公开(公告)号：US20130066104A1

公开(公告)日：2013-03-14

申请号：US13669607

申请日：2012-11-06

Applicant: Benedikt LAUX ,  Christian Maul ,  Volker Schleep ,  Ingo Sander

Inventor： Benedikt LAUX ,  Christian Maul ,  Volker Schleep ,  Ingo Sander

IPC: B01D3/00 ,  C07C69/54

CPC classification number: B01D1/0088 ,  B01D1/0094 ,  B01D1/22 ,  C07C67/54 ,  C07C69/54

Abstract: Process for purifying unsaturated compounds, and a plant for performing the process. Unsaturated compound obtained by the process.

Abstract translation: 用于纯化不饱和化合物的方法和用于进行该方法的设备。 通过该方法得到的不饱和化合物。

公开(公告)号：US08394982B2

公开(公告)日：2013-03-12

申请号：US12677540

申请日：2008-08-29

Applicant: Benedikt Laux ,  Christian Maul ,  Volker Schleep ,  Ingo Sander

Inventor： Benedikt Laux ,  Christian Maul ,  Volker Schleep ,  Ingo Sander

IPC: C07C67/54 ,  C07C69/54 ,  B01D1/22

CPC classification number: B01D1/0088 ,  B01D1/0094 ,  B01D1/22 ,  C07C67/54 ,  C07C69/54

Abstract: A process for purifying an unsaturated compound, where purification is performed in a plant with evaporators.

Abstract translation: 一种纯化不饱和化合物的方法，其中在具有蒸发器的设备中进行纯化。

公开(公告)号：US20110313195A1

公开(公告)日：2011-12-22

申请号：US13254280

申请日：2010-03-03

Applicant: Bardo Schmitt ,  Wolfgang Klesse ,  Martina Ebert ,  Dirk Broell ,  Guido Protzmann ,  Joachim Knebel ,  Thomas Kehr ,  Hans-Gerhard Stadler ,  Gerhard Koelbl ,  Benedikt Laux

Inventor： Bardo Schmitt ,  Wolfgang Klesse ,  Martina Ebert ,  Dirk Broell ,  Guido Protzmann ,  Joachim Knebel ,  Thomas Kehr ,  Hans-Gerhard Stadler ,  Gerhard Koelbl ,  Benedikt Laux

IPC: C07C231/02

CPC classification number: C07C231/02 ,  Y02P20/582 ,  Y02P20/584 ,  C07C233/38

Abstract: The invention relates to a process for continuously preparing N-alkyl(meth)acrylamides by reacting alkyl (meth)acrylates with high-boiling amines. A catalyst activation and specific workup technique achieve product qualities which have not been achieved to date. In addition, very high space-time yields and overall yields can be achieved.

Abstract translation: 本发明涉及通过使（甲基）丙烯酸烷基酯与高沸点胺反应来连续制备（甲基）丙烯酰胺的N-烷基酯的方法。 催化剂激活和具体的后处理技术实现迄今尚未实现的产品质量。 此外，可以实现非常高的时空产量和总产量。

公开(公告)号：US09221738B2

公开(公告)日：2015-12-29

申请号：US13256469

申请日：2010-03-26

Applicant: Dirk Broell ,  Christian Maul ,  Benedikt Laux ,  Volker Schleep

Inventor： Dirk Broell ,  Christian Maul ,  Benedikt Laux ,  Volker Schleep

IPC: C07C67/54 ,  C07C51/573 ,  B01D3/12 ,  B01D3/42

CPC classification number: C07C51/573 ,  B01D3/12 ,  B01D3/42 ,  C07C67/54 ,  C07C57/04 ,  C07C69/54

Abstract: The present invention relates to a process for purifying monomers, by evaporating at least a portion of the monomers present in a starting composition and then condensing it, which is characterized in that at least a portion of the starting composition is evaporated in a short-path evaporator, the mass flow density of the vapors {dot over (m)} being selected according to the relation (I) m . ≤ 1800 ⁢ kg · K mbar · m 2 · h · kg kmol · p i · ( M ~ T ) 0.5 ( I ) in which {tilde over (M)} is the average molar mass of the vapors in the short-path evaporator in kg/kmol T is the temperature of the vapors in K pi is the pressure in the short-path evaporator in mbar {dot over (m)} is the mass flow density of the vapors in kg/(m2·h). A further aspect of the present invention is a plant for performing the process.

Abstract translation: 本发明涉及通过蒸发存在于起始组合物中的至少一部分单体然后使其冷凝来纯化单体的方法，其特征在于起始组合物的至少一部分在短路径中蒸发 蒸发器，根据关系式（I）m选择蒸气的质量流量密度（点（m）}）。 ≤M1·m························································· 以kg / kmol为单位T是蒸气的温度，K pi是短路蒸发器中的压力，单位为mbar（点）（m）}是蒸汽的质量流密度，单位为kg /（m2·h）。 本发明的另一方面是用于执行该方法的设备。

公开(公告)号：US20110306783A1

公开(公告)日：2011-12-15

申请号：US13202248

申请日：2010-02-25

Applicant: Dirk Broell ,  Benedikt Laux ,  Christian Maul ,  Thorben Schuetz ,  Bardo Schmitt ,  Volker Schleep ,  Claus Zimmer

Inventor： Dirk Broell ,  Benedikt Laux ,  Christian Maul ,  Thorben Schuetz ,  Bardo Schmitt ,  Volker Schleep ,  Claus Zimmer

IPC: C07C67/62 ,  C07C69/54

CPC classification number: C07C67/54 ,  C07C67/26 ,  C07C67/62 ,  C07D211/94 ,  C08K5/13 ,  C08K5/3435 ,  C09K15/08 ,  C09K15/30 ,  C07C69/54

Abstract: The present invention relates to a composition which comprises at least one hydroxyalkyl(meth)acrylate and has been stabilized for a purification, which comprises hydroquinone monomethyl ether and 4-hydroxy-2,2,6,6-tetramethylpiperidine N-oxyl. The present invention additionally describes processes for purifying and for preparing hydroxyalkyl(meth)acrylates. A further aspect of the present invention is a composition which is obtainable by the processes mentioned.

Abstract translation: 本发明涉及包含至少一种（甲基）丙烯酸羟烷基酯并已被稳定以进行纯化的组合物，其包含氢醌单甲醚和4-羟基-2,2,6,6-四甲基哌啶N-氧基。 本发明另外描述了纯化和制备（甲基）丙烯酸羟烷基酯的方法。 本发明的另一方面是可通过所述方法获得的组合物。

公开(公告)号：US20090163735A1

公开(公告)日：2009-06-25

申请号：US12296780

申请日：2007-03-14

Applicant: Volker Schleep ,  Benedikt Laux

Inventor： Volker Schleep ,  Benedikt Laux

IPC: C07C255/12 ,  C07C253/16 ,  B01D3/14

CPC classification number: C07C253/16 ,  C07C255/12

Abstract: The invention relates to an apparatus and to a process for continuously preparing ethylene cyanohydrin.

Abstract translation: 本发明涉及连续制备乙烯氰醇的装置和方法。

公开(公告)号：US08674133B2

公开(公告)日：2014-03-18

申请号：US13254280

申请日：2010-03-03

Applicant: Bardo Schmitt ,  Wolfgang Klesse ,  Martina Ebert ,  Dirk Broell ,  Guido Protzmann ,  Joachim Knebel ,  Thomas Kehr ,  Hans-Gerhard Stadler ,  Gerhard Koelbl ,  Benedikt Laux

Inventor： Bardo Schmitt ,  Wolfgang Klesse ,  Martina Ebert ,  Dirk Broell ,  Guido Protzmann ,  Joachim Knebel ,  Thomas Kehr ,  Hans-Gerhard Stadler ,  Gerhard Koelbl ,  Benedikt Laux

IPC: C07C231/02

CPC classification number: C07C231/02 ,  Y02P20/582 ,  Y02P20/584 ,  C07C233/38

Abstract: The invention relates to a process for continuously preparing N-alkyl(meth)acrylamides by reacting alkyl(meth)acrylates with high-boiling amines. A catalyst activation and specific workup technique achieve product qualities which have not been achieved to date. In addition, very high space-time yields and overall yields can be achieved.

Abstract translation: 本发明涉及通过使（甲基）丙烯酸烷基酯与高沸点胺反应来连续制备（甲基）丙烯酰胺的N-烷基酯的方法。 催化剂激活和具体的后处理技术实现迄今尚未实现的产品质量。 此外，可以实现非常高的时空产量和总产量。

公开(公告)号：US06936734B2

公开(公告)日：2005-08-30

申请号：US10068849

申请日：2002-02-11

Applicant: Bardo Schmitt ,  Joachim Knebel ,  Wolfgang Klesse ,  Andrea Wittkowski ,  Benedikt Laux

Inventor： Bardo Schmitt ,  Joachim Knebel ,  Wolfgang Klesse ,  Andrea Wittkowski ,  Benedikt Laux

IPC: C07B61/00 ,  C07C51/56 ,  C07C51/573 ,  C07C57/04 ,  C07C65/00

CPC classification number: C07C51/56 ,  C07C57/04

Abstract: The present invention relates to a process for preparing an unsaturated carboxylic acid anhydride by reacting an unsaturated carboxylic acid and a lower aliphatic carboxylic acid anhydride in the presence of a stabilizer and catalyst that contains a metal salt of an anionic organic compound which has at least one carboxyl group.

Abstract translation: 本发明涉及一种在稳定剂和含有阴离子有机化合物的金属盐的催化剂存在下使不饱和羧酸和低级脂族羧酸酐反应制备不饱和羧酸酐的方法，所述阴离子有机化合物的金属盐具有至少一个 羧基。

公开(公告)号：US20140288330A1

公开(公告)日：2014-09-25

申请号：US14351981

申请日：2012-11-20

Applicant: Dirk Broell ,  Benedikt Laux ,  Christian Maul ,  Patrick Peter ,  Claus Zimmer

Inventor： Dirk Broell ,  Benedikt Laux ,  Christian Maul ,  Patrick Peter ,  Claus Zimmer

IPC: C07C231/02 ,  C07C231/24

CPC classification number: C07C231/02 ,  C07C231/24 ,  C07C233/09

Abstract: The invention relates to a process for preparing N-alkyl(meth)acrylamides by reacting (meth)acrylic anhydride with corresponding alkylamines.

Abstract translation: 本发明涉及通过使（甲基）丙烯酸酐与相应的烷基胺反应制备N-（烷基）丙烯酰胺的方法。

公开(公告)号：US20120000764A1

公开(公告)日：2012-01-05

申请号：US13256469

申请日：2010-03-26

Applicant: Dirk Broell ,  Christian Maul ,  Benedikt Laux ,  Volker Schleep

Inventor： Dirk Broell ,  Christian Maul ,  Benedikt Laux ,  Volker Schleep

IPC: B01D3/02

CPC classification number: C07C51/573 ,  B01D3/12 ,  B01D3/42 ,  C07C67/54 ,  C07C57/04 ,  C07C69/54

Abstract: The present invention relates to a process for purifying monomers, by evaporating at least a portion of the monomers present in a starting composition and then condensing it, which is characterized in that at least a portion of the starting composition is evaporated in a short-path evaporator, the mass flow density of the vapours {dot over (m)} being selected according to the relation (I) m . ≤ 1800  kg · K mbar · m 2 · h · kg kmol · p i · ( M ~ T ) 0.5 ( I ) in which {tilde over (M)} is the average molar mass of the vapours in the short-path evaporator in kg/kmol T is the temperature of the vapours in K pi is the pressure in the short-path evaporator in mbar {dot over (m)} is the mass flow density of the vapours in kg/(m2·h). A further aspect of the present invention is a plant for performing the process.

Abstract translation: 本发明涉及通过蒸发存在于起始组合物中的至少一部分单体然后使其冷凝来纯化单体的方法，其特征在于起始组合物的至少一部分在短路径中蒸发 蒸发器，根据关系式（I）m选择蒸气的质量流量密度（点（m）}）。 ≤M1·m······································（1）式中，（波形）（M）}是短路蒸发器中蒸气的平均摩尔质量 以kg / kmol为单位T是蒸气的温度，K pi是短路蒸发器中的压力，单位为mbar（点）（m）}是蒸汽的质量流密度，单位为kg /（m2·h）。 本发明的另一方面是用于执行该方法的设备。