Abstract:
Pyridinium salts of the formula ##STR1## are prepared. The compounds are useful as phase transfer catalysts for the preparation of methacryloyloxyalkylalkoxysilanes and acryloyloxyalkylalkoxysilanes.
Abstract:
Disclosed are casting resins made from acrylic acid esters with a high content of finely dispersed fillers. The casting resins contain a polymeric organosilicon compound having functional and nonfunctional groups. As functional groups, the copolymer contains one or more alkoxysilyl groups and one or more (meth)acryloxysilyl groups. The copolymer furthermore contains by copolymerization at least one nonfunctional comonomer having an ethylenically unsaturated grouping as well as an additional comonomer of the group of the vinyl carboxylic acid esters and (meth)acrylic acid esters, if desired. The addition of these polymeric organosilanes to known casting resins brings about a greater lowering of the viscosity of these resins, which are used, for example, for the manufacture of sanitary appliances.
Abstract:
The present invention relates to copolymers which can be used as adhesion mediating agents (adhesivers) between polymers and inorganic-oxide material. They are characterized by a reactive alkoxysilyl group and an acrylic or methacrylic acid moiety. Each of these two groups is linked to a fundamental constituent having two chain carbon atoms, this fundamental constituent being constructed on a compound having an ethylenically unsaturated group as monomer. The ratio of the alkoxysilyl groups to the acrylic or methacrylic acid esters in the new copolymers can be established as desired, for example by copolymerizing the copolymers with other compounds having ethylenically unsaturated groups, which do not have the above-named moieties. The present invention also relates to a method of preparing these new copolymers as well as intermediates which occur in the practice of this method, as formerly unknown products.
Abstract:
A method for making a gas chamber for photometric measuring equipment comprises providing a metal frame with recesses on opposite sides establishing a web and at least one opening in the web and having solder surface areas; providing at least two calcium fluoide panes, said panes each having a rim portion; is improved by providing rim surface portions of the panes about to face the recess-web portion of said metal frame with a plurality of layers, by (i) physical vapor depositing a thin chromium nickel layer, (ii) physical vapor depositing thereon a nickel layer, and (iii) by physical vapor depositing thereon a gold layer; vapor depositing on the web portion around the opening of said recesses a gold layer; providing at least two solder elements of basically ring-shaped configuration respectively to be interposed between the web and the panes, the soldering elements being configured so that between their respective outer contour and walls of the recesses a solder flow space obtains when the solder elements are placed into the recesses; and soldering the element on one side for solder-connecting the respective pane to the web at a temperature of about 213.degree. C. in an inert gas and the other element on the other side of and to the web and the respective other pane at a soldering temperature at about 170.degree. C. in an inert gas.
Abstract:
A process for the preparation of a terephthalic, isophthalic or phthalic dialdehyde is described by dehydrogenation of the corresponding xylylene glycol in the vapor phase at 250.degree. to 500.degree. C. The process is carried out in the presence of oxygen, water vapor and a dehydrogenation catalyst, suitably a silver dehydrogenation catalyst.
Abstract:
Organosilanes comprising methacryloxy groups or acryloxy groups are stabilized with a mixture consisting of at least one N,N'-di-substituted-p-phenylenediamine and at least one substituted phenol, which yields products with high purity and high yields.
Abstract:
Vinyl chloride copolymers of vinyl chloride and a comonomer of the formula ##EQU1## wherein Z contains an alkenyl group and X and Y are H or other substituents. The copolymers can be cross linked to form shaped articles of improved elongation and tenacity.
Abstract:
Pyridinium salts of the formula ##STR1## are prepared. The compounds are useful as phase transfer catalysts for the preparation of methacryloyloxyalkylalkoxysilanes and acryloyloxyalkylalkoxysilanes.
Abstract:
A quaternary pyridinium halide is used as the phase transfer catalyst in a process for the preparation of an organosilane containing methacryloyloxy or acryloyloxy groups by reacting an alkali metal methacrylate or alkali metal acrylate with a chloroalkylsilane.
Abstract:
The present invention is in the preparation of methacrylic or acryloxyalkylalkoxysilanes by the reaction at a temperature of from 80.degree. and 130.degree. C. of an alkali (meth) acrylate with a halogen alkylalkoxysilane in the presence of a quaternary ammonium salt which has long-chin alkyl moieties, in which the sum of all carbon atoms is between 10 and 40 as a phase-transfer catalyst. In the new procedure no solvents need to be used. The yields are better than 95%.