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    Impact-modified polycarbonate compositions which have an emulsion graft polymer precipitated under basic conditions and comprise acidic phosphorus compounds
    1.
    发明授权
    Impact-modified polycarbonate compositions which have an emulsion graft polymer precipitated under basic conditions and comprise acidic phosphorus compounds 有权
    具有乳液接枝聚合物的冲击改性聚碳酸酯组合物在碱性条件下沉淀并包含酸性磷化合物

    公开(公告)号：US07943686B2

    公开(公告)日：2011-05-17

    申请号：US12629342

    申请日：2009-12-02

    申请人： Andreas Seidel ,  Evgueni Avtomonov ,  Thomas Eckel

    发明人： Andreas Seidel ,  Evgueni Avtomonov ,  Thomas Eckel

    IPC分类号： C08K5/524 ,  C08K3/32

    CPC分类号： C08L69/005 ,  C08K5/098 ,  C08K5/527 ,  C08L51/04 ,  C08L69/00 ,  C08L2666/24

    摘要： The disclosure relates to impact-modified polycarbonate compositions and moulding compositions comprising A) aromatic polycarbonate or aromatic polyester carbonate or mixtures of these, B) a mixture containing Ba) at least one graft polymer prepared in emulsion polymerization and Bb) at least one carboxylate salt, wherein this mixture, suspended as a 10 wt. % strength suspension in distilled water, has a pH of >7, C) at least one acidic phosphorus compound with at least one P—OH functionality, which are distinguished compared with the prior art by an improved combination of stability to hydrolysis and heat stability, and which are suitable for production of injection-moulded components which have a good toughness at low temperatures and—even with critical processing conditions (high processing temperatures)—still have a good resistance to stress cracking under the influence of chemicals.

    摘要翻译： 本公开涉及冲击改性聚碳酸酯组合物和模塑组合物，其包含A）芳族聚碳酸酯或芳族聚酯碳酸酯或它们的混合物，B）含有Ba）至少一种在乳液聚合中制备的接枝聚合物的混合物，以及Bb）至少一种羧酸盐 ，其中该混合物以10重量％ 在蒸馏水中具有％强度的悬浮液，pH> 7，C）至少一种具有至少一个P-OH官能度的酸性磷化合物，其与现有技术相比通过改进的稳定性与水解和热稳定性的组合而被区分开来 适用于在低温下即使在临界加工条件（高加工温度）下具有良好韧性的注射成型部件的生产，在化学品的影响下也具有良好的抗应力开裂性。

    IMPACT-MODIFIED POLYCARBONATE COMPOSITIONS WHICH HAVE AN EMULSION GRAFT POLYMER PRECIPITATED UNDER BASIC CONDITIONS AND COMPRISE ACIDIC PHOSPHORUS COMPOUNDS
    2.
    发明申请
    IMPACT-MODIFIED POLYCARBONATE COMPOSITIONS WHICH HAVE AN EMULSION GRAFT POLYMER PRECIPITATED UNDER BASIC CONDITIONS AND COMPRISE ACIDIC PHOSPHORUS COMPOUNDS 有权
    具有根据基本条件和包含酸性磷酸盐化合物降解的乳液聚合物的影响改性的聚碳酸酯组合物

    公开(公告)号：US20100144938A1

    公开(公告)日：2010-06-10

    申请号：US12629342

    申请日：2009-12-02

    申请人： Andreas SEIDEL ,  Evgueni Avtomonov ,  Thomas Eckel

    发明人： Andreas SEIDEL ,  Evgueni Avtomonov ,  Thomas Eckel

    IPC分类号： C08K5/527

    CPC分类号： C08L69/005 ,  C08K5/098 ,  C08K5/527 ,  C08L51/04 ,  C08L69/00 ,  C08L2666/24

    摘要： The disclosure relates to impact-modified polycarbonate compositions and moulding compositions comprising A) aromatic polycarbonate or aromatic polyester carbonate or mixtures of these, B) a mixture containing Ba) at least one graft polymer prepared in emulsion polymerization and Bb) at least one carboxylate salt, wherein this mixture, suspended as a 10 wt. % strength suspension in distilled water, has a pH of >7, C) at least one acidic phosphorus compound with at least one P—OH functionality, which are distinguished compared with the prior art by an improved combination of stability to hydrolysis and heat stability, and which are suitable for production of injection-moulded components which have a good toughness at low temperatures and—even with critical processing conditions (high processing temperatures)—still have a good resistance to stress cracking under the influence of chemicals.

    摘要翻译： 本公开涉及冲击改性聚碳酸酯组合物和模塑组合物，其包含A）芳族聚碳酸酯或芳族聚酯碳酸酯或它们的混合物，B）含有Ba）至少一种在乳液聚合中制备的接枝聚合物的混合物，以及Bb）至少一种羧酸盐 ，其中该混合物以10重量％ 在蒸馏水中具有％强度的悬浮液，pH> 7，C）至少一种具有至少一个P-OH官能度的酸性磷化合物，其与现有技术相比通过改进的稳定性与水解和热稳定性的组合而被区分开来 适用于在低温下即使在临界加工条件（高加工温度）下具有良好韧性的注射成型部件的生产，在化学品的影响下也具有良好的抗应力开裂性。

    Impact-modified polycarbonate compositions
    4.
    发明授权
    Impact-modified polycarbonate compositions 有权
    冲击改性聚碳酸酯组合物

    公开(公告)号：US08461260B2

    公开(公告)日：2013-06-11

    申请号：US12640328

    申请日：2009-12-17

    申请人： Achim Feldermann ,  Eckhard Wenz ,  Andreas Seidel ,  Evgueni Avtomonov

    发明人： Achim Feldermann ,  Eckhard Wenz ,  Andreas Seidel ,  Evgueni Avtomonov

    IPC分类号： C08L25/12 ,  C08L55/02 ,  C08L69/00 ,  C08L83/10

    CPC分类号： C08L51/085 ,  C08G77/20 ,  C08L25/12 ,  C08L51/04 ,  C08L51/06 ,  C08L67/02 ,  C08L69/00 ,  C08L69/005 ,  C08L2666/02 ,  C08L2666/14

    摘要： Impact-modified polycarbonate compositions are disclosed that comprise a first graft polymer based on silicone-acrylate composite rubber as graft base, wherein the amount of silicone rubber is from 65 to 95 wt. % (based on the graft base), and a second graft polymer containing free copolymer, that is to say copolymer that is not chemically bonded to the rubber, and having a weight-average molecular weight of from 60,000 to 150,000 g/mol. The use of the polycarbonate compositions in the production of molded articles, and to the molded articles themselves are also disclosed. The compositions and molding compositions have an optimum combination of good elongation at tear, good hydrolytic stability and low melt viscosity.

    摘要翻译： 公开了冲击改性聚碳酸酯组合物，其包含基于硅氧烷 - 丙烯酸酯复合橡胶作为接枝基材的第一接枝聚合物，其中硅橡胶的量为65至95重量％。 ％（基于接枝基质）和含有游离共聚物的第二接枝聚合物，即不与橡胶化学键合的共聚物，重均分子量为60,000至150,000g / mol。 还公开了在制造模塑制品中使用聚碳酸酯组合物以及模制品本身。 组合物和模塑组合物具有良好的撕裂伸长率，良好的水解稳定性和低熔体粘度的最佳组合。

    IMPACT-MODIFIED POLYCARBONATE COMPOSITIONS WITH HIGH HYDROLYSIS RESISTANCE AND A LIGHT NATURAL COLOUR
    5.
    发明申请
    IMPACT-MODIFIED POLYCARBONATE COMPOSITIONS WITH HIGH HYDROLYSIS RESISTANCE AND A LIGHT NATURAL COLOUR 审中-公开
    具有高耐水性和轻质自然色的冲击改性聚碳酸酯组合物

    公开(公告)号：US20090281216A1

    公开(公告)日：2009-11-12

    申请号：US12428256

    申请日：2009-04-22

    申请人： Evgueni AVTOMONOV ,  Andreas SEIDEL ,  Thomas ECKEL ,  Eckhard WENZ

    发明人： Evgueni AVTOMONOV ,  Andreas SEIDEL ,  Thomas ECKEL ,  Eckhard WENZ

    IPC分类号： C08K5/3492 ,  C08K5/13 ,  C08K5/52 ,  C08K5/10 ,  C08K5/53 ,  C08K5/36

    CPC分类号： C08L69/00 ,  C08K5/005 ,  C08K5/52 ,  C08L51/04 ,  C08L55/02 ,  C08L69/005 ,  C08L2201/02 ,  C08L2205/03 ,  C08L2207/04 ,  C08L2666/24

    摘要： The present invention relates to polycarbonate compositions comprising: A) an aromatic polycarbonate and/or aromatic polyester carbonate; B) a graft polymer obtainable by co-precipitation of a mixture of at least two graft polymer dispersions B.1 and B.2, wherein the production of the graft polymer component B.1 takes place using at least one redox system as initiator and wherein the production of the graft polymer component B.2 takes place using at least one persulfate compound as initiator; C) optionally a vinyl (co)polymer and/or polyalkylene terephthalate; D) optionally a phosphorus-containing flame retardant; E) at least one phenolic antioxidant; F) optionally a neutral phosphorus- or sulfur-containing co-stabilisers (synergists); and G) optionally additives. Compositions of the present invention are distinguished by an optimum combination of good hydrolysis resistance and a light natural colour. The present invention also relates to the use of polycarbonate compositions for the production of mouldings and mouldings per se as well.

    摘要翻译： 本发明涉及聚碳酸酯组合物，其包含：A）芳族聚碳酸酯和/或芳族聚酯碳酸酯; B）可通过共沉淀至少两种接枝聚合物分散体B.1和B.2的混合物获得的接枝聚合物，其中接枝聚合物组分B.1的生产使用至少一种氧化还原体系作为引发剂进行， 其中接枝聚合物组分B.2的生产使用至少一种过硫酸盐化合物作为引发剂进行; C）任选的乙烯基（共）聚合物和/或聚对苯二甲酸亚烷基酯; D）任选的含磷阻燃剂; E）至少一种酚类抗氧化剂; F）任选的中性含磷或硫的共稳定剂（增效剂）; 和G）任选的添加剂。 本发明的组合物通过良好的耐水解性和轻的自然色的最佳组合来区分。 本发明还涉及聚碳酸酯组合物本身也用于生产模制品和模制品的用途。