公开(公告)号：US5902918A

公开(公告)日：1999-05-11

申请号：US765746

申请日：1997-03-13

Applicant: Alfred Hagemeyer ,  Gunter Lauth ,  Thomas Lautensack ,  Axel Deimling

Inventor： Alfred Hagemeyer ,  Gunter Lauth ,  Thomas Lautensack ,  Axel Deimling

IPC: B01J23/18 ,  B01J23/92 ,  C07B61/00 ,  C07C5/42 ,  C07C11/02 ,  C07C15/40 ,  C07C15/46 ,  C07C5/367

CPC classification number: C07C5/42 ,  B01J23/92 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2523/10 ,  C07C2523/18 ,  C07C2523/22 ,  Y02P20/584

Abstract: Alkenylaromatics are produced by catalytic oxidative dehydrogenation of alkylaromatics employing a redox catalyst which is bismuth oxide, in combination with an additive compound of an alkali metal and/or an alkaline earth metal, on a titanium diooxide carrier. In a first reaction step, an alkylaromatic starting material is oxidatively dehydrogenated with the redox catalyst in the absence of molecular oxygen with attending reduction of the redox catalyst. In a second reaction step, the reduced redox catalyst is reoxidized with an oxygen-containing gas.

Abstract translation: PCT No.PCT / EP95 / 02483第 371日期1997年3月13日 102（e）日期1997年3月13日PCT归档1995年6月26日PCT Pub。 公开号WO96 / 01796 日期1996年1月25日烯烃芳烃通过使用氧化铋催化剂的烷基芳族化合物的催化氧化脱氢产生，氧化铋催化剂与碱金属和/或碱土金属的添加剂化合物结合在钛二氧化物载体上。 在第一反应步骤中，在不存在分子氧的情况下，使烷基芳族原料与氧化还原催化剂进行氧化脱氢，同时引起氧化还原催化剂的还原。 在第二反应步骤中，还原的氧化还原催化剂用含氧气体再氧化。

公开(公告)号：US5658538A

公开(公告)日：1997-08-19

申请号：US550738

申请日：1995-10-31

Applicant: Axel Deimling ,  Uwe Behling

Inventor： Axel Deimling ,  Uwe Behling

IPC: B01J8/02 ,  B01J8/06 ,  C07C5/333

CPC classification number: B01J8/06 ,  B01J8/0285 ,  C07C5/333 ,  B01J2208/00221

Abstract: Apparatus, in particular reactor for carrying out endothermic catalytically promoted gas-phase reactions, which has, arranged one on top of the other or one inside the other in a common jacket, a tube-bundle heat exchanger 1 consisting of a plurality of parallel tubes provided with baffles 1a securing a flow of the heat exchanging medium in a direction transverse to the axis of said tubes, a reaction space 6 which preferably widens conically upward, has a base and is intended for holding a catalyst bed, a tube-bundle heat exchanger 2 to which material flows laterally and which is provided with baffles 2a, a reaction space 4 which has a base, is closed at the top by a gas dome and is intended for holding a catalyst bed, a central tube 3 for connecting the outer space of the heat exchanger 1 to the gas space above the reaction space 4, and inlet and outlet means for a heating or cooling gas (c) and inlet and outlet means (a or b) for the fresh gas or reaction mixture, respectively.

Abstract translation: 装置，特别是用于进行吸热催化促进的气相反应的反应器，其具有一个在另一个的顶部或另一个上在一个共同的夹套中排列的管 - 热交换器1，由多个平行的管 设置有挡板1a，该挡板1a沿横向于所述管的轴线的方向固定热交换介质的流动，反应空间6优选地向上锥形向上扩展，具有基部并且用于保持催化剂床，管束热 交换器2，其材料横向流动并且设置有挡板2a，具有基座的反应空间4在顶部由气体圆顶封闭并且用于保持催化剂床，用于连接外部的中心管3 热交换器1的空间与反应空间4上方的气体空间以及用于新鲜气体或反应混合物的加热或冷却气体（c）和入口和出口装置（a或b）的入口和出口装置。

公开(公告)号：US5559066A

公开(公告)日：1996-09-24

申请号：US381916

申请日：1995-02-13

Applicant: Wolfgang J. Poepel ,  Gregor Tremmel ,  Wolfgang Buechele ,  Axel Deimling ,  Hermann Petersen

Inventor： Wolfgang J. Poepel ,  Gregor Tremmel ,  Wolfgang Buechele ,  Axel Deimling ,  Hermann Petersen

IPC: B01J23/78 ,  B01J23/85 ,  B01J23/94 ,  B01J37/00 ,  B01J38/00 ,  B01J38/68 ,  C07C5/32

CPC classification number: B01J23/94 ,  B01J37/0036 ,  B01J38/68 ,  C07C5/321 ,  Y02P20/584

Abstract: A process for the preparation of iron-, potassium- and cerium-containing catalysts for the dehydrogenation of hydrocarbons from the same spent catalysts (regeneration) by grinding and, if necessary, purifying the spent material, restoring the original activity by adjusting the composition and restoring the external shape comprises adding to the ground material an effective amount of potassium and such an amount of cerium that the total amount of cerium is greater than the amount originally present.

Abstract translation: PCT No.PCT / EP93 / 03083第 371日期1995年2月13日 102（e）日期1995年2月13日PCT 1993年11月5日PCT公布。 出版物WO94 / 11104 日期1994年5月26日制备用于通过研磨从相同的废催化剂（再生）中脱氢烃类的含铁，钾和铈的催化剂的方法，如有必要，纯化废料，通过 调整组成并恢复外部形状包括向研磨材料中加入有效量的钾和这样一定量的铈，使铈的总量大于原来存在的量。

公开(公告)号：US5691262A

公开(公告)日：1997-11-25

申请号：US542185

申请日：1995-10-12

Applicant: Alfred Hagemeyer ,  Otto Watzenberger ,  Axel Deimling

Inventor： Alfred Hagemeyer ,  Otto Watzenberger ,  Axel Deimling

IPC: B01J23/08 ,  B01J23/10 ,  B01J23/14 ,  B01J23/48 ,  B01J23/70 ,  B01J38/12 ,  C07B35/04 ,  C07B61/00 ,  C07C5/42 ,  C07C11/02 ,  C07C15/46 ,  B01J38/32

CPC classification number: C07C5/42 ,  B01J38/12 ,  C07B35/04 ,  C07C2521/06 ,  C07C2523/26 ,  Y02P20/584

Abstract: A regenerative process for the preparation of olefinically unsaturated compounds by oxidation/dehydrogenation of selectively oxidizable hydrocarbons over an oxygen carrier acting as catalyst, in the absence of molecular oxygen, alternating (in repeated cycles) with regeneration of the spent oxygen carrier with a gaseous molecular oxidizing agent, in which the spent (reduced) catalyst is cooled, prior to introduction of the regenerating gas, to a temperature which is below the temperature of the reaction, regeneration being controlled in such a manner that the highest temperature occurring during regeneration does not exceed the temperature of reaction at which dehydrogenation is commenced.

Abstract translation: 通过在不存在分子氧的情况下，在不存在分子氧的情况下，以氧气载体氧化/脱氢的氧选择性氧化烃氧化/脱氢制备烯属不饱和化合物的再生方法，与废氧载体与气态分子的再生交替（重复循环） 在将再生气体引入之前将已用（还原的）催化剂冷却的氧化剂达到低于反应温度的温度，再生被控制为使再生时发生的最高温度不再 超过开始脱氢反应的温度。

公开(公告)号：US5895829A

公开(公告)日：1999-04-20

申请号：US849712

申请日：1997-06-18

Applicant: Wolfgang Jurgen Popel ,  Alfred Hagemeyer ,  Wolfgang Buchele ,  Axel Deimling ,  Wolfgang Hoffmann

Inventor： Wolfgang Jurgen Popel ,  Alfred Hagemeyer ,  Wolfgang Buchele ,  Axel Deimling ,  Wolfgang Hoffmann

IPC: B01J23/648 ,  C07C5/42 ,  C07C15/46

CPC classification number: C07C5/42 ,  C07C2521/10 ,  C07C2523/22

Abstract: In a process for preparing olefinically unsaturated compounds such as styrene by oxidative dehydrogenation of corresponding hydrocarbons using a previously oxidized oxygen transferer acting as catalyst in the absence of molecular oxygen and reoxidation of the oxygen transferer in at least two reactors, the dehydrogenation and regeneration takes place alternately in time in the two reactors and the reactors are connected to one another in terms of heat via heat exchangers and a common circuit for heat transfer medium.

Abstract translation: PCT No.PCT / EP95 / 04895 371日期：1997年6月18日 102（e）日期1996年6月18日PCT提交1995年12月12日PCT公布。 WO96 / 20149 PCT出版物 日期1996年7月4日在通过在不存在分子氧作为催化剂和在至少两个反应器中的氧转移体再氧化的氧化氧转移体的氧化脱氢制备烯属不饱和化合物如苯乙烯的方法中， 脱氢和再生在两个反应器中交替地交替发生，并且反应器通过热交换器和用于传热介质的公共电路在热量方面彼此连接。

公开(公告)号：US5856605A

公开(公告)日：1999-01-05

申请号：US859184

申请日：1997-05-20

Applicant: Axel Deimling ,  Wilhelm Ruppel ,  Uwe Behling ,  Dieter Biedenkapp

Inventor： Axel Deimling ,  Wilhelm Ruppel ,  Uwe Behling ,  Dieter Biedenkapp

IPC: C07C5/333 ,  C07C5/367 ,  C07C5/32

CPC classification number: C07C5/333

Abstract: A process for the dehydrogenation of ethylbenzene to styrene with input of heat by a heat-transfer medium on a dehydrogenation catalyst which is essentially located in a tube bundle, wherein the heat-transfer medium flows countercurrently to the reaction mixture in the region of the tube bundle, and, if required, another reaction chamber is located downstream of the tube bundle and is provided with a catalyst for adiabatic reaction.

Abstract translation: 一种通过热传递介质在基本上位于管束中的脱氢催化剂输入热量使乙苯脱氢的方法，其中传热介质在管的区域中与反应混合物逆流流动 并且如果需要，另一反应室位于管束的下游，并且设置有用于绝热反应的催化剂。

公开(公告)号：US06399703B1

公开(公告)日：2002-06-04

申请号：US09582879

申请日：2000-07-06

Applicant: Wolfgang Fischer ,  Eugen-Walter Büchner ,  Axel Deimling ,  Hermann Gausepohl ,  Christian Schade

Inventor： Wolfgang Fischer ,  Eugen-Walter Büchner ,  Axel Deimling ,  Hermann Gausepohl ,  Christian Schade

IPC: C08F29700

CPC classification number: C08F279/02 ,  C08F287/00 ,  C08F212/08

Abstract: A process for preparing impact-modified styrene polymers (HIPS) omprises anionic polymerization of styrene in the presence of a rubber in one or more polymerization reactors in succession. The rubber is prepared in solution in an immediately upstream process. The heat of polymerization is utilized to remove the solvent for the rubber, this solvent having a boiling point lower than those of styrene and ethylbenzene, from at least one of the polymerization reactors via distillation with distillative cooling, and the solvent is reintroduced into the process of rubber preparation.

Abstract translation: 制备冲击改性苯乙烯聚合物（HIPS）的方法在连续的一个或多个聚合反应器中在橡胶存在下进行苯乙烯的阴离子聚合。 橡胶在紧密上游过程中在溶液中制备。 使用聚合热来除去溶剂，该溶剂的沸点低于苯乙烯和乙苯的溶剂，来自至少一个聚合反应器通过蒸馏蒸馏冷却，并将溶剂重新引入该方法 的橡胶制剂。

公开(公告)号：US5780700A

公开(公告)日：1998-07-14

申请号：US527683

申请日：1995-09-13

Applicant: Alfred Hagemeyer ,  Thomas Lautensack ,  Otto Watzenberger ,  Axel Deimling

Inventor： Alfred Hagemeyer ,  Thomas Lautensack ,  Otto Watzenberger ,  Axel Deimling

IPC: C07B31/00 ,  C07B35/04 ,  C07B61/00 ,  C07C2/84 ,  C07C5/333 ,  C07C5/42 ,  C07C11/02 ,  C07C15/44 ,  C07C45/28 ,  C07C45/65 ,  C07C51/377 ,  C07C57/055 ,  C07C67/39 ,  C07C253/26 ,  C07C5/09

CPC classification number: C07B35/04 ,  C07C2/84 ,  C07C45/28 ,  C07C45/65 ,  C07C5/42 ,  C07C51/377 ,  C07C67/39 ,  C07C2521/06 ,  C07C2523/26 ,  Y02P20/584

Abstract: A process for the preparation of olefinically unsaturated compounds by catalytic oxidation, ie oxidative dehydrogenation by transferring oxygen from a previously oxidized oxygen carrier acting as catalyst, in the absence of molecular oxygen, the catalyst being regenerated after exhaustion, wherein, during the operating phase of the catalyst (oxidation/dehydration partial step), the residence time, space velocity and/or temperature of the reactants in the reactor is/are adjusted, ie, controlled, continuously or in discrete steps, in a manner appropiate to the momentary state of activity of the redox catalyst by adjusting--continuously or stepwise--the residence time of the reactants in the freshly regenerated catalyst (ie at the commencement of the reaction) to a shorter time, and/or the temperature to a lower value, than the corresponding parameter(s) in the partially reduced catalyst.

Abstract translation: 一种通过催化氧化制备烯属不饱和化合物的方法，即通过在不存在分子氧的情况下，将氧气从作为催化剂的氧化氧载体中转移而进行的氧化脱氢，该催化剂在耗尽后再生，其中，在操作阶段 催化剂（氧化/脱水部分步骤），反应器中的反应物的停留时间，空间速度和/或温度被调整，即以适当的方式适当地连续或以离散步骤控制 通过将新鲜再生催化剂中的反应物（即反应开始时）的停留时间连续或逐步调节至较短时间和/或温度降至较低值的氧化还原催化剂的活性， 部分还原催化剂中的参数。