公开(公告)号：US5110740A

公开(公告)日：1992-05-05

申请号：US403530

申请日：1989-09-06

Applicant: Alexander R. Pokora ,  John J. Stolfo

Inventor： Alexander R. Pokora ,  John J. Stolfo

IPC: C08G8/10 ,  C08G8/00 ,  C08G8/08 ,  C12P7/22

CPC classification number: C12P7/22 ,  C08G8/08 ,  Y10T428/31536

Abstract: A method for treating a suspension of a phenolic resin containing residual phenols comprising the step of adding a peroxidase enzyme and a peroxide material or an oxidase enzyme and an oxygen material to said suspension to polymerize said residual phenolic monomer, and the purified suspension produced thereby is disclosed. The inventive method is used to pretreat a suspension containing a phenolic material so that the suspension may be subsequently used in a commercial process, such as the production of paper.

公开(公告)号：USRE35247E

公开(公告)日：1996-05-21

申请号：US270867

申请日：1994-07-05

Applicant: William L. Cyrus, Jr. ,  Alexander R. Pokora

Inventor： William L. Cyrus, Jr. ,  Alexander R. Pokora

IPC: C12P7/22 ,  C12N9/04 ,  C12N9/08 ,  C12P7/32

CPC classification number: C12P7/22

Abstract: A process for preparing a phenolic resin which comprises preparing a reaction medium containing a phenol and a peroxidase enzyme and adding a solution of a peroxide to said medium, said peroxide being added to said medium at a rate which decreases from an initial rate of about 2 to 3 millimolar/min as the amount of phenol in said medium decreases such that the concentration of peroxide does not exceed about 12 millimolar.

Abstract translation: 一种制备酚醛树脂的方法，包括制备含有苯酚和过氧化物酶的反应介质，并向所述介质中加入过氧化物溶液，所述过氧化物以从约2的初始速率降低的速率加入到所述介质中 至3毫摩尔/分钟，因为所述介质中苯酚的量减少，使得过氧化物的浓度不超过约12毫摩尔。

公开(公告)号：US5370770A

公开(公告)日：1994-12-06

申请号：US973725

申请日：1992-11-09

Applicant: Mark A. Johnson ,  Alexander R. Pokora

Inventor： Mark A. Johnson ,  Alexander R. Pokora

IPC: D21C5/00 ,  D21C5/02

CPC classification number: D21C5/027 ,  D21C5/005 ,  Y02W30/648

Abstract: A method of deinking printed waste paper for recycle which comprises converting a printed waste paper to a fibrous pulp in an aqueous medium to form a fibrous pulp slurry; contacting the slurry with a soybean peroxidase and a peroxide to deink the pulp; separating the deinked pulp from the aqueous medium; and recovering the deinked pulp.

Abstract translation: 一种用于再循环的印刷废纸脱墨方法，包括将印刷废纸转化为水介质中的纤维纸浆以形成纤维纸浆; 使浆料与大豆过氧化物酶和过氧化物接触以使纸浆脱墨; 将脱墨纸浆与水性介质分离; 并回收脱墨纸浆。

公开(公告)号：US5330619A

公开(公告)日：1994-07-19

申请号：US12039

申请日：1993-02-01

Applicant: Mark A. Johnson ,  Alexander R. Pokora ,  Joseph B. Henry

Inventor： Mark A. Johnson ,  Alexander R. Pokora ,  Joseph B. Henry

IPC: D21C5/00 ,  D21C5/02 ,  D21H21/20

CPC classification number: D21C5/02 ,  D21C5/005 ,  D21H21/20 ,  Y02W30/648

Abstract: A method for treating fibrous sheet materials such as paper or paperboard containing polyamide resin as a wet strength agent which comprises reacting the fibrous materials with an enzyme to hydrolyze the resin and thereby improve repulping of the fibrous materials.

Abstract translation: 一种处理纤维片材的方法，例如含有聚酰胺树脂的纸或纸板作为湿强度剂，其包括使纤维材料与酶反应以水解树脂，从而改善纤维材料的再浆化。

公开(公告)号：US5278055A

公开(公告)日：1994-01-11

申请号：US895905

申请日：1992-06-09

Applicant: William L. Cyrus, Jr. ,  Alexander R. Pokora

Inventor： William L. Cyrus, Jr. ,  Alexander R. Pokora

IPC: C12P7/22 ,  C12N9/04 ,  C12N9/08 ,  C12P7/32

CPC classification number: C12P7/22

Abstract: A process for preparing a phenolic resin which comprises preparing a reaction medium containing a phenol and a peroxidase enzyme and adding a solution of a peroxide to said medium, said peroxide being added to said medium at a rate which decreases from an initial rate of about 2 to 3 millimolar/min as the amount of phenol in said medium decreases such that the concentration of peroxide does not exceed about 12 millimolar.

Abstract translation: 一种制备酚醛树脂的方法，包括制备含有苯酚和过氧化物酶的反应介质，并向所述介质中加入过氧化物溶液，所述过氧化物以从约2的初始速率降低的速率加入到所述介质中 至3毫摩尔/分钟，因为所述介质中苯酚的量减少，使得过氧化物的浓度不超过约12毫摩尔。

公开(公告)号：US5178762A

公开(公告)日：1993-01-12

申请号：US876509

申请日：1992-04-29

Applicant: Alexander R. Pokora ,  Mark A. Johnson

Inventor： Alexander R. Pokora ,  Mark A. Johnson

IPC: B09C1/08 ,  B09C1/10 ,  C02F3/34 ,  C08G61/00 ,  C12N9/08 ,  C12P7/22

CPC classification number: C12N9/0065 ,  B09C1/08 ,  B09C1/10 ,  C02F3/342 ,  C08G61/00 ,  C12P7/22 ,  Y10S210/908 ,  Y10S210/909 ,  Y10S210/912 ,  Y10S210/917 ,  Y10S210/928

Abstract: A method for oxidizing organic and/or heavy metal contaminants in wastewaters, sludges, or soils containing such contaminants by contacting the wastewaters, sludges, or soils with soybean peroxidase and a peroxide.

Abstract translation: 通过使废水，污泥或土壤与大豆过氧化物酶和过氧化物接触来对含有这种污染物的废水，污泥或污垢中的有机和/或重金属污染物进行氧化的方法。

公开(公告)号：US5147793A

公开(公告)日：1992-09-15

申请号：US599584

申请日：1990-10-18

Applicant: Mark A. Johnson ,  Alexander R. Pokora ,  William L. Cyrus, Jr.

Inventor： Mark A. Johnson ,  Alexander R. Pokora ,  William L. Cyrus, Jr.

IPC: C08G61/00 ,  C12N9/08 ,  C12P7/22 ,  C12P7/24

CPC classification number: C12N9/0065 ,  C08G61/00 ,  C12P7/22

Abstract: Biocatalytic oxidative processes wherein oxidizable substrates are reacted with peroxides in the presence of a peroxidase such as soybean peroxidase or another legume peroxidase; an oxidative coupling reaction for producing phenolic resins; a method for the purification of peroxidase enzyme-containing extracts generally also are described.

公开(公告)号：US4992372A

公开(公告)日：1991-02-12

申请号：US305311

申请日：1989-02-02

Applicant: Alexander R. Pokora ,  Mary M. Stanley ,  William L. Cyrus, Jr.

Inventor： Alexander R. Pokora ,  Mary M. Stanley ,  William L. Cyrus, Jr.

IPC: C12N9/08

CPC classification number: C12N9/0065 ,  Y10S435/814 ,  Y10S435/816

Abstract: A method for purifying an aqueous peroxidase enzyme containing solution and peroxidase solution purified thereby are disclosed; the method includes the steps of:providing an aqueous solution containing a peroxidase enzyme;adding a water-immiscible or partially water-miscible organic solvent to said aqueous solution to form a mixture having an organic phase and an aqueous phase;agitating said mixture to extract impurities from said aqueous phase into said organic phase;separating said aqueous phase from said organic phase; anddiscarding said organic phase.

Abstract translation: 公开了一种纯化过氧化物酶水溶液和由此提纯过氧化物酶溶液的方法， 该方法包括以下步骤：提供含有过氧化物酶的水溶液; 向所述水溶液中加入与水不混溶或部分水混溶的有机溶剂以形成具有有机相和水相的混合物; 搅拌所述混合物以将杂质从所述水相中提取到所述有机相中; 将所述水相与所述有机相分离; 并丢弃所述有机相。

公开(公告)号：US4900671A

公开(公告)日：1990-02-13

申请号：US70594

申请日：1987-07-08

Applicant: Alexander R. Pokora ,  William L. Cyrus, Jr.

Inventor： Alexander R. Pokora ,  William L. Cyrus, Jr.

IPC: B41M5/155 ,  C08G61/10

CPC classification number: B41M5/155 ,  C08G61/10 ,  Y10T428/234 ,  Y10T428/31967

Abstract: A process for the preparation of a phenolic resin which comprises reacting a phenol with a peroxidase or an oxidase enzyme and a peroxide in an organic solvent containing medium to generate phenolic radicals which react to form a phenolic resin.

Abstract translation: 一种制备酚醛树脂的方法，其包括使苯酚与过氧化物酶或氧化酶和过氧化物在含有机溶剂的介质中反应以产生酚醛树脂反应形成酚醛树脂。

公开(公告)号：US5583267A

公开(公告)日：1996-12-10

申请号：US379202

申请日：1995-01-27

Applicant: Thurman M. Wheeler ,  Mark K. Morehart ,  Gregory Kaplan ,  Alexander R. Pokora

Inventor： Thurman M. Wheeler ,  Mark K. Morehart ,  Gregory Kaplan ,  Alexander R. Pokora

IPC: C12P7/22 ,  C07C37/00

CPC classification number: C12P7/22

Abstract: In accordance with the present invention, tetraalkylbisphenols are prepared by biocatalytic dimerization of di-(lower alkyl)-substituted phenols in the presence of peroxidase enzyme and peroxide. Three reaction pathways to the desired diols are provided.

Abstract translation: 根据本发明，在过氧化物酶和过氧化物的存在下，通过二 - （低级烷基）取代的酚的生物催化二聚制备四烷基双酚。 提供了对所需二醇的三种反应途径。