Semiconductive metal chalcogenides of the type Cu.sub.3 VS.sub.4 and
methods for preparing them
    3.
    发明授权
    Semiconductive metal chalcogenides of the type Cu.sub.3 VS.sub.4 and methods for preparing them 失效
    Cu(hd 3 {b VS {HD 4 {B及其制备方法)的半导体金属硫族化物

    公开(公告)号:US3945935A

    公开(公告)日:1976-03-23

    申请号:US193701

    申请日:1971-10-29

    CPC分类号: C30B25/00 C30B29/46 C30B29/48

    摘要: Novel semiconductive tertiary and higher order type copper-Group V transition metal chalcogenides having useful broad-band photoconductive properties are characterized by containing fewer than 100 ppm of impurities as determined by electron microprobe analysis, excluding doping agents which may be present. These materials are made e.g. by chemical vapor transport methods using the powdered chalcogenide or mixtures of stoichiometric amounts of the elements of which it is composed, with a small amount of halogen or hydrogen halide and heating the mixture in vacuum in a temperature gradient in which the highest temperature is below about 1200.degree. C. Photoconducting devices can be made e.g. by supplying electrodes to a thin film of the material upon a dielectric substrate.

    摘要翻译: 具有有用的宽带光电导性质的新型半导体三级和高级类型的铜 - 族V族过渡金属硫族化物的特征在于,通过电子微探针分析测定的含量少于100ppm的杂质,不包括可能存在的掺杂剂。 这些材料例如制成。 通过化学气相传输方法,使用粉末状硫族化物或其组成的化学计量的其元素的混合物与少量的卤素或卤化氢,并在真空中以最高温度低于约的温度梯度加热该混合物 1200℃。可以制成光导器件,例如 通过在电介质基板上向该材料的薄膜供电。