公开(公告)号：US4269923A

公开(公告)日：1981-05-26

申请号：US114296

申请日：1980-01-22

申请人： Raymond A. Roosen ,  Robert J. Pollet ,  Antoon L. Vandenberghe

发明人： Raymond A. Roosen ,  Robert J. Pollet ,  Antoon L. Vandenberghe

IPC分类号： G03C1/00 ,  G03C1/06 ,  G03C5/42 ,  G03C5/50 ,  G03C7/24 ,  G03C7/305 ,  G03C8/08

CPC分类号： G03C8/08 ,  G03C5/42 ,  G03C5/50 ,  G03C7/24 ,  G03C7/305 ,  Y10S430/135 ,  Y10S430/156

摘要： Novel photographic imaging process and materials suitable therefor are provided, which can find their application in multi-color motion picture and simultaneous sound recording, in direct-positive image formation, in image-intensification processes, etc. A photographic silver image is formed in at least one hydrophilic colloid layer of a light-sensitive photographic material incorporating silver halide, by means of exposure and alkaline development steps, followed by bleaching of quantities of silver which are present in areas of said layer extraneous to those where imaging silver is required. A non-diffusible silver bleach inhibitor is initially present in said layer or is released therein during processing of the material but before the bleaching step to prevent bleaching of the required imaging silver in said layer in the bleaching step and the prevention of the bleaching of the silver by the bleach inhibitor in the areas extraneous to those where imaging silver is required is counteracted by the presence in the corresponding areas of such layer of a bleach accelerator which is caused to diffuse into such areas from an adjacent hydrophilic colloid layer during the development processing of the material.

摘要翻译： 提供了适合于其的新型摄影成像工艺和材料，可以在图像强化处理等中，将其应用于多色运动图像和同时录音，直接成像，形成图像。 通过曝光和碱性显影步骤将含有卤化银的光敏照相材料的至少一个亲水胶体层，随后漂白出存在与需要成像银的那些层相邻的所述层的区域中的数量的银。 最初在所述层中存在非扩散性银漂白抑制剂，或者在处理材料期间但在漂白步骤之前释放其中，以防止漂白步骤中所需层中所需的成像银漂白，并防止漂白 通过漂白剂促进剂的这种层的相应区域的存在，在显影处理过程中由相邻的亲水胶体层扩散到这些区域中的那些区域中，通过漂白剂抑制剂与需要成像银的那些区域的银相抵消 的材料。

公开(公告)号：US4727017A

公开(公告)日：1988-02-23

申请号：US823948

申请日：1986-01-29

申请人： Robert J. Pollet ,  Antoon L. Vandenberghe ,  Hendrik E. Kokelenberg ,  Piet Kok

发明人： Robert J. Pollet ,  Antoon L. Vandenberghe ,  Hendrik E. Kokelenberg ,  Piet Kok

IPC分类号： C07D487/04 ,  G03C1/34

CPC分类号： C07D487/04 ,  G03C1/34 ,  Y10S430/15

摘要： Photographic element comprising a support and a silver halide emulsion layer comprising in said emulsion layer and/or in a water-permeable layer coated at the same side of the support as said emulsion layer a compound corresponding to the following general formula: ##STR1## wherein: each of R.sup.1, R.sup.2, and R.sup.3, which may be the same or different, can represent hydrogen, C.sub.1 -C.sub.8 alkyl, or Alk.sub.1 - X - Alk.sub.2 - Y -, wherein: Alk.sub.1 is C.sub.1 -C.sub.8 alkyl, which may be substituted, X is --O-- or --S--, Alk.sub.2 is C.sub.1 -C.sub.8 alkylene, which may be substituted, and Y is a single bond, --O--, --S--, --CONH--, --SO.sub.2 NH--, or --NHCONH--, R.sup.3 can alternatively represent C.sub.1 -C.sub.8 alkyl-thio, the C.sub.1 -C.sub.8 alkyl group of which can be substituted, at least one of R.sup.1, R.sup.2, and R.sup.3, however, being other than hydrogen and other than C.sub.1 -C.sub.8 alkyl.The invention disclosed includes compounds per se, which correspond to said general formula.

摘要翻译： 包含载体和卤化银乳剂层的照相元件包括在所述乳剂层中和/或在与所述乳剂层的支持物的同一侧涂覆的透水层中，所述化合物对应于以下通式：其中 ：可以相同或不同的R 1，R 2和R 3可以表示氢，C 1 -C 8烷基或Alk 1 -X-Alk 2 -Y-，其中：Alk1是可被取代的C 1 -C 8烷基，X 是-O-或-S-，Alk2是可以被取代的C1-C8亚烷基，Y是单键，-O - ， - S - ， - CONH - ， - SO2NH-或-NHCONH-，R3可以 或者表示C1-C8烷基 - 硫基，其C1-C8烷基可以被取代，R 1，R 2和R 3中的至少一个，但不是氢并且不是C 1 -C 8烷基。 所公开的本发明包括对应于所述通式的化合物本身。

公开(公告)号：US4132551A

公开(公告)日：1979-01-02

申请号：US541123

申请日：1975-01-15

申请人： Robert J. Pollet ,  Robrecht J. Thiers ,  Theofiel H. Ghys ,  Antoon L. Vandenberghe ,  Herman A. Philippaerts ,  Hubert Vandenabeele

发明人： Robert J. Pollet ,  Robrecht J. Thiers ,  Theofiel H. Ghys ,  Antoon L. Vandenberghe ,  Herman A. Philippaerts ,  Hubert Vandenabeele

IPC分类号： G03C1/34 ,  G03C5/305 ,  G03C5/30

CPC分类号： G03C1/34 ,  G03C5/305

摘要： A method for producing photographic images by development of an exposed silver halide element at elevated temperature is provided wherein the development occurs in the presence of a non-quaternary, non-heterocyclic nitrobenzene compound of the formula: ##STR1## WHEREIN: (R).sub.n stands for one or more substituents selected from hydrogen, halogen, alkyl, substituted alkyl, alkenyl, substituted alkenyl, alkynyl, substituted alkynyl, alkoxy, substituted alkoxy, alkylmercapto, substituted alkylmercapto, amino, substituted amino, aryl, substituted aryl, hydroxy, nitro, cyano, sulpho or carboxy in acid or salt form, alkoxycarbonyl and an acyl group derived from a carboxylic or sulphonic acid.The nitrobenzene compounds have a favorable effect on the sensitometric properties of the silver halide emulsion that are developed at elevated temperature. They reduce the supplemental fog produced by development at elevated temperature.

摘要翻译： 提供了一种通过在升高的温度下开发暴露的卤化银元素来生产照相图像的方法，其中显影发生在下式的非季铵非杂环硝基苯化合物存在下：其中：

公开(公告)号：US4451555A

公开(公告)日：1984-05-29

申请号：US324805

申请日：1981-11-25

申请人： Robert J. Pollet ,  Antoon L. Vandenberghe ,  Roger A. Spriet

发明人： Robert J. Pollet ,  Antoon L. Vandenberghe ,  Roger A. Spriet

IPC分类号： C07D257/04 ,  G03C1/34

CPC分类号： C07D257/04 ,  G03C1/346

摘要： The present invention deals with novel antifogging compounds and their use in a method of photographic reproduction comprising developing a photographic material having at least one exposed silver halide emulsion layer in the presence of a 1-phenyl-5-mercaptotetrazole compound wherein the phenyl group bears a substituent comprising at least one thioether function.

摘要翻译： 本发明涉及新颖的防雾化合物及其在照相生产方法中的用途，包括在1-苯基-5-巯基四唑化合物存在下显影具有至少一个暴露的卤化银乳剂层的照相材料，其中苯基带有 取代基包含至少一个硫醚官能团。

公开(公告)号：US4307175A

公开(公告)日：1981-12-22

申请号：US185932

申请日：1980-09-10

申请人： Robert J. Pollet ,  Hendrik E. Kokelenberg ,  Antoon L. Vandenberghe

发明人： Robert J. Pollet ,  Hendrik E. Kokelenberg ,  Antoon L. Vandenberghe

IPC分类号： G03C7/00 ,  C07D257/04 ,  C07D307/46 ,  F02D41/02 ,  G03C1/34 ,  G03C8/00

CPC分类号： C07D257/04 ,  C07C323/00 ,  C07D307/46 ,  G03C1/346 ,  G03C8/00

摘要： A photographic material comprising in at least one light-sensitive silver halide emulsion layer and/or in a hydrophilic colloid layer in water-permeable relationship with such an emulsion layer an antifoggant precursor corresponding to one of the following general formulae: ##STR1## wherein: each of Y.sup.1 and Y.sup.2 (same or different) is an acyl groupeach of Y.sup.10 and Y.sup.20 (same or different) is an aromatic acyl group,R is an alkyl group, an aryl group or a heterocyclic nitrogen-containing 5-, 6- or 7-membered ring,R.sup.1 is hydrogen, an alkyl group, an aryl group, a carboxyl group in free acid, salt or esterified form, a carbamoyl group or a N-substitued carbamoyl group,R.sup.2 is hydrogen, an alkyl group or an aryl group,R.sup.3 has the same meaning as Y.sup.10, or is hydrogen, or is an alkyl group or an aryl group, or is a R.sup.7 -S- group wherein R.sup.7 is an alkyl group, an aryl group, or a heterocyclic group,R.sup.4 is hydrogen, an aryl group or a heterocyclic group,R.sup.5 is hydrogen, an alkyl group, an aryl group or a heterocyclic group, andZ represents the necessary atoms to close a heterocyclic nitrogen-containing 5-, 6- or 7-membered ring.

摘要翻译： 一种照相材料，其在至少一种感光卤化银乳剂层和/或亲水胶体层中与这种乳剂层具有水可渗透的关系，该防沫剂前体对应于以下通式之一：其中： Y1和Y2（相同或不同）分别为Y10和Y20（相同或不同）为酰基，芳基为酰基，R为烷基，芳基或杂环含氮的5-，6- 或7-元环，R 1是氢，烷基，芳基，游离酸中的羧基，盐或酯化形式，氨基甲酰基或N-取代的氨基甲酰基，R 2是氢，烷基或 芳基，R 3具有与Y 10相同的含义，或为氢原子，或为烷基或芳基，或为R 7 -S-基，其中R 7为烷基，芳基或杂环基，R 4 是氢，芳基或杂环基，R 5是氢，烷基，芳基或 杂环基，Z表示封闭杂环含氮的5-，6-或7-元环的必需原子。