0,0.0,0.0,0.0=0.0 /=z

公开(公告)号：US07943255B2

公开(公告)日：2011-05-17

申请号：US11546336

申请日：2006-10-12

Applicant: Kojiro Ito ,  Shinichiro Ito ,  Hajime Seri ,  Shinichi Yuasa ,  Munehisa Ikoma

Inventor： Kojiro Ito ,  Shinichiro Ito ,  Hajime Seri ,  Shinichi Yuasa ,  Munehisa Ikoma

IPC: H01M4/38 ,  H01M4/58 ,  H01M4/26 ,  B22F1/00

CPC classification number: C01B3/0078 ,  C01B3/0057 ,  H01M4/383 ,  H01M2004/021 ,  Y02E60/327 ,  Y10S420/90 ,  Y10T29/49108

Abstract: A method of manufacturing a hydrogen-absorption alloy electrode which comprises particles of a hydrogen-absorption alloy that comprises a rare earth element, Ni, Co and Al. The method comprises subjecting the hydrogen-absorption alloy particles to an alkaline treatment in a 10 to 50 weight % NaOH solution at 60 to 140° C. for 0.5 to 5 hours such that on the surface of the particles (amount of Al on surface/amount of Al in alloy)

Abstract translation: 一种制造氢吸收合金电极的方法，其包括含有稀土元素Ni，Co和Al的吸氢合金颗粒。 该方法包括使氢吸收合金颗粒在10至50重量％的NaOH溶液中在60至140℃下进行碱处理0.5至5小时，使得在颗粒表面上的Al（表面/ 合金中的Al的量）（表面上的Co的量/合金中的Co的量）。

公开(公告)号：US20050026032A1

公开(公告)日：2005-02-03

申请号：US10930790

申请日：2004-09-01

Applicant: Nobuyasu Morishita ,  Shinichiro Ito ,  Hajime Seri

Inventor： Nobuyasu Morishita ,  Shinichiro Ito ,  Hajime Seri

IPC: H01M10/30 ,  H01M4/24 ,  H01M4/38 ,  H01M10/34 ,  H01M10/44 ,  H01M4/58

CPC classification number: H01M4/242 ,  H01M10/345 ,  H01M10/44 ,  Y02E60/124

Abstract: In a nickel-metal hydride rechargeable battery comprising a positive electrode of nickel hydroxide and a negative electrode of hydrogen-absorption alloy, prolonged battery life is achieved by limiting the charge and discharge operations to be performed in the range of 20-60% of the hydrogen-absorption capacity of the hydrogen-absorption alloy.

Abstract translation: 在包含氢氧化镍的正极和氢吸收合金的负极的镍氢二次电池中，通过将充电和放电操作限制在20-60％的范围内来实现延长的电池寿命 氢吸收合金的吸氢能力。

公开(公告)号：US5994877A

公开(公告)日：1999-11-30

申请号：US103982

申请日：1998-06-24

Applicant: Hajime Seri ,  Yoshinori Yamada ,  Kenichi Takeyama ,  Teruhisa Kanbara

Inventor： Hajime Seri ,  Yoshinori Yamada ,  Kenichi Takeyama ,  Teruhisa Kanbara

IPC: G01R31/36 ,  H01M10/44

CPC classification number: G01R31/362 ,  G01R31/3679 ,  G01R31/3624

Abstract: The present invention provides methods for detecting a working condition of a non-aqueous electrolyte secondary battery which allow easy and accurate determination of the degree of degradation and remaining capacity of the non-aqueous electrolyte secondary battery by a simple test irrespective of the past charging and discharging history of the battery. In the methods of the present invention, the degree of degradation of battery is quantitatively determined on the basis of the voltage value in charging or discharging at a constant current, or from an equation with that voltage value as variable.

Abstract translation: 本发明提供用于检测非水电解质二次电池的工作状态的方法，其通过简单的测试容易且准确地确定非水电解质二次电池的劣化程度和剩余容量，而不管过去的充电和 放电电池的历史。 在本发明的方法中，电池的劣化程度根据恒定电流充电或放电时的电压值，或者以该电压值为可变的方程定量确定。

公开(公告)号：US5205985A

公开(公告)日：1993-04-27

申请号：US858366

申请日：1992-03-26

Applicant: Hajime Seri ,  Yoshio Moriwaki ,  Yasuharu Yamamura ,  Yoichiro Tsuji ,  Tsutomu Iwaki

Inventor： Hajime Seri ,  Yoshio Moriwaki ,  Yasuharu Yamamura ,  Yoichiro Tsuji ,  Tsutomu Iwaki

IPC: H01M4/38

CPC classification number: H01M4/383 ,  Y10S420/90

Abstract: A hydrogen storage alloy preferably used for electrodes in an alkaline storage battery is provided. The alloy is of the general formula ZrMn.sub.w V.sub.x M.sub.y Ni.sub.z which comprises C15-type Laves phases having a crystal structure similar to that of MgCu.sub.2 as a main alloy phase, where M is an element selected from the group consisting of Fe and Co; w, x, y, and z are respectively the mole ratios of Mn, V, M and Ni to Zr; the conditions 0.4.ltoreq.w.ltoreq.0.8, 0.1.ltoreq.x.ltoreq.0.3, 0.ltoreq.y.ltoreq.0.2, 1.0.ltoreq.z.ltoreq.1.5 and 2.0.ltoreq.w+x+y+z.ltoreq.2.4 are satisfied.

公开(公告)号：US5131920A

公开(公告)日：1992-07-21

申请号：US713286

申请日：1991-06-11

Applicant: Yoshio Moriwaki ,  Hajime Seri ,  Akemi Shintani ,  Tsutomu Iwaki ,  Yoshinori Toyoguchi

Inventor： Yoshio Moriwaki ,  Hajime Seri ,  Akemi Shintani ,  Tsutomu Iwaki ,  Yoshinori Toyoguchi

IPC: H01M4/38 ,  H01M10/34

CPC classification number: H01M4/383 ,  H01M10/345 ,  Y02E60/124 ,  Y10T29/4911

Abstract: The invention relates to a new method of manufacturing a sealed rechargeable alkaline battery including metal oxides as positive electrode active materials and a hydrogen absorbing alloy as a negative electrode material. The basic principle of the method is that, instead of the conventional electrochemical formation, the property of a hydrogen absorbing alloy is utilized to cause the negative electrode to absorb hydrogen to thereby achieve precharged portions within the negative electrode having a relatively larger capacity as compared with the positive electrode. Regardless of the kind of positive electrode, the method of the invention insures a broad freedom in the capacity appropriation between the positive and negative electrodes.

Abstract translation: 本发明涉及一种包括金属氧化物作为正极活性物质和作为负极材料的吸氢合金的密封可充电碱性电池的新方法。 该方法的基本原理是，代替常规的电化学形成，利用吸氢合金的性质使负极吸收氢，从而在具有相对较大容量的负极内实现预充电部分，与 正电极。 无论正极的种类如何，本发明的方法确保了正极和负极之间的容量容限的广泛的自由度。

公开(公告)号：US5149383A

公开(公告)日：1992-09-22

申请号：US677572

申请日：1991-03-29

Applicant: Hajime Seri ,  Yoshio Moriwaki ,  Akemi Shintani ,  Tsutomu Iwaki

Inventor： Hajime Seri ,  Yoshio Moriwaki ,  Akemi Shintani ,  Tsutomu Iwaki

IPC: H01M4/38

CPC classification number: H01M4/383 ,  Y10S420/90

Abstract: The present invention provides a hydrogen storage alloy electrode made of a pentanary or higher multi-component hydrogen storage alloy or a hydride thereof where the alloy comprises at least Zr, Mn, Cr, Ni, and M where M is one or more elements selected from V an Mo, and a major component of the alloy phase is C.sub.15 (MgCu.sub.2) type Laves phase. This hydrogen storage alloy electrode may be enhanced in its performance by subjecting the alloy after the production thereof to a homogenizing heat-treatment at a temperature of 900.degree. to 1300.degree. C. in vacuum or in an inert gaseous atmosphere.